Modification of single molecule fluorescence by a scanning probe

We examine the optical near-field interaction between different types of scanning tips and single oriented fluorescent molecules. We demonstrate the influence of a tip on the excitation intensity as well as on the integrated fluorescence signal, the excited state lifetime, and the angular emission of single molecules. By using a standard model describing the radiation of an oscillating dipole close to a nanosphere or a flat interface, we interpret our observations and describe some central criteria for obtaining fluorescence enhancement or quenching. PACS 33.80.-b; 07.79.Fc; 78.90.+t     

Optical properties of in situ doped and undoped titania nanocatalysts and doped titania sol-gel nanofilms

In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO₂) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO₂ thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO₂ absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO₂ are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO₂ films prepared for undoped sol-gels and by sputtering is performed.     

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayers

High temperature annealing effect on structural and magnetic properties of Ti/Ni multilayer (ML) up to 600 °C have been studied and reported in this paper. Ti/Ni multilayer samples having constant layer thicknesses of 50 Å each are deposited on float glass and Si(1 1 1) substrates using electron-beam evaporation technique under ultra-high vacuum (UHV) conditions at room temperatures. The micro-structural parameters and their evolution with temperature for as-deposited as well as annealed multilayer samples up to 600 °C in a step of 100 °C for 1 h are determined by using X-ray diffraction (XRD) and grazing incidence X-ray reflectivity techniques. The X-ray diffraction pattern recorded at 300 °C annealed multilayer sample shows interesting structural transformation (from crystalline to amorphous) because of the solid-state reaction (SSR) and subsequent re-crystallization at higher temperatures of annealing, particularly at ≥400 °C due to the formation of TiNi₃ and Ti₂Ni alloy phases. Sample quality and surface morphology are examined by using atomic force microscopy (AFM) technique for both as-deposited as well as annealed multilayer samples. In addition to this, a temperature dependent dc resistivity measurement is also used to study the structural transformation and subsequent alloy phase formation due to annealing treatment. The corresponding magnetization behavior of multilayer samples after each stage of annealing has been investigated by using Magneto-Optical Kerr Effect (MOKE) technique and results are interpreted in terms of observed micro-structural changes.     

On an evasion problem on a semi-infinite interval for a class of controlled distributed systems

In this paper, we study an evasion problem in systems described by equations of parabolic type. We consider four versions of constraints on the control parameters.     

On the structure of finite coverings of compact connected groups

Finite-sheeted covering mappings onto compact connected groups are studied. We show that for a covering mapping from a connected Hausdorff topological space onto a compact (in general, non-abelian) group there exists a topological group structure on the covering space such that the mapping becomes a homomorphism of groups. To prove this fact we construct an inverse system of covering mappings onto Lie groups which approximates the given covering mapping. As an application, it is shown that a covering mapping onto a compact connected abelian group G must be a homeomorphism provided that the character group of G admits division by degree of the mapping. We also get a criterion for triviality of coverings in terms of means and prove that each finite covering of G is equivalent to a polynomial covering.     

Corn stover fractions and bioenergy

Information is presented on structure, composition, and response to enzymes of corn stover related to barriers for bioconversion to ethanol. Aromatic compounds occurred in most tissue cell walls. Ferulic acid esterase treatment before cellulase treatment significantly improved dry weight loss and release of phenolic acids and sugars in most fractions over cellulase alone. Leaf fractions were considerably higher in dry weight loss and released sugars with esterase treatment, but stem pith cells gave up the most phenolic acids. Results help identify plant fractions more appropriate for coproducts and bioconversion and those more suitable as residues for soil erosion control.