MEASUREMENT OF FISSION FRAGMENT ANGULAR DISTRIBUTION IN HEAVY-IONS INDUCED REACTION

The angular distributions of fission fragments for a series of compound nuclei formed in the bombardment of ¹⁸¹Ta,¹⁹⁷Au Pb and ²⁰⁹Bi by ¹²C ions and in the bombardment of natural lead by ¹⁴N ions were measu ed with mica track detectors and gold surface barrier detectors.It is shown that all experimental data for the fission fragment angular distributions can be fitted by the statistical scission model of fission fragment angular distribution.     

MEASUREMENTS OF ANGULAR MOMENTUM EFFECT OF FISSION BARRIER

The fission cross sections and the evaporation residue cross sections for ¹²C+²⁰⁹Bi and ¹⁴N+Pb reactions were measured with the gold surface barrier silicon detectors and the mica nuclear track detectors.The critical angular momentum l_er was deduced from the measured evaporation residue cross section σ_er on the basis of the sharp-off model.The fission barrier with the particular angular momentum i derived from the condition Γ_f/Γ_n=1 at l=l_e The angular momentum effect of the fission barrier was studied experimentally.     

基于AFM纳米氧化技术的金纳米粒子定点组装

二维纳米粒子矩阵列在纳米电子器件^[1,2]、表面增强喇曼活性基底^[3,4]、刻蚀掩模^[5]等领域具有广泛的应用前景。在这些纳米粒子阵列为内部,纳米粒子的排布是随机、无序的。这一缺点已经妨碍了纳米粒子阵列在上述领域中的进一步应用。基于此,人们开始关注纳米粒子的可控组装。传统的光刻技术^[6]、微接触印刷技术^[7]以及生物分子模板技术^[8]都被用来实现纳米粒子在固体表面上的可控组装,本实验室在纳米粒子的合成及可控组装方面也进行了研究^[7,9,11]。本文力图精确控制单个纳米粒子在基底表面上的组装位置。利用AFM纳米氧化技术。在硅表面构建了纳米级的化学图形化表面,通过不同的化学官能团,如甲基、氨基对金纳米粒子亲和性质的差异,实现了纳米粒子在固体表面的定点组装。     

Synthesis and Structure Elucidation of Celangulin Derivatives

Celangulins are sesquiterpene polyol esters based on a core structure known as β-dihydroagarofuran from Celastrus angulatus Max. Some of them are environment acceptable-pesticides. In order to find new active compounds and study their SAR, sesquiterpene polyol esters libraries were synthesized based on the basic hydrolysis of the extract of the root bark of Celastrus angulatus which could offer the β-dihydroagarofuran polyol by combinatorial chemical method and the compounds with insecticidal activity were isolated by bioassay-guided fractionation. Two new compounds with insecticidal activity against Mythimna separata, were isolated and elucidated as 2β,6α,8β, 13-tetraisobutanoyloxy-1β,4,9α-trihydroxy-β-dihydroagarofuran (A) and 1β,2β,6α,8β, 13-pentaisobutanoyloxy-4α,9α-dihydroxy-β-dihydroagarofuran (B) mainly by 1H NMR, 13C NMRH-HCOSY, HMQC, HMBC and HRMS spectral data. A: [α]20D -7.3 (c 0.12, CHCl3), B: [α]20D -34.6 (c 0.8,CHCl3).     

稳定自由基掺杂有机物的动态核极化研究

The DNP-enhanced NMR experiment was performed on the DBF samples doped with free radicals. The experimental results show that it becomes very easy to perform the complicate NMR experiments under DNP enhancement. For the sample whose spin lattice relaxation is very slow, if it is doped with appropriate quantity free radicals.     

Crystal structure of [Cu4(pytp)2(SO4)2(H2O)10](SO4)2 · 4H2O. A tetranuclear copper(II) complex with a new asymmetric ligand,pytp*, as a bridge

A new asymmetric bridge ligand, pytp, was prepared and characterized systematically by f.t.i.r., u.v.–vis., ¹H-n.m.r. and by FAB-MS spectroscopy. A tetranuclear Cu^II complex [Cu₄(pytp)₂(SO₄)₂(H₂O)₁₀](SO₄)₂·4H₂O (1) was prepared and characterized by elemental analysis and u.v.–vis. spectroscopy. A crystal structure analysis indicates that there are two different coordination spheres in (1) and that two of the copper centers are bridged by two ₂-SO₄ entities, creating a most unusual sulphate bridge.     

Impedance method for rapid detection of total counts of bacteria and fungi in bottled purified water

A study was conducted to compare the current conventional method and the impedance method for rapid detection of total counts of bacteria and fungi in bottled purified water. The results indicated that the corresponding detection rate for the 2 methods was 94.5 and 90.4%, respectively. The detection time was shortened from 48 h (bacteria) and 5 days (fungi) to 14.5 and 44 h, respectively. Moreover, for more serious contamination, less time was needed. The impedance method predicted a positive sample within 11.3 h (bacteria) and 27.1 h (fungi). Therefore, the impedance method was found to be a rapid, accurate method.     

New Neutron-Rich Isotope 208Hg

The new neutron-rich isotope ²⁰⁸Hg has been identified for the first time from the reaction products in fully-stopping thick ^nat.Pb target bombarded by 30MeV/u ¹²C beam provided by the Heavy Ion Research Facility in Lanzhou.Assignment of the nuclide ²⁰⁸Hg was based on the measurements of the deacy γ energy and halflife of its daughter ²⁰⁸Ti,which was grown up with ²⁰⁸Hg β-deacy.The half-life of ²⁰⁸Hg β-deacy was determined to be 42+23－12 min.The average production cross section of ²⁰⁸Hg over the incident energy region from Coulomb barrier to 30MeV/u is found to be 1.1±0.5μb.     

The dihydro-beta-agarofuran sesquiterpenoids

Dihydro-Beta-agarofuran sesquiterpenoids are a structurally diverse class of natural products based on tricyclic 5,11-epoxy-5Beta,10alpha-eudesman-4-(14)-ene skeleton. Between January 1990 and June 2006, 462 new dihydro-Beta-agarofuran sesquiterpenoids of 74 structural types have been isolated from about 64 species of Celastraceae, 3 species of Hippocrateaceae and one species of Lamiaceae. The present review covers the chemical and biological activity research of dihydro-Beta-agarofuran sesquiterpenoids in the past 16 years. The chemical research includes structural classification into sesquiterpene polyesters and macrolide sesquiterpene pyridine alkaloids, synthesis of dihydro-Beta-agarofuran as well as extraction, isolation and purification methods. The biological activity research includes activities such as multidrug resistance (MDR) reversal activity, HIV inhibition, cytotoxicity, antitumor activity, antifeedant activity and insecticidal activity with some insights to their modes of actions.     

Particle swarm optimization of the stable structure of tetrahexahedral Pt-based bimetallic nanoparticles

Bimetallic nanoparticles, enclosed by high-index facets, have great catalytic activity and selectivity owing to the synergy effects of high-index facets and the electronic structures of alloy. In this paper, a discrete particle swarm optimization algorithm was employed to systematically investigate the structural stability and features of tetrahexahedral Pt-based bimetallic nanoparticles with high-index facets. Different Pt/Ag, Pt/Cu, Pt/Pd atom ratios and particle sizes were considered in this work. The simulation results reveal that these alloy nanoparticles exhibit considerably different structural characteristics. Pt–Ag nanoparticles tend to form Pt–Ag core–shell structure. Pt–Cu nanoparticles are preferred to take multi-shell structure with Cu on the outer surface while Pt–Pd nanoparticles present a mixing structure in the interior and Pd-dominated surface. Atomic distribution and bonding characteristics were applied to further characterize the structural features of Pt-based nanoparticles. This study provides an important insight into the structural stability and features of Pt-based nanoparticles with different alloys.