金属卟啉配合物在无机层状框架中的插入组装及光学性能

利用插入化学法,将金属卟啉配合物——四苯基卟啉合银(Ⅱ),组装到改性磷酸锆(十二烷基三甲基铵磷酸锆)无机层状物中.配合物与改性磷酸锆作用后,层状框架的层间距由3.00nm调整到1.96 nm,卟啉的Soret吸收带和发射光谱都出现明显的位移,其中最大吸收由421 nm红移到429 nm,最大发射由651 nm红移到65...     

第一性原理研究KDP晶体中Ba取代K点缺陷

 用基于第一性原理的CASTEP模拟了Ba替代K缺陷前后形成的电子结构和能态密度。发现晶体能带宽度降至6.4 eV左右,对应着380 nm的双光子吸收,这一结果可以解释掺Ba晶体在紫外波段的吸收现象。Ba替代K点缺陷仅使其周围的晶格及电子结构发生轻微畸变,对晶体整体结构影响不大。     

含超导材料Thue-Morse序列一维光子晶体传输特性研究

超导光子晶体是一类重要的带隙可调谐的光子晶体.利用传输矩阵法研究了含超导材料的Thue -Morse序列准周期结构—维光子晶体在可见光波段的传输特性.数值结果表明在正入射时,光子带隙宽度和位置基本不随序列项数的增加而改变;准周期超导光子晶体的传输特性可以通过改变传统电介质材料的结构参数和环境温度等来进行调节.     

Development of optical fiber-based respiration sensor for noninvasive respiratory monitoring

In this study, two types of nasal-cavity-attached fiber-optic respiration sensors have been fabricated for noninvasive respiratory monitoring. One is a silver halide optical-fiber-based respiration sensor that can measure the variations of infrared radiation generated by the respiratory airflow from a nasal cavity. The other is a thermochromic-pigment-based fiber-optic respiration sensor that can measure the intensity of reflected light which changes owing to color variations of the temperature-sensing film according to the temperature difference between inspiratory and expiratory air. We have demonstrated the similarities of the respiratory signals using the fiber-optic respiration sensors and the temperature transducer of the BIOPAC? system. In addition, we verified that respiratory signals without the deterioration of the MR image can be obtained using the fiber-optic respiration sensors. It is anticipated that the proposed noninvasive fiberoptic respiration sensors will be highly effective for respiratory monitoring of a patient during MRI procedures.     

High-speed scanning fiber-optic heterodyne interferometer using a micro-electro-mechanical system mirror and an f-theta lens

This paper describes a novel fiber-coupled heterodyne interferometer using a micro-electro-mechanical system (MEMS) mirror and an f-theta lens. In this interferometer system, the cross-polarized laser beams operating at 2 μm with the frequency difference of 100 kHz are introduced by means of the two acousto-optic modulators (AOM). The sample with diameter of 300 mm is uniformly scanned by the 1 mm laser beam with the help of the combined optical scanning configuration, a MEMS mirror and an f-theta lens. The output intermediate signal from the two channels, reference channel and the measurement channel, are processed in the 12 bit analog-to-digital (A/D) process system. Details of our interferometer scheme are discussed.     

Evaluation of the dosimetric characteristics of a radiophotoluminescent glass dosimeter for high-energy photon and electron beams in the field of radiotherapy

We aimed to evaluate the suitability of a glass dosimeter (GD) for high-energy photon and electron beams in experimental and clinical use, especially for radiation therapy. We examined the expanded dosimetric characteristics of GDs including dose linearity up to 500 Gy, uniformity among GD lots and for individual GDs, the angular dependence, and energy dependence of 4 therapeutic x-ray qualities. In addition, we measured the dosimetric features (dose linearity, uniformity, angular dependence, and energy dependence) of the GD for electron beams of 10 different electron energy qualities. All measurements with the exception of dose linearity for photon beam were performed in a water phantom. For high-energy photon beams, dose linearity has a linear relationship for a dose ranging from 1 to 500 Gy with the coefficient of determination; R² of 0.998. The uniformity of each GD of dose measurements was within ±0.5% for four GD lots and within ±1.2% for 80 GDs. In terms of the effects of photon beam angle, lower absorbed doses of within 1.0% were observed between 60° and 105° than at 90°. The GD energy dependence of 4 photon beam energy qualities was within ±2.0%. On the other hand, the result of the dose linearity for high-energy electron beams showed well fitted regression line with the coefficient of determination; R² of 0.999 between 6 and 20 MeV. The uniformity of GDs exposed to the nominal electron energies 6, 9, 12, 16, and 20 MeV was ±1.2%. In terms of the angular dependence to electron beams, absorbed doses were within 2.0% between 60° and 105° than at 90°. In evaluation of the energy dependence of the GD at nominal electron energies between 5 and 20 MeV, we obtained responses between 1.1% and 3.5% lower than that for a cobalt-60 beam. Our results show that GDs can be used as a detector for determining doses when a high-energy photon beam is used, and that it also has considerable potential for dose measurement of high-energy electron beam.     

Effects of geometrical symmetry on the vortex in mesoscopic superconductors

We first systematically study the multivortex states in mesoscopic superconductors via self-consistent Bogoliubov-de Gennes equations. Our work focuses on how the geometrical symmetry affects the penetration and arrangement of vortices in mesoscopic superconductors and find that the key parameter determining the entrance of the vortex is the current density at the hot spots on the edge of sample. Through determining the spatial distribution of hot spots, the geometrical symmetry of the superconducting sample influences the nucleation and entrance of vortices. Our results propose one possible experimental approach to control and manipulate the quantum states of mesoscopic superconductors with their topological geometries, and they can be easily generalized to the confined superfluids and Bose-Einstein condensates.     

High efficiency top-emitting white organic light-emitting devices with a (metal/organic)2 cathode

White top-emitting organic light-emitting devices (TEOLEDs) were fabricated on a glass substrate with metal/organic multilayer of (Ag/Alq₃)₂ (Alq₃ is tris-(8-hydroxyquinoline) aluminum) as cathode. White TEOLEDs with high efficiency were obtained due to the microcavity effects. And the (Ag/Alq₃)₂ cathode, which adjusted the optical characteristics of the devices, played an important role. In addition, Alq₃–Ag–Alq₃ multilayer could work as a buffer layer, which would simplify the process of encapsulation for devices. We also calculated the electroluminescence spectrum of devices encapsulated with Al₂O₃ (150 nm) and Al₂O₃(75 nm)/ZrO₂(75 nm). And the results indicated that the CIE coordinates is almost the same between with and without encapsulating.     

Signaling-based path-segment protection in mesh optical networks

Path protections have become increasingly important for current mesh optical networks because fast restorations in generalized multiprotocol label switching(GMPLS) networks are uncertain.However,setting up additional disjoint paths to protect connections leads to more path setup blocking and signaling collisions.We analyze signaling collisions,path blocking and blocking probability,as well as calculate node-to-node blocking probabilities.A signaling-based path-segment protection(PSP) is proposed,which integrates segment protections and path protections as well as enhances the performance of path protections and ring protections.The setup of PSP connections causes less blocking probability than the setup of path protection connections in the simulations.     

Reflex optical sensor based on dual metal gratings with high angular sensitivity

An interesting reflection phenomenon in a dual metal grating (DMG) structure is studied, which is related to the competition between Fabry-Prot (F-P) resonance effect and evanescent-field coupling effect inside the gap between the two composing single metal gratings. This competition leads to high angular sensitivity in response to the refractive index variation of the sample solution in the gap. A reflex optical sensor with high sensitivity based on DMG for detecting the change in refractive index is proposed and its performance theoretically is discussed.