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991.
Petr Vlček Miroslav Janata Petra Látalová Jiří Dybal Milena Špírková Luděk Toman 《Journal of polymer science. Part A, Polymer chemistry》2008,46(2):564-573
Graft copolymers with cellulose diacetate (CDA) backbone and both the poly(ε‐caprolactone) and polystyrene, or poly(butyl acrylate) or PMMA grafts were prepared by two‐step process. First, ε‐caprolactone (CL) was polymerized by ring‐opening polymerization (ROP) initiated with CDA, partly funcionalized with 2‐bromo‐isobutyryl groups (degree of functionalization was 0.5). The p(CDA‐g‐CL) copolymers were used in the second step as polyfunctional macroinitiators of ATRP of the vinyl monomer, giving densely grafted copolymers with polyester and PSt, or PBuA, or PMMA grafts. The prepared copolymers were characterized by SEC, some of them also by FTIR spectroscopy and atomic force microscopy (AFM). © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 564–573, 2008 相似文献
992.
L. Q. Ji 《Journal of Thermal Analysis and Calorimetry》2008,91(3):885-889
Three rational fraction approximations for the temperature integral have been proposed using the pattern search method. The
validity of the new approximations has been tested by some numerical analyses. Compared with several published approximating
formulas, the new approximations is more accurate than all approximations except the approximations proposed by Senum and
Yang in the range of 5≤E/RT≤100. For low values of E/RT, the new approximations are superior to Senum-Yang approximations as solutions of the temperature integral. 相似文献
993.
994.
在介质水中,直接耐晒翠蓝GB在609nm处有特征吸收峰,据此建立了一种紫外分光光度法测定直接耐晒翠蓝GB染色强度的方法。 相似文献
995.
996.
997.
998.
Ji‐Fang Fu Li‐Yi Shi Shuai Yuan Qing‐Dong Zhong Deng‐Song Zhang Yi Chen Jun Wu 《先进技术聚合物》2008,19(11):1597-1607
New hyperbranched poly(trimellitic anhydride‐triethylene glycol) ester epoxy (HTTE) is synthesized and used to toughen diglycidyl ether of bisphenol A (DGEBA) 4,4′‐diaminodiphenylmethane (DDM) resin system. The effects of content and generation number of HTTE on the performance of the cured systems are studied in detail. The impact strength is improved 2–7 times for HTTE/DGEBA blends compared with that of the unmodified system. Scanning electron microscopy (SEM) of fracture surface shows cavitations at center and fibrous yielding phenomenon at edge which indicated that the particle cavitations, shear yield deformation, and in situ toughness mechanism are the main toughening mechanisms. The dynamic mechanical thermal analyzer (DMA) analyses suggest that phase separation occurred as interpenetrating polymer networks (IPNs) for the HTTE/DGEBA amine systems. The IPN maintains transparency and shows higher modulus than the neat epoxy. The glass transition temperature (Tg) decreases to some extent compared with the neat epoxy. The Tg increases with increase in the generation number from first to third of HTTE and the concentrations of hard segment. The HTTE leads to a small decrease in thermal stability with the increasing content from TGA analysis. The thermal stability increases with increase in the generation number from first to third. Moreover, HTTE promotes char formation in the HTTE/DGEBA blends. The increase in thermal properties from first to third generation number is attributed to the increase in the molar mass and intramolecular hydrogen bridges, the increasing interaction of the HTTE/DGEBA IPNs, and the increasing crosslinking density due to the availability of a greater number of end hydroxyl and end epoxide functions. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
999.
This paper presents the derivation of the precise relation between the displacement of a light spot on an object's surface and the displacement of its image on the detector in an optical triangulation device, along with applications of the design of triangulation devices. Based on this relation, improved designs of optical triangulation devices, including devices of adjustable configurations, are proposed and discussed. 相似文献
1000.
Yanju Wang Xianhong Wang Ji Li Hongfang Zhang Zhishen Mo Xiabin Jing Fosong Wang 《Journal of Polymer Science.Polymer Physics》2002,40(7):605-612
Conducting polyaniline‐poly(ethylene oxide) blends were prepared from their aqueous solutions. The blends displayed an electrical conductivity percolation threshold as low as 1.83 wt % of polyaniline loading. As demonstrated by scanning electron microscopy, polarized optical microscopy, and wide‐angle X‐ray diffraction studies, the conducting polyaniline took a fibrillar morphology in the blend, and it existed only in the amorphous phase of poly(ethylene oxide). A three‐phase model combining morphological factors instead of a two‐phase model was proposed to explain the low‐conductivity percolation threshold. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 605–612, 2002; DOI 10.1002/polb.10114 相似文献