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971.
972.
XuHai Yang ZhiGang Li ChuGang Feng Ji Guo HuLi Shi GuoXiang Ai FengLei Wu RongChuan Qiao 《中国科学G辑(英文版)》2009,52(3):333-338
A geostationary (GEO) satellite may serve as a navigation satellite, but there is a problem that maneuvers frequently occur
and the forces are difficult to model. Based on the technique of determining satellite orbits by transfer, a predicted orbit
with high accuracy may be achieved by the method of statistical orbit determination in case of no maneuver force. The predicted
orbit will soon be invalid after the maneuver starts, and it takes a long time to get a valid orbit after the maneuver ends.
In order to improve ephemeris usability, the method of rapid orbit forecasting after maneuvers is studied. First, GEO satellite
movement is analyzed in case of maneuvers based on the observation from the orbit measurement system by transfer. Then when
a GEO satellite is in the free status just after maneuvers, the short arc observation is used to forecast the orbit. It is
assumed that the common system bias and biases of each station are constant, which can be obtained from orbit determination
with long arc observations. In this way, only 6 orbit elements would be solved by the method of statistical orbit determination,
and the ephemeris with high accuracy may be soon obtained. Actual orbit forecasting with short arc observation for SINOSAT-1
satellite shows that, with the tracking network available, the precision of the predicted orbit (RMS of O-C) can reach about
5 m with 15 min arc observation, and about 3 m with 30 min arc observation.
Supported by the National High Technology Research and Development Program of China (Grant No. 2006AA12Z322), the National
Basic Research Program of China (Grant No. 2007CB815503), and the West Light Program of Chinese Academy of Sciences (Grant
No. 2007LH01) 相似文献
973.
974.
975.
An alternative approach to synthesize pedamide,a key building block of pederin was described.Iodine-induced asymmetric heterocyclization was used as the key step to construct the skeleton,a tetrahydropyran ring with three chiral centers.Brown's asymmetric allylation and Lewis acid-mediated allylation were investigated to introduce chains and chiral alcohols.Sharpless dihydroxylation decorated the side chain.And high optically pure target was obtained by removing the epimers formed in these reactions on c... 相似文献
976.
Yong Wang Xinyi Cao Jingfei Ji Xiuling Cui Chao Pi Leyao Zhao Yangjie Wu 《中国化学快报》2021,32(5):1696-1700
A green tandem reaction, including insertion/aerobic oxidation/bisindolylation, starting from indoles and diazo compounds has been developed. The combination of water and fluorinated alcohol plays dual roles as solvent and promoter in this chemical transformation. Molecular oxygen in the air acts as an oxidant. 3,3′-Bis(indolyl)methanes with quaternary carbon were produced under metal-free conditions. No any catalyst and additive were required. N2 and water were released as sole by-products. Absence of water and fluorinated alcohol resulted in Wolff rearrangement product. 相似文献
977.
Bartosz Mozgawa Dr. Filip Zasada Dr. Monika Fedyna Prof. Kinga Góra-Marek Dr. Edyta Tabor Dr. Kinga Mlekodaj Dr. Jiří Dědeček Prof. Zhen Zhao Dr. Piotr Pietrzyk Prof. Zbigniew Sojka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(68):17159-17180
NH3 temperature-programmed desorption (NH3-TPD) is frequently used for probing the nature of the active sites in CuSSZ-13 zeolite for selective catalytic reduction (SCR) of NOx. Herein, we propose an interpretation of NH3-TPD results, which takes into account the temperature-induced dynamics of NH3 interaction with the active centers. It is based on a comprehensive DFT/GGA+D and first-principles thermodynamic (FPT) modeling of NH3 adsorption on single Cu2+, Cu+, [CuOH]+ centers, dimeric [Cu-O-Cu]2+, [Cu-O22−-Cu]2 species, segregated CuO nanocrystals and Brønsted acid sites (BAS). Theoretical TPD profiles are compared with the experimental data measured for samples of various Si/Al ratios and distribution of Al within the zeolite framework. Copper reduction, its relocation, followed by the intrazeolite olation/oxolation processes, which are concomitant with NH3 desorption, were revealed by electron paramagnetic resonance (EPR) and IR. DFT/FPT results show that the peaks in the desorption profiles cannot be assigned univocally to the particular Cu and BAS centers, since the observed low-, medium- and high-temperature desorption bands have contributions coming from several species, which dynamically change their speciation and redox states during NH3-TPD experiment. Thus, a rigorous interpretation of the NH3-TPD profiles of CuSSZ-13 in terms of the strength and concentration of the active centers of a particular type is problematic. Nonetheless, useful connections for molecular interpretation of TPD profiles can be established between the individual component peaks and the corresponding ensembles of the adsorption centers. 相似文献
978.
主要论述n次单位根在一些组合数求和、多项式的整除、因式分解中的应用,说明了n次单位根法可拓宽解题思路,是一种方便、快捷的数学解题方法. 相似文献
979.
We prove that a system of linear inequalities with interval-valued data is weakly solvable (each system obtained by fixing coefficeints in the intervals prescribed has a solution) if and only if it is strongly solvable (all such systems have a solution in common) and desribe an algorithm for checking strong solvability. 相似文献
980.
C.-X. Ji M. L. Huang M. J. Kramer C. Zhang K. S. Wu Y. Yang Y. A. Chang 《Applied Physics A: Materials Science & Processing》2010,99(2):471-475
Pt0.5−x
Mn0.5+x
films were prepared by sputtering deposition of Pt foil and Mn target to study the order-disorder transition from a thermodynamic
metastable fcc (A1) phase to L10 phase. Both Differential Scanning Calorimetry and High Temperature X-Ray Diffraction studies showed the phase transformation
from fcc to the L10 structure for the Pt0.50Mn0.50 and Pt0.40Mn0.60 samples but along completely different kinetic paths. A composition dependent phase transformation was observed by comprehensive
Differential Scanning Calorimetry studies on a series of Pt0.5−x
Mn0.5+x
samples. The changes of the lattice parameter and the cell volume of L10 Pt0.5−x
Mn0.5+x
as a function of composition suggest that the anti-site is not the dominant point defect for L10 Pt0.5−x
Mn0.5+x
. 相似文献