TFA-catalyzed C–N bond activation of enamides with indoles: efficient synthesis of 3,3-bisindolylpropanoates and other bisindolylalkanes

An efficient TFA-catalyzed cleavage of C–N bonds in alkylation of indoles by tertiary enamides was described. A variety of bisindolylalkane derivatives, especially 3,3-bisindolylpropanoates, were expeditiously synthesized in good yields.     

Asymptotics of variance of the lattice point count

The variance of the number of lattice points inside the dilated bounded set rD with random position in ℝ ^d has asymptotics ∼ r ^d−1 if the rotational average of the squared modulus of the Fourier transform of the set is O(ϰ ^−d−1). The asymptotics follow from Wiener’s Tauberian theorem.     

Synthesis and fungicidal activity of novel strobilurin analogues containing substituted N-phenylpyrimidin-2-amines

A number of novel strobilurin analogues containing substituted N-phenylpyrimidin-2-amines were synthesized.The structures of these new compounds were confirmed by ~1H NMR,IR and elemental analysis.Biological evaluation in the greenhouse showed several compounds have good fungicidal activities at 25 mg/L.     

A new alkaloid from Lycoris aurea

A new alkaloid was isolated from the bulbs of Lycoris aurea(L'Herit.) Herb.Its structure was established as 3-o-ethyltazettinol through chemical and spectroscopic studies including 2D NMR.     

Retention Behaviors of Uronic Acid-containing Polysaccharides and Neutral Polysaccharides in HPGPC

The determination of molecular weights (Mw) of polysaccharides has served as an important process since the physical properties of the polysaccharides are closely related to their Mw and/or molecular weights distribution (MWD). For Mw and MWD determinations, high performance gel permeation chromatography (HPGPC) has gained wide acceptance as a preferred method due to its high sensitivity, speed and reproducibility. In chromatography, it is well known that the molecular weights are determ…     

Single-photon time response of reach-through APD

Time response of avalanche photodiode (APD) is very important in photon counting systems, and there are many models for circuit simulation. But these studies generally based on the carrier rate equations of steady-state condition, disagree with the single-photon-indicate condition. In this paper, a time response function based on an integration of APD’s sub-domain carriers for reach-through APD arising from a single photo-carrier is derived. The analytical results are shown to be in good accord with experimental results.