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431.
Chandrasekhar Chatterjee Sunandan Gangopadhyay Arindam Ghosh Hazra Saurav Samanta 《International Journal of Theoretical Physics》2008,47(9):2372-2381
The appearance of non(anti)commutativity in superstring theory, satisfying the Neveu-Schwarz boundary conditions is discussed
in this paper. Both an open free superstring and also one moving in a background antisymmetric tensor field are analyzed to
illustrate the point that string non(anti)commutativity is a consequence of the nontrivial boundary conditions. The method
used here is quite different from several other approaches where boundary conditions were treated as constraints. An interesting
observation of this study is that, one requires that the bosonic sector satisfies Dirichlet boundary conditions at one end
and Neumann at the other in the case of the bosonic variables X
μ
being antiperiodic. The non(anti)commutative structures derived in this paper also leads to the closure of the super constraint
algebra which is essential for the internal consistency of our analysis. 相似文献
432.
1‐Aroyl‐2‐styrylsulfonylethene is the precursor for 4,4‐dimethoxycarbonyl‐2′,5‐diaryl‐3‐(1′,3′‐dioxolano)‐1‐thia‐1,1‐dioxide ( 4 ), which is the key intermediate for the synthesis of 7‐aroyl‐11‐aryl‐2,4‐diazaspiro[5,5]undecane‐1,3,5‐trione‐9‐thia‐9,9‐dioxide( 10 )/3‐thioxo‐1,5‐dione‐9‐thia‐9,9‐dioxide ( 11 ), 6‐aroyl‐10‐aryl‐2,3‐diazaspiro[4,5]decane‐1,4‐dione‐8‐thia‐8,8‐dioxide ( 12 )/2‐oxo‐3‐azaspiro [4,5]decane‐1,4‐dione‐8‐thia‐8,8‐dioxide ( 13 ). The new compounds were characterized by IR and 1H NMR spectral data. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:131–135, 2001 相似文献
433.
434.
A. Nallini K. Saraboji M. N. Ponnuswamy M. Venkatraj R. Jeyaraman 《Crystal Research and Technology》2005,40(6):622-626
Adducing structural analogies between the two fused systems, N1, N5‐Dibenzoyltetrahydro‐4‐methyl‐1,5‐benzodiazepin‐2‐one, C24H20N2O3 (DBTBO CCDC 200341) and Tetrahydro‐4‐methyl‐1,5‐benzodiazepin‐2‐one, C10H12 N2O (TBO CCDC 200342) helps to find the pharmacological differences from the view point of variant hetero atom substitutions in the hetero cycle. Both the diazepines crystallized in identical monoclinic space group P21/n with a = 14.1134(1) Å, b = 9.2444(1) Å, c = 16.3812(1) Å; β = 107.11(1)º, V = 2042.7(3) Å3 for DBTBO and a = 9.3363(7) Å, b = 10.4895(8) Å, c = 9.9852(7) Å, β = 91.314(1)º, V = 977.62(1) Å3 for TBO, respectively. The two structures were solved by direct methods and refined by full‐matrix least‐squares procedure to final R‐values of R1 = 0.0575(DBTBO) and R1 = 0.0984(TBO). Structural differences include non‐identical boat conformations of these seven‐membered rings and the different non‐bonding interactions in the benzodiazepine pair. 相似文献
435.
Gandham Munikumari Ramaiah Konakanchi Venkata Bharat Nishtala Gondru Ramesh Laxma Reddy Kotha K. B. Chandrasekhar 《合成通讯》2019,49(1):146-158
Substituted heterocyclic (isatin) appended thiosemicarbazone ligands (L1–L3) are synthesized by condensation of substituted isatin molecule with N(4)-phenyl-3-thiosemicarbazide in good yields. The palladium(II) complexes are synthesized from ligands (L1–L3) and PdCl2, with a general formula [PdCl(X-C15H10N4OS)] where X?=?5-chloro (1), 5-bromo (2), and 5-nitro (3). Both analytical and spectroscopic methods have been used for the analysis and characterization of the synthesized compounds. The antimicrobial activity results observed that complexes, 1 and 2 have registered potent antibacterial activity against B. subtilis and K. pneumoniae and also complex 2 has shown good antifungal activity against the micro organisms. The antioxidant activity analysis revealed that the complex 3 showed significant activity with IC50 values 7.24?±?0.09?µM. Moreover, the in vitro antiproliferative activity results suggested that complex 3 exhibited high activity against HeLa cell line compared with the standard with the IC50 value 16.52?±?1.08?µM. The docking results correlate well. 相似文献
436.
Debabrata Dhara Shubhajit Das Swapan K. Pati David Scheschkewitz Vadapalli Chandrasekhar Anukul Jana 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(43):15511-15515
An NHC‐coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon‐soluble monomeric AuI hydride, which readily adds CO2 at room temperature yielding the corresponding AuI formate. The reversible reaction can be expedited by the addition of NHC, which induces β‐hydride shift and the removal of CO2 from equilibrium through the formation of an NHC‐CO2 adduct. The AuI formate is alternatively formed by dehydrogenative coupling of the AuI hydride with formic acid (HCO2H), thus in total establishing a reaction sequence for the AuI hydride mediated dehydrogenation of HCO2H as chemical hydrogen storage material. 相似文献
437.
Chandrasekhar Mandala Prasad Gandavaram Syam Venkataramaiah Chintha Naga Raju Chamarthi Seshaiah Kalluru Rajendra Wudayagiri 《Molecular diversity》2019,23(3):723-738
Molecular Diversity - A series of new urea/thiourea derivatives 3a–j were synthesized by simple addition reaction of functionalized phenyl isocyanates/isothiocyanates 2a–j with... 相似文献
438.
Daniel Becker Dr. Bishnu P. Biswal Paula Kaleńczuk Dr. Naisa Chandrasekhar Dr. Lars Giebeler Dr. Matthew Addicoat Dr. Silvia Paasch Prof. Dr. Eike Brunner Prof. Dr. Karl Leo Dr. Arezoo Dianat Prof. Dr. Gianaurelio Cuniberti Dr. Reinhard Berger Prof. Dr. Xinliang Feng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(26):6562-6568
Cyano-substituted polyphenylene vinylenes (PPVs) have been the focus of research for several decades owing to their interesting optoelectronic properties and potential applications in organic electronics. With the advent of organic two-dimensional (2D) crystals, the question arose as to how the chemical and optoelectronic advantages of PPVs evolve in 2D compared with their linear counterparts. In this work, we present the efficient synthesis of two novel 2D fully sp2-carbon-linked crystalline PPVs and investigate the essentiality of inorganic bases for their catalytic formation. Notably, among all bases screened, cesium carbonate (Cs2CO3) plays a crucial role and enables reversibility in the first step with subsequent structure locking by formation of a C=C double bond to maintain crystallinity, which is supported by density functional theory (DFT) calculations. A quantifiable energy diagram of a “quasi-reversible reaction” is proposed, which allows the identification of further suitable C−C bond formation reactions for 2D polymerizations. Moreover, the narrowing of the HOMO–LUMO gap is delineated by expanding the conjugation into two dimensions. To enable environmentally benign processing, the post-modification of 2D PPVs is further performed, which renders stable dispersions in the aqueous phase. 相似文献
439.
Dr. Debdeep Mandal Shubhadeep Chandra Dr. Nicolás I. Neuman Alok Mahata Arighna Sarkar Dr. Abhinanda Kundu Dr. Srinivas Anga Hemant Rawat Prof. Dr. Carola Schulzke Dr. Kaustubh R. Mote Prof. Dr. Biprajit Sarkar Prof. Vadapalli Chandrasekhar Dr. Anukul Jana 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(27):5951-5955
A N-heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl-substituted alkenes in which the central carbon–carbon double bond is in a twisted geometry. 相似文献
440.