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Beatriz Veleirinho Manuel F. Rei J. A. Lopes‐DA‐Silva 《Journal of Polymer Science.Polymer Physics》2008,46(5):460-471
This study describes the preparation and characterization of nanofibrous mats obtained by electrospinning poly(ethylene terephthalate) (PET) solutions in trifluoroacetic acid/dichloromethane (TFA/DCM). Special attention was paid to the effect of polymer concentration and solvent properties on the morphology, structure, and mechanical and thermal properties of the electrospun nonwovens. The results show that the spinnable concentration of PET solution in TFA/DCM solvents is above 10 wt %. Mats have nanofibrous morphology with fibers having an average diameter in the range of 200–700 nm (depending on polymer concentration and solvent composition) and an interconnected pore structure. Higher solution concentration favors the formation of uniform fibers without beads and with higher diameter. Morphology and fiber assembly changed with the solvent properties. Solvent mixtures rich in TFA, i.e., those with higher dielectric constant and lower surface tension, originated fibers with small diameter. However, due to the lower volatility, those solvent mixtures also produced more branched and crosslinking fibers, with less morphologic uniformity. Mechanical properties (Young's modulus, ultimate strength, and elongation at break) and thermal properties (glass transition, crystallization, and melting) have been studied for the PET electrospun nanomats and compared with those of the original polymer. Solvent effect on fiber crystallinity was not significant, but a complex effect was observed on the mechanical properties of the electrospun mats, as a consequence of the different structural organization of the fibers within the mat network. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 460–471, 2008 相似文献
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龙爪芦荟和库拉索芦荟中微量锗的测定与红外光谱区别 总被引:1,自引:0,他引:1
采用吸光光度法对龙爪芦荟和库拉索芦荟中的微量锗进行了测定,并探讨了两种芦荟的红外光谱的区别。结果表明,龙爪芦荟中含锗量在26.1~28.6μg·g-1,回收率为91.6%~97 5%。库拉索芦荟中含锗量在16.8~20.0μg·g-1,回收率为87.1%~94.5%。两种芦荟的FT IR光谱图在2100cm-1处有明显差异,由此可区别两种芦荟。 相似文献
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QuEChERS-液相色谱-串联质谱法测定植物性食品中30种氨基甲酸酯类农药残留 总被引:3,自引:0,他引:3
基于欧洲标准化委员会标准方法(EN 15662)对食品基质的分类,选择6种代表性植物性食品作为基质,系统优化了QuEChERS样品前处理方法;在此基础上,建立了30种氨基甲酸酯类农药的液相色谱-串联质谱分析方法。实验结果表明,除涕灭威砜的线性范围为2~100 μg/kg,其他29种氨基甲酸酯类农药的线性范围均为1~100 μg/kg;6种样品基质在3个添加水平(5、20、100 μg/kg)下的回收率为56.13%~127.6%,相对标准偏差为0.47%~16%;以信噪比(S/N)≥10计,30种农药的定量限(LOQ)为0.041~1.9 μg/kg。本文方法灵敏、有效,适用于植物性食品基质中30种氨基甲酸酯类农药残留的测定。 相似文献
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研究了碱基在十二胺-N,N-二亚甲基膦酸(DDPA)改性氧化锆固定相(DPZ)上的色谱保留行为,考察了流动相中甲醇含量、流动相pH值、缓冲溶液中离子类型和离子强度对碱基保留的影响,对DDPA在氧化锆表面的吸附方式进行了研究。研究结果表明,DDPA仅以一个膦酸基与氧化锆结合,因而DPZ固定相表面上除了有长链的疏水烷基外,还有酸性的膦酸基和碱性的氨基。碱基分子中也存在氨基和酰胺基等极性基团,因此碱基在DPZ固定相上除了有疏水作用外,还具有电荷排斥作用、离子交换作用等多种保留机理。由于多种保留机理的存在,使得碱基在DPZ固定相上具有较好的分离选择性,在酸性条件下对碱基混合样品的分离取得了满意的结果。 相似文献
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A fluorocarbon-modified poly(N-isopropylacrylamide) has been synthesized by copolymerization of N-isopropyl acrylamide with a small amount of acrylate or methacrylate containing a perfluoroalkyl group. It was found that the hydrophilicity of macromolecular backbone is an important factor to the solution properties of the copolymers and that hydrophobic association between fluorocarbon groups is stronger than that between the corresponding hydrocarbon analogies. The viscosity of some of the copolymer solutions was very sensitive to temperature. It was dilatant at higher fluorocarbon comonomer content ( > 0.20-1.0 mol%) and was Newtonian at very low fluorocarbon comonomer content (0.03-0.2 mol% ) . Evidence for hydrophobic association of the fluorocarbon groups was obtained from the effects of adding Nad and surfactants on the solution viscosity. The LC-ST properties of these copolymers were studied by DSC method and this was also found to be consistent with hydrophobic association between the fluorocarbo 相似文献
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