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91.
Yejia Li Boyu Zhang Jessica N. Hoskins Scott M. Grayson 《Journal of polymer science. Part A, Polymer chemistry》2012,50(6):1086-1101
The copper (I)‐catalyzed azide‐alkyne cycloaddition “click” reaction was successfully applied to prepare well‐defined 3, 6, and 12‐arms polystyrene and polyethylene glycol stars. This study focused particularly on making “perfect” star polymers with an exact number of arms, as well as developing techniques for their purification. Various methods of characterization confirmed the star polymers high purity, and the structural uniformity of the generated star polymers. In particular, matrix‐assisted laser desorption ionization‐time‐of‐flight mass spectrometry revealed the quantitative transformation of the end groups on the linear polymer precursors and confirmed their quantitative coupling to the dendritic cores to yield star polymers with an exact number of arms. In addition to preparing well‐defined polystyrene and poly(ethylene glycol)homopolymer stars, this technique was also successfully applied to amphiphilic, PCL‐b‐PEG star polymers. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
92.
Rabindra N. Roy Lakshmi N. Roy Kathleen A. Allen Casey J. Mehrhoff Isaac B. Henson Jessica M. Stegner Alexis L. Jenkins Ankita A. Shah Stephen D. Rocchio 《Journal of solution chemistry》2012,41(6):1044-1053
In this study, we report the pH values of two buffer solutions without chloride ion and eight buffer solutions with NaCl with an ionic strength I=0.16 mol?kg?1. Electromotive force (emf) techniques have been used to get the cell potentials at 12 temperatures from 5 to 55?°C, including 37?°C. An extended form of the Bates-Guggenheim convention is used in the entire ionic strength range, 0.04 to 0.16?mol?kg?1. The residual liquid junction potentials (??E j ) of the buffer solutions of MOBS have been estimated from previous measurements with a flowing junction cell. These values of ??E j have been used for correction in order to ascertain the operational pH values of four buffer solutions of MOBS at 25 and 37?°C. These solutions are recommended as pH standards for physiological application in the pH range 7.4 to 7.7. 相似文献
93.
Jessica M. Torres Christopher M. Stafford David Uhrig Bryan D. Vogt 《Journal of Polymer Science.Polymer Physics》2012,50(5):370-377
The modulus and glass transition temperature (Tg) of ultrathin films of polystyrene (PS) with different branching architectures are examined via surface wrinkling and the discontinuity in the thermal expansion as determined from spectroscopic ellipsometry, respectively. Branching of the PS is systematically varied using multifunctional monomers to create comb, centipede, and star architectures with similar molecular masses. The bulk‐like (thick film) Tg for these polymers is 103 ± 2 °C and independent of branching and all films thinner than 40 nm exhibit reductions in Tg. There are subtle differences between the architectures with reductions in Tg for linear (25 °C), centipede (40 °C), comb (9 °C), and 4 armed star (9 °C) PS for ≈ 5 nm films. Interestingly, the room temperature modulus of the thick films is dependent upon the chain architecture with the star and comb polymers being the most compliant (≈2 GPa) whereas the centipede PS is most rigid (≈4 GPa). The comb PS exhibits no thickness dependence in moduli, whereas all other PS architectures examined show a decrease in modulus as the film thickness is decreased below ~40 nm. We hypothesize that the chain conformation leads to the apparent susceptibility of the polymer to reductions in moduli in thin films. These results provide insight into potential origins for thickness dependent properties of polymer thin films. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2012 相似文献
94.
Bahni Ray P. Dinesh Sankar Reddy Dipankar Bandyopadhyay Sang Woo Joo Ashutosh Sharma Shizhi Qian Gautam Biswas 《Theoretical and Computational Fluid Dynamics》2012,26(1-4):311-318
Instability of a thin electrolyte film undergoing a direct current electroosmotic flow has been investigated. The film with a compliant electrolyte–air interface is flowing over a rigid charged substrate. Unlike previous studies, inclusion of the Maxwell stresses in the formulation shows the presence of a new finite wavenumber shear-flow mode of instability, alongside the more frequently observed long-wave interfacial mode. The shear mode is found to be the dominant mode of instability when the electrolyte–solid and electrolyte–air interfaces are of opposite charge or of same charge but have very large zeta-potential at the electrolyte–air interface. The conditions for mode-switch (interfacial to shear) and the direction of the travelling waves are discussed through stability diagrams. Interestingly, the analysis shows that when the interfaces are of nearly same zeta potential, the ‘free’ electrolyte–air interface behaves more like a ‘stationary’ wall because of the ion transport in the reverse direction of the flow. 相似文献
95.
96.
Ray L. Frost Yunfei Xi Ricardo Scholz Andrés López Fernanda M. Belotti Mário L. S. C. Chaves 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):1526-1534
Abstract The metal lithium is very important in industry, including lithium batteries. An important source of lithium besides continental brines is granitic pegmatites as in Australia. Lithiophilite is a lithium and manganese phosphate with chemical formula LiMnPO4 and forms a solid solution with triphylite, its Fe analog, and belongs to the triphylite group that includes karenwebberite, natrophilite, and sicklerite. The mineral lithiophilite was characterized by chemical analysis and spectroscopic techniques. The chemical is: Li1.01(Mn0.60, Fe0.41, Mg0.01, Ca0.01)(PO4)0.99 and corresponds to an intermediate member of the triphylite-lithiophilite series, with predominance of the lithiophilite member. The mineral lithiophilite is readily characterized by Raman and infrared spectroscopy. 相似文献
97.
Elise A. Dennis Alexander W. Gundlach–Graham Christie G. Enke Steven J. Ray Anthony J. Carado Charles J. Barinaga David W. Koppenaal Gary M. Hieftje 《Journal of the American Society for Mass Spectrometry》2013,24(5):690-700
Resolution in time–of–flight mass spectrometry (TOFMS) is ordinarily limited by the initial energy and space distributions within an instrument’s acceleration region and by the length of the field–free flight zone. With gaseous ion sources, these distributions lead to systematic flight–time errors that cannot be simultaneously corrected with conventional static–field ion–focusing devices (i.e., an ion mirror). It is known that initial energy and space distributions produce non–linearly correlated errors in both ion velocity and exit time from the acceleration region. Here we reinvestigate an old acceleration technique, constant–momentum acceleration (CMA), to decouple the effects of initial energy and space distributions. In CMA, only initial ion energies (and not their positions) affect the velocity ions gain. Therefore, with CMA, the spatial distribution within the acceleration region can be manipulated without creating ion–velocity error. The velocity differences caused by a spread in initial ion energy can be corrected with an ion mirror. We discuss here the use of CMA and independent focusing of energy and space distributions for both distance–of–flight mass spectrometry (DOFMS) and TOFMS. Performance characteristics of our CMA–DOFMS and CMA–TOFMS instrument, fitted with a glow–discharge ionization source, are described. In CMA–DOFMS, resolving powers (FWHM) of greater than 1000 are achieved for atomic ions with a flight length of 285 mm. In CMA–TOFMS, only ions over a narrow range of m/z values can be energy–focused; however, the technique offers improved resolution for these focused ions, with resolving powers of greater than 2000 for a separation distance of 350 mm. 相似文献
98.
Jing Yang Qi Tao Ray L. Frost János Kristóf Erzsébet Horváth 《Journal of Thermal Analysis and Calorimetry》2013,111(1):329-334
Chromium oxyhydroxide nanomaterials with narrow size-distribution were synthesised through a simple hydrothermal method. Experimental conditions, such as reaction duration and pH values of the precipitation process and hydrothermal treatment played important roles in determining the nature of the final product chromium oxyhydroxide nanomaterials. The effect of these synthesis parameters were studied with the assistance of X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and thermogravimetric analyses. This research has developed a controllable synthesis of Chromium oxyhydroxide nanomaterials from Chromium oxide colloids. 相似文献
99.
Being able to predict the final product yield at all stages in long-running, industrial, mammalian cell culture processes is vital for both operational efficiency, process consistency, and the implementation of quality by design (QbD) practices. Here we used Raman spectroscopy to monitor (in terms of glycoprotein yield prediction) a fed-batch fermentation from start to finish. Raman data were collected from 12 different time points in a Chinese hamster ovary (CHO) based manufacturing process and across 37 separate production runs. The samples comprised of clarified bioprocess broths extracted from the CHO cell based process with varying amounts of fresh and spent cell culture media. Competitive adaptive reweighted sampling (CoAdReS) and ant colony optimization (ACO) variable selection methods were used to enhance the predictive ability of the chemometric models by removing unnecessary spectral information. Using CoAdReS accurate prediction models (relative error of predictions between 2.1% and 3.3%) were built for the final glycoprotein yield at every stage of the bioprocess from small scale up to the final 5000 L bioreactor. This result reinforces our previous studies which indicate that media quality is one of the most significant factors determining the efficiency of industrial CHO-cell processes. This Raman based approach could thus be used to manage production in terms of selecting which small scale batches are progressed to large-scale manufacture, thus improving process efficiency significantly. 相似文献
100.
Richard A. Bunce James E. Schammerhorn Jessica Sigle 《Journal of heterocyclic chemistry》2013,50(2):373-380
A tandem imine addition‐SNAr annulation reaction has been developed as a new approach to the synthesis of 4‐oxo‐1,2,3,4‐tetrahydroquinoline‐3‐carboxylic esters. A series of these structures has been generated by reacting selected imines with tert‐butyl 2‐fluoro‐5‐nitrobenzoylacetate. Structural variations in the final products are accomplished by changing the substituents on the imine and the alkyl group of the ester. The title compounds are isolated as their enols in 55–97% yield without the need for added base or catalysts. The synthesis of the starting materials as well as mechanistic studies and further synthetic conversions of the products are presented. 相似文献