Stabilization of Black Phosphorus by Sonication-Assisted Simultaneous Exfoliation and Functionalization

Black phosphorus (BP) has extraordinary properties, but its ambient instability remains a critical challenge. Functionalization has been employed to overcome the sensitivity of BP to ambient conditions while preserving its properties. Herein, a simultaneous exfoliation–functionalization process is reported that functionalizes BP flakes during exfoliation and thus provides increased protection, which can be attributed to minimal exposure of the flakes to ambient oxygen and water. A tetrabutylammonium salt was employed for intercalation of BP, resulting in the formation of flakes with large lateral dimensions. The addition of an aryl iodide or an aryl iodonium salt to the exfoliation solvent creates a scalable strategy for the production of functionalized few-layer BP flakes. The ambient stability of functionalized BP was prolonged to a period of one week, as revealed by STEM, AFM, and X-ray photoelectron spectroscopy.     

Particle-image velocimetry measurements of flow over interacting barchan dunes

Barchan dunes are crescentic planform-shaped dunes that are present in many natural environments, and may occur either in isolation or in groups. This study uses high-resolution particle-image velocimetry (PIV) experiments using fixed-bed models to examine the effects of barchan dune interaction upon the flow field structure. The barchan dune models were created from an idealized contour map, the shape and dimensions of which were based upon previous empirical studies of dune morphology. The experimental setup comprised two, co-axially aligned, barchan dune models that were spaced at different distances apart. In this paper, two volumetric ratios (V _r, upstream dune: downstream dune) of 1.0 and 0.175 were examined. Models were placed in a boundary-layer wind tunnel and flow quantification was achieved via PIV measurements of the mean and turbulent flow field in the streamwise–wall-normal plane, along the centerline of the barchan(s), at an average flow Reynolds number of 59,000. The presence of an upstream barchan dune induces a “sheltering effect” on the flow. Flow on the stoss side of the downstream dune is controlled by the developing internal boundary layer from the upstream dune, as well as by the turbulent flow structures shed from the free shear layer of the upstream dune leeside. At both volumetric ratios, enhanced turbulence is present over the downstream barchan dune leeside, which is proposed to be caused by the interaction of shear layers from the upstream and downstream dunes. Both the size and magnitude of the shear layer formed in the leeside of the upstream dune control this interaction, together with the proximity of this shear layer to the stoss side of the downstream dune. Proper orthogonal decomposition (POD) analysis shows that the distribution of turbulent kinetic energy is shifted to higher modes (i.e., smaller spatial scales) over interacting barchan dunes, which also reflects the role of the leeside free shear layer in dominating the flow field by generation, or redistribution, of TKE to smaller scales.     

Quinoidal oligoquinoline: a novel quinodimethane exhibiting high electroluminescence efficiency and p-channel field effect charge transport

A novel tetraphenylquinodimethane based on electron-deficient 4-phenylquinoline oligomer displayed an unusually low ionization potential and was used as a p-channel semiconductor in thin-film transistors and as an emitter to achieve very bright and high efficiency green light-emitting diodes.     

Solid-state carrier-envelope phase stabilization via quantum interference control of injected photocurrents

We demonstrate carrier-envelope phase stabilization of a mode-locked Ti:sapphire laser by use of quantum interference control of injected photocurrents in a semiconductor. No harmonic generation is required for this stabilization technique. Instead, interference between coexisting single- and two-photon absorption pathways in the semiconductor provides a phase comparison between different spectral components. The phase comparison, and the detection of the photocurrent that it produces, both occur within a single low-temperature-grown gallium arsenide sample. The carrier-envelope offset beat note fidelity is 30 dB in a 10-kHz resolution bandwidth. The out-of-loop phase-noise level is essentially identical to the best previous measurements with the standard self-referencing technique.     

Compulsive checking behavior of quinpirole-sensitized rats as an animal model of Obsessive-Compulsive Disorder(OCD): form and control

Background

A previous report showed that the open field behavior of rats sensitized to the dopamine agonist quinpirole satisfies 5 performance criteria for compulsive checking behavior. In an effort to extend the parallel between the drug-induced phenomenon and human obsessive-compulsive disorder (OCD), the present study investigated whether the checking behavior of quinpirole rats is subject to interruption, which is an attribute characteristic of OCD compulsions. For this purpose, the rat's home-cage was placed into the open field at the beginning or the middle of a 2-hr test.

Results

Introduction of the home-cage reduced checking behavior, as rats stayed inside the cage. After 40 min, checking resurfaced, as quinpirole rats exited the home-cage often. An unfamiliar cage had no such effects on quinpirole rats or saline controls.

Conclusions

Checking behavior induced by quinpirole is not irrepressible but can be suspended. Results strengthen the quinpirole preparation as an animal model of OCD compulsive checking.     

Explicit attention interferes with selective emotion processing in human extrastriate cortex

Background  

Brain imaging and event-related potential studies provide strong evidence that emotional stimuli guide selective attention in visual processing. A reflection of the emotional attention capture is the increased Early Posterior Negativity (EPN) for pleasant and unpleasant compared to neutral images (~150–300 ms poststimulus). The present study explored whether this early emotion discrimination reflects an automatic phenomenon or is subject to interference by competing processing demands. Thus, emotional processing was assessed while participants performed a concurrent feature-based attention task varying in processing demands.