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151.
Nilsson JR Li S Önfelt B Andréasson J 《Chemical communications (Cambridge, England)》2011,47(39):11020-11022
In this work we present a novel water soluble spiropyran photoswitch that can be photonically activated inside live cells from a form that has no significant effect on the cellular survival to a form that induces a dramatic toxic response. 相似文献
152.
Dreiser J Schnegg A Holldack K Pedersen KS Schau-Magnussen M Nehrkorn J Tregenna-Piggott P Mutka H Weihe H Bendix J Waldmann O 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(27):7492-7498
We have investigated the novel single-molecule magnet (NEt(4))[Mn(2)(5-Brsalen)(2)(MeOH)(2)Cr(CN)(6)] (1; 5-Brsalen = N,N'-ethylenebis(5-bromosalicylidene)iminato anion) using spectroscopic as well as magnetization and susceptibility measurements. Frequency-domain Fourier-transform terahertz electron paramagnetic resonance (FDFT THz-EPR) based on the generation of THz radiation from a synchrotron in combination with inelastic neutron scattering (INS) allows for the discrimination between intermultiplet and intramultiplet transitions. Together with ac/dc magnetic susceptibility measurements the obtained set of data provides a complete characterization of the lowest energetic magnetic excitations. We find that the new compound 1 exhibits much weaker intermolecular interactions than found in the closely related compound: K[Mn(2)(5-Brsalen)(2)(H(2)O)(2)Cr(CN)(6)] (2). Furthermore, two phonon lines in the vicinity of the magnetic excitations are detected. 相似文献
153.
In this paper we continue the investigation of partition functions of critical systems on a rectangle initiated in [R. Bondesan, et al., Nucl. Phys. B 862 (2012) 553–575]. Here we develop a general formalism of rectangle boundary states using conformal field theory, adapted to describe geometries supporting different boundary conditions. We discuss the computation of rectangular amplitudes and their modular properties, presenting explicit results for the case of free theories. In a second part of the paper we focus on applications to loop models, discussing in details lattice discretizations using both numerical and analytical calculations. These results allow to interpret geometrically conformal blocks, and as an application we derive new probability formulas for self-avoiding walks. 相似文献
154.
Jesper Rydén 《International Journal of Mathematical Education in Science & Technology》2013,44(3):357-363
Extreme-value statistics is often used to estimate so-called return values (actually related to quantiles) for environmental quantities like wind speed or wave height. A basic method for estimation is the method of block maxima which consists in partitioning observations in blocks, where maxima from each block could be considered independent. Typically a block could be chosen as one year. Large portions of missing data could result in problems for estimation and seems to be an issue not highlighted in detail in the literature. The method of block maxima is here applied to real data and a related simulation study was performed, pointing out that substantially low values tend to increase the estimated return values. A plausible explanation is given by studying the redistribution of probability mass and the implications of this for the behaviours of the tails of distributions. 相似文献
155.
Christophe A. N. Biscio Jesper Møller 《Journal of computational and graphical statistics》2013,22(3):671-681
We start with a simple introduction to topological data analysis where the most popular tool is called a persistence diagram. Briefly, a persistence diagram is a multiset of points in the plane describing the persistence of topological features of a compact set when a scale parameter varies. Since statistical methods are difficult to apply directly on persistence diagrams, various alternative functional summary statistics have been suggested, but either they do not contain the full information of the persistence diagram or they are two-dimensional functions. We suggest a new functional summary statistic that is one-dimensional and hence easier to handle, and which under mild conditions contains the full information of the persistence diagram. Its usefulness is illustrated in statistical settings concerned with point clouds and brain artery trees. The supplementary materials include additional methods and examples, technical details, and the R code used for all examples. 相似文献
156.
Munsch M Claudon J Bleuse J Malik NS Dupuy E Gérard JM Chen Y Gregersen N Mørk J 《Physical review letters》2012,108(7):077405
We introduce dielectric elliptical photonic nanowires to funnel efficiently the spontaneous emission of an embedded emitter into a single optical mode. Inside a wire with a moderate lateral aspect ratio, the electromagnetic environment is largely dominated by a single guided mode, with a linear polarization oriented along the ellipse major axis. The resulting monomode spontaneous emission is maintained over a broad wavelength range, a key asset of this 1D photonic structure. Our theoretical analysis is completed by an experimental study of GaAs elliptical photonic wires with embedded InAs quantum dots. In particular, the fraction of collected photons with the desired linear polarization can exceed 95%. 相似文献
157.
Kasper S. Pedersen Katie R. Meihaus Andrei Rogalev Fabrice Wilhelm Daniel Aravena Martín Amoza Eliseo Ruiz Jeffrey R. Long Jesper Bendix Rodolphe Clrac 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(44):15797-15801
The first structurally characterized hexafluorido complex of a tetravalent actinide ion, the [UF6]2? anion, is reported in the (NEt4)2[UF6]?2 H2O salt ( 1 ). The weak magnetic response of 1 results from both UIV spin and orbital contributions, as established by combining X‐ray magnetic circular dichroism (XMCD) spectroscopy and bulk magnetization measurements. The spin and orbital moments are virtually identical in magnitude, but opposite in sign, resulting in an almost perfect cancellation, which is corroborated by ab initio calculations. This work constitutes the first experimental demonstration of a seemingly non‐magnetic molecular actinide complex carrying sizable spin and orbital magnetic moments. 相似文献
158.
159.
We consider proper colorings of planar graphs embedded in the annulus, such that vertices on one rim can take Q
s colors, while all remaining vertices can take Q colors. The corresponding chromatic polynomial is related to the partition function of a boundary loop model. Using results
for the latter, the phase diagram of the coloring problem (with real Q and Q
s) is inferred, in the limits of two-dimensional or quasi one-dimensional infinite graphs. We find in particular that the special
role played by Beraha numbers
for the usual chromatic polynomial does not extend to the case Q≠Q
s. The agreement with (scarce) existing numerical results is perfect; further numerical checks are presented here. 相似文献