From noncommutative κ-Minkowski to Minkowski space–time

We show that free κ-Minkowski space field theory, discussed in the context of κ-Poincaré algebra and Doubly Special Relativity is equivalent to a relativistically invariant free field theory on Minkowski space–time. The field theory we obtain has in spectrum a relativistic mode of arbitrary mass m and a Planck mass tachyon. We show that while the energy–momentum for the relativistic mode is essentially the standard one, it diverges for the tachyon, so that there are no asymptotic tachyonic states in the theory. It also follows that the dispersion relation is not modified, so that, in particular, in this theory the speed of light is energy-independent.     

Inheriting independence and chi-squaredness under certain matrix orderings

Let x ～ N(μ, Z), and let S = (Σ:μ). It is shown that if x′A₁x is independent of x′Bx (x′A₁x is distributed as a chi-square variable), then this property is inherited by every x′A₂x for which S′A₂S precedes S′A₁S with respect to the range preordering (with respect to the rank subtractivity partial ordering).     

The cyanide-catalyzed conversion of β-formylmuconates into triglochinates: A useful biomimetic synthesis

Upon treatment with cyanide under slightly basic conditions, β-formyl-cis,cis-muconic acid and esters, prepared from vanillin, undergo a sequence of prototropic shifts equivalent to an internal redox process in which 1,4-reduction of the diene system is blanaced by oxidation of the formyl group.     

The kinetics of tritium-hydrogen exchange between xanthine,theophylline,caffeine and water

Isotopic hydrogen exchange at C-8 of xanthine, theophylline and caffeine in water has been studied at several temperatures and constant pH. The rates of detritiation of these compounds have been determined over a pH range at constant temperature. The rate-pH profiles for theophylline and caffeine are interpreted in terms of rate determining attack by hydroxide ion on protonated substrate. For caffeine and xanthine at high pH an additional mechanism involving hydroxide catalysed exchange of the neutral compound is suggested.     

A tetranuclear 3d-4f single molecule magnet: [CuIILTbIII(hfac)2]2

We report now the first single molecule magnet (SMM) consisting of d-f elements. The present study demonstrates that the synthesis of the d-f polynuclear molecule is a very promising approach to SMMs. (1) The d-f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.     

Exact solution of the Schrödinger equation with a new expansion of anharmonic potential with the use of the supersymmetric quantum mechanics and factorization method

The study involves finding exact eigenvalues of the radial Schrödinger equation for new expansion of the anharmonic potential energy function. All analytical calculations employ the mathematical formalism of the supersymmetric quantum mechanics. The novelty of this study is underlined by the fact that for the first time the recurrence formulas for rovibrational bound energy levels have been derived employing factorization method and algebraic approach. The ground state and the excited states have been determined by means of the hierarchy of the isospectral Hamiltonians. The Riccati nonlinear differential equation with superpotentials has been solved analytically. It has been shown that exact solutions exist when the potential and superpotential parameters satisfy certain supersymmetric constraints. The results obtained can be utilized both in computations of quantum chemistry and theoretical spectroscopy of diatomic molecules.     

Low-birefringence liquid crystal mixtures for photonic liquid crystal fibres application

ABSTRACT

Series of low-birefringence liquid crystal mixtures composed of alkyl alkylbicyclohexyl carbonates and modified mixtures with other compounds have been formulated, their refractive indices and electric permittivity measured upon temperature. They exhibit the ordinary refraction index n_o lower than the refractive index of silica glass in a different range of temperature. This enables to observe in photonic liquid crystal fibres (PLCFs) a change in the light propagation mechanism from photonic band gap guiding to modified total internal reflection at different temperatures. Selected applications of PLCFs are also discussed.     

In silico modeling of functionalized graphene oxide-metal cluster conjugates as Raman probe: Raman activity of pyridine

Functionalized graphene – metal nano-conjugates are used as Raman probes, in recent years, for trace level identification of materials having specific Raman active modes. In the present paper, model Raman probes were modeled through conjugation of Au₄ and Ag₄ clusters with functionalized graphene systems. In silico models of functionalized (5,5)-graphene sheets were designed at the density functional theory (DFT) level through attachments of epoxy, -OH and –NH(CH₃)₂SH/-CONH(CH₃)₂SH groups. Model Raman probes were designed through attachment of Au₄ and Ag₄ clusters to the functional sites. Full geometry optimizations followed by vibrational analysis were carried out to ensure that the designed Raman probes have acceptable geometric characteristics to attach Raman-active molecules to the metal site. Pyridine was used as a test system to investigate the functionality of such model Raman probes through attachment with the metal clusters. It was observed that the chemical effects due to such attachments increase the Raman intensities (RI) of specific Raman modes of pyridine (in-plane symmetric bending (1040 cm^-1) and asymmetric stretch-bend (1634 cm^-1)), which are too weak in the isolated molecule. Furthermore, the suggested in silico system could provide an important model for basic understanding of RI-enhancements of molecules through increase of the size of the metal clusters, as the observed enhancement was found to be dependent on the polarizability of the metal clusters attached to the molecule of interest.     

Analytic monoids and factorization problems

The main goal of this paper is to initiate study of analytic monoids as a general framework for quantitative theory of factorization. So far the latter subject was developed either in concrete settings, for instance in orders of number fields, or abstractly, in an axiomatic way. Some of the abstract approaches are too general to address delicate problems concerning oscillatory nature of the related counting functions, or are too restrictive in the sense that they suffer from the lack of examples except classical ones i.e. the Hilbert monoids of algebraic integers and their products. The notion of an analytic monoid is enough flexible to allow constructions of many other examples, and also ensures sufficiently rich analytic structure. In particular, we construct examples of such monoids with the associated L-functions being products of classical Dirichlet L-functions and L-functions of twisted irreducible unitary cuspidal automorphic representations of \(GL_d({\mathbb {A}}_{\mathbb {Q}})\) satisfying the Ramanujan conjecture and having real coefficients. Finally, to illustrate how a typical problem from the quantitative theory of factorization can be studied in the framework of analytic monoids, we formulate several results concerning oscillations of the remainder term in the asymptotic formula for the number of irreducible elements with norms less or equal x, as x tends to infinity.