全文获取类型
收费全文 | 1681篇 |
免费 | 18篇 |
国内免费 | 22篇 |
专业分类
化学 | 1091篇 |
晶体学 | 15篇 |
力学 | 51篇 |
数学 | 311篇 |
物理学 | 253篇 |
出版年
2022年 | 17篇 |
2021年 | 23篇 |
2020年 | 15篇 |
2019年 | 19篇 |
2018年 | 19篇 |
2017年 | 21篇 |
2016年 | 38篇 |
2015年 | 20篇 |
2014年 | 44篇 |
2013年 | 82篇 |
2012年 | 80篇 |
2011年 | 77篇 |
2010年 | 60篇 |
2009年 | 70篇 |
2008年 | 89篇 |
2007年 | 112篇 |
2006年 | 102篇 |
2005年 | 86篇 |
2004年 | 78篇 |
2003年 | 59篇 |
2002年 | 48篇 |
2001年 | 33篇 |
2000年 | 23篇 |
1999年 | 20篇 |
1998年 | 20篇 |
1997年 | 22篇 |
1996年 | 33篇 |
1995年 | 25篇 |
1994年 | 22篇 |
1993年 | 23篇 |
1992年 | 20篇 |
1991年 | 16篇 |
1990年 | 21篇 |
1989年 | 15篇 |
1988年 | 19篇 |
1987年 | 15篇 |
1986年 | 16篇 |
1985年 | 24篇 |
1984年 | 19篇 |
1983年 | 13篇 |
1982年 | 24篇 |
1981年 | 12篇 |
1980年 | 15篇 |
1979年 | 8篇 |
1978年 | 13篇 |
1977年 | 18篇 |
1976年 | 10篇 |
1975年 | 7篇 |
1974年 | 10篇 |
1965年 | 8篇 |
排序方式: 共有1721条查询结果,搜索用时 0 毫秒
81.
Derrien G Charnay C Zajac J Jones DJ Rozière J 《Chemical communications (Cambridge, England)》2008,(27):3118-3120
Copper-containing mesoporous silica spheres of size in the colloidal range with perfect conservation of pore-ordering, shape and monodispersity and high intra-pore metal dispersion were prepared via a new one-step synthesis and functionalisation route. 相似文献
82.
A theoretical analysis of the concept of lifetime and mean life of unstable elementary particles is presented. New analytic formulas for lifetime and mean life as a function of decay width and the mass of unstable particle are derived for Breit-Wigner and Matthews-Salam energy distributions. It is demonstrated that, for unstable particles with a larger width or decay energy threshold, the deviation from the generally accepted mean life
m =
–1
is significant. The behavior of the decay law P(t) for small times is analyzed, and it is shown that the Breit-Wigner distribution violates the condition P(t = 0) = 0, whereas the Matthews-Salam distribution satisfies it. 相似文献
83.
Christel Laberty Jerzy Pielaszek Pierre Alphonse Abel Rousset 《Solid State Ionics》1998,110(3-4):293-302
Cation deficient spinels NixMn3−x□3δ/4O4+δ (0≤x≤1) have been prepared by thermal decomposition of mixed oxalates Nix/3Mn(3−x)/3(C2O4)·nH2O in air at 623 K. They have been characterised by temperature programmed reduction (TPR) under H2, the reaction being followed by gravimetric and powder X-ray diffraction measurements. It has been shown that TPR proceeds in several steps. The first steps correspond to the loss of nonstoichiometric oxygen leading to the formation of a stoichiometric oxide. During the following stages the manganese cations are reduced, causing the spinel structure to be destroyed, and the formation of solid solution of NiO in a cubic MnO. Subsequently, Ni2+ cations undergo a reduction to metallic nickel, and, finally, a mixture of nonstoichiometric MnO1−δ and metallic nickel is formed. These oxides contain a high level of vacancies which vary with the nickel content with a maximum of δ≈1 near x=0.6. This nonstoichiometry is ascribed both to the presence of Ni3+ and excess of Mn4+. 相似文献
84.
In this paper, we investigate the Sznajd model of opinion dynamics with anticonformity on a complete graph. We show that below some threshold value of anticonformal behavior spontaneous reorientations occur between two stable states. Dealing with a complete graph allows us also for an analytical treatment. We provide analytical calculations both for the infinite and finite systems. We show that opinion dynamics can be understood as a movement of a public opinion in a symmetric bistable effective potential. We focus also on the spontaneous transitions between stable states in the case of the finite system and show that a typical waiting time can be observed. 相似文献
85.
Kamil Kaminski Marian Paluch R. Wrzalik Jerzy Ziolo Radoslav Bogoslovov C. Michael Roland 《Journal of polymer science. Part A, Polymer chemistry》2008,46(11):3795-3801
The polymerization and crosslinking of tetraethylene glycol dimethacrylate were induced by high pressure. The product was analyzed by both swelling experiments and broadband dielectric spectroscopy to determine the structure, with IR measurements used to follow the extent of reaction and its temperature dependence. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 3795–3801, 2008 相似文献
86.
Krystyna Wejroch Jerzy Lange Anna Kielak Janina Karolak‐Wojciechowska Jacek Sonicki Tadeusz Jagodziski 《Journal of heterocyclic chemistry》2001,38(4):877-884
Bis(ethoxycarbonyl)alkylidene derivatives 4 and 5 of the respective title hydrazones were obtained in the reactions with diethyl oxomalonate, diethyl oxosuccinate, diethyl 2‐oxoglutarate, and diethyl oxalo‐propionate as mixtures of geometric isomers with high predominance of one of them. On heating at 160‐200° without any solvent or on refluxing in ethanol 4 cyclized to yield the corresponding pyri‐dazino[6, 1‐c]triazines 6 , whereas heating of 5 gave, depending on the chain length, the corresponding pyra‐zolylpyridazines 8b and 8d or the pyridazinylpyridazine 8c . X‐ray analysis was used to determine the structures of 6 and 8 ; the unit cell of 6c was found to accommodate 16 molecules representing four conforma‐tional varieties. The different behavior of 4 and 5 in the cyclization reactions was interpreted in terms of the tautomeric equilibrium which was shifted towards the enamine form in 4 , and towards the imine form, in 5 . Transmission of a long‐range chirality effect in 4d and 5a‐d manifested itself in the 1H nmr spectra as the magnetic non‐equivalence of the CH2 protons in one or both ester ethyl groups. 相似文献
87.
Maciej Kubicki Teresa Borowiak Jerzy Suwiński Paweł Wagner 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(1):106-108
Crystalline 4-nitro-1-phenylimidazole, C9H7N3O2, (I), and 4′-nitro-1-phenyl-4,1′-biiimidazole, C12H9N5O2, (II), contain C—H⃛O and C—H⃛N hydrogen bonds, connecting the molecules into infinite chains. The aromatic fragments in both compounds are nearly planar. The dihedral angles between the benzene and imidazole rings are 26.78 (5)° in (I) and 29.36 (8)° in (II). 相似文献
88.
Jerzy Siuzdak 《Optical and Quantum Electronics》1986,18(1):23-27
Incoherent light propagation over a folded path in the turbulent atmosphere has been examined using the phase-screen method. Expressions for the variance of the received power have been obtained in the weak turbulence conditions. 相似文献
89.
In the article we undertook the attempt of using the theory of random fields in the analysis of the separation process of particles in non-contiguous systems. The presentation of the complete model is a complicated problem. We can say that this article is start point of the theory, which will be supplemented gradually in the future. The separation process of particles on sieves is a phenomenon with random character. It is a result of random character of cleaned mixture and the nature of the separation process. Undoubtedly, an important part is played by the theory of random fields in which system-events, inherently not determined, are described in undetermined-probabilistic way. However, we can perceive one paradox in such actions – correctly constructed probabilistic models serve to impose deterministic frames on the given random process. We can say that stochastic models generate the matrix of the causal-consecutive dependence, which will give the ability of controlling a given process. 相似文献
90.
Jerzy Dajka 《Entropy (Basel, Switzerland)》2021,23(6)
Quantum ring accommodating interacting spin-less fermions threaded by magnetic flux with a non-classical component added to a static, inducing persistent current, is considered. It is investigated how current flowing in the ring becomes affected by a state of non-classical flux and how Coulomb interaction between fermions influences entanglement of quantum ring and the driving field. In particular it is shown that in an absence of decoherence and under certain conditions fermion–fermion interaction is necessary for a ring–field entanglement to occur. 相似文献