Growth and characterization of borono phenylalanine

Borono phenylalanine abbreviated as BPA is a biologically important compound which is obtained from L‐Phenylalanine (C₉H₁₁NO₂) in which a boron atom is bonded. BPA is an amino acid analogue, helpful in the treatment of glioblastoma multiforme, a highly malignant form of brain tumor is crystallized in silica gel under pH 6.0 by single diffusion method in a period of 30 minutes. The grown crystals were characterized by x‐ray powder diffraction, Fourier Transform infrared spectroscopy and visible ultraviolet spectroscopy. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Palladium Aryl Sulfonate Phosphine Catalysts for the Copolymerization of Acrylates with Ethene

The reaction of 2‐[bis(2‐methoxy‐phenyl)phosphanyl]‐4‐methyl‐benzenesulfonic acid (a) and 2‐[bis(2′,6′‐dimethoxybiphenyl‐2‐yl)phosphanyl]benzenesulfonic acid (b) with dimethyl(N,N,N′,N′‐tetramethylethylenediamine)‐palladium(II) (PdMe₂(TMEDA)) leads to the formation of TMEDA bridged palladium based polymerization catalysts ( 1a and 1b ). Upon reaction with pyridine, two mononuclear catalysts are formed ( 2a and 2b ). These catalysts are able to homopolymerize ethylene and also copolymerize ethylene with acrylates or with norbornenes. With ligand b , high molecular weight polymers are formed in high yields, but higher comonomer incorporations are obtained with ligand a .

     

Computational models for the numerical simulation of voltage operated channels in nano–bio–electronics

In this article, we discuss the use of computational models in the study of voltage operated channels (VOCs) for bio-electronic applications. Electrochemical and fluid–mechanical ionic transport are described through the coupled use of systems of partial and ordinary differential equations (PDEs and ODEs). Functional iteration techniques for system decoupling and mixed–hybridized finite element discretization methods are proposed and validated in the simulation of realistic problems in Electrophysiology and Biochemistry. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Canady Cold Helios Plasma Reduces Soft Tissue Sarcoma Viability by Inhibiting Proliferation,Disrupting Cell Cycle,and Inducing Apoptosis: A Preliminary Report

Soft tissue sarcomas (STS) are a rare and highly heterogeneous group of solid tumors, originating from various types of connective tissue. Complete removal of STS by surgery is challenging due to the anatomical location of the tumor, which results in tumor recurrence. Additionally, current polychemotherapeutic regimens are highly toxic with no rational survival benefit. Cold atmospheric plasma (CAP) is a novel technology that has demonstrated immense cancer therapeutic potential. Canady Cold Helios Plasma (CHCP) is a device that sprays CAP along the surgical margins to eradicate residual cancer cells after tumor resection. This preliminary study was conducted in vitro prior to in vivo testing in a humanitarian compassionate use case study and an FDA-approved phase 1 clinical trial (IDE G190165). In this study, the authors evaluate the efficacy of CHCP across multiple STS cell lines. CHCP treatment reduced the viability of four different STS cell lines (i.e., fibrosarcoma, synovial sarcoma, rhabdomyosarcoma, and liposarcoma) in a dose-dependent manner by inhibiting proliferation, disrupting cell cycle, and inducing apoptosis-like cell death.     

Effect of oxygen enrichment on CI engine behavior fueled with vegetable oil: an experimental study

Journal of Thermal Analysis and Calorimetry - The present study investigated the effect of oxygen enrichment in a CI engine on performance, emission and combustion characteristics with mahua oil...     

Ab-initio heats of formation of medium-sized hydrocarbons. 4. Perhydrotriquinacene

The ΔH_f of perhydrotriquinacene is obtained from that of adamantane and their enthalpy of isomerization computed by ab initio SCF methods, with corrections for zero-point and thermal effects.     

Approximate Newton methods and homotopy for stationary operator equations

A quadratically convergent algorithm based on a Newton-type iteration is defined to approximate roots of operator equations in Banach spaces. Fréchet derivative operator invertibility is not required; approximate right inverses are used in a neighborhood of the root. This result, which requires an initially small residual, is sufficiently robust to yield existence; it may be viewed as a generalized version of the Kantorovich theorem. A second algorithm, based on continuation via single, Euler-predictor-Newton-corrector iterates, is also presented. It has the merit of controlling the residual until the homotopy terminates, at which point the first algorithm applies. This method is capable of yielding existence of a solution curve as well. An application is given for operators described by compact perturbations of the identity.     

A local normal form theorem for infinitary logic with unary quantifiers

We prove a local normal form theorem of the Gaifman type for the infinitary logic L_∞ω( Q _u)^ω whose formulas involve arbitrary unary quantifiers but finite quantifier rank. We use a local Ehrenfeucht‐Fraïssé type game similar to the one in [9]. A consequence is that every sentence of L_∞ω( Q _u)^ω of quantifier rank n is equivalent to an infinite Boolean combination of sentences of the form (?^≥iy)ψ(y), where ψ(y) has counting quantifiers restricted to the (2^n–1 – 1)‐neighborhood of y. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)