Problems for Broome’s Cognitivist Account of Instrumental Reasoning

In this paper, I examine an account of instrumental reasoning recently put forth by John Broome. His key suggestion is that anyone who engages in reasoning about his intentions also believes that he will do what he intends to do and that combined with a belief about necessary means this creates rational pressure towards believing that one will take the necessary means. I argue that Broome’s model has three significant problems; his key premise is false—the sincere expression of an intention does not entail the belief that one will successfully execute that intention; his account yields a model of instrumental reasoning that is uncomfortably reflective; he seems unable to explain the rational pressure towards taking necessary means that arises directly from having an end and an instrumental belief. All three problems, I argue, are a consequence of Broome’s inadequate position on what it is to intend to do something.     

Understanding the role of the teacher in emerging classroom practices: searching for patterns of participation

The relationship between acquisitionism and participationism is a challenge in research on and with teachers. This study uses a patterns-of-participation framework (PoP), which aims to develop coherent and dynamic understandings of teaching as well as to meet the conceptual and methodological problems of other approaches. The paper presents PoP theoretically, but also illustrates its empirical use. It presents a novice teacher, Anna, who often engages with mathematics and with aspects of ‘the reform’ in ways that link well with how she builds relationships with her students and positions herself in her team of teachers. However, in other situations her engagement with mathematics is overshadowed by her involvement in other practices. The study suggests that there is some potential in PoP in spite of methodological difficulties.     

Physical aging of molecular glasses studied by a device allowing for rapid thermal equilibration

Aging to the equilibrium liquid state of organic glasses is studied. The glasses were prepared by cooling the liquid to temperatures just below the glass transition. Aging following a temperature jump was studied by measuring the dielectric loss at a fixed frequency using a microregulator in which temperature is controlled by means of a Peltier element. Compared to conventional equipment, the new device adds almost two orders of magnitude to the span of observable aging times. Data for the following five glass-forming liquids are presented: dibutyl phthalate, diethyl phthalate, 2,3-epoxy propyl-phenyl-ether, 5-polyphenyl-ether, and triphenyl phosphite. The aging data were analyzed using the Tool-Narayanaswamy formalism. The following features are found for all five liquids: (1) The liquid has an "internal clock," a fact that is established by showing that aging is controlled by the same material time that controls the dielectric properties. (2) There are no so-called expansion gaps between the long-time limits of the relaxation rates following up and down jumps to the same temperature. (3) At long times, the structural relaxation appears to follow a simple exponential decay. (4) For small temperature steps, the rate of the long-time exponential structural relaxation is identical to that of the long-time decay of the dipole autocorrelation function.     

Cluster-support interactions and morphology of MoS2 nanoclusters in a graphite-supported hydrotreating model catalyst

Supported MoS(2) nanoparticles constitute the active component of the important hydrotreating catalysts used for industrial upgrading and purification of the oil feedstock for the production of fossil fuels with a low environmental load. We have synthesized and studied a model system of the hydrotreating catalyst consisting of MoS(2) nanoclusters supported on a graphite surface in order to resolve a number of very fundamental questions related to the atomic-scale structure and morphology of the active clusters and in particular the effect of a substrate used in some types of hydrotreating catalysts. Scanning tunneling microscopy (STM) is used to image the atomic-scale structure of graphite-supported MoS(2) nanoclusters in real space. It is found that the pristine graphite (0001) surface does not support a high dispersion of MoS(2), but by introducing a small density of defects in the surface, highly dispersed MoS(2) nanoclusters could be synthesized on the graphite. From high-resolution STM images it is found that MoS(2) nanoclusters synthesized at low temperature in a sulfiding atmosphere preferentially grow as single-layer clusters, whereas clusters synthesized at 1200 K grow as multilayer slabs oriented with the MoS(2)(0001) basal plane parallel to the graphite surface. The morphology of both single-layer and multilayer MoS(2) nanoclusters is found to be preferentially hexagonal, and atom-resolved images of the top facet of the clusters provide new atomic-scale information on the MoS(2)-HOPG bonding. The structure of the two types of catalytically interesting edges terminating the hexagonal MoS(2) nanoclusters is also resolved in atomic detail in STM images, and from these images it is possible to reveal the atomic structure of both edges and the location and coverage of sulfur and hydrogen adsorbates.     

What is a ‘gel’?

Some of the existing definitions of the term ‘gel’ are discussed and shortcomings are identified. A purely phenomenological definition is proposed: a gel is a soft, solid or solid-like material consisting of two or more components one of which is a liquid, present in substantial quantity. ‘Solid-like gels’ are further defined in terms of the dynamic mechanical properties.     

Neue Unbestimmtheitseigenschaften des elektromagnetischen Feldes

Zeitschrift für Physik A Hadrons and nuclei - Aus der Betrachtung einer Ausmessung elektromagnetischer Felder durch ein einzelnes Elektron (Proton) als Probekörper werden gewisse...