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921.
We investigated the internal dynamics of an electro-fluid shuttle memory element, consisting of K+@C60 and F−@C60 encapsulated in a C640 nanocapsule. Energetics and operating responses of bipolar endo-fullerenes shuttle memory device, (K+@C60–F−@C60)@C640, were examined by classical molecular dynamics simulations under the external force fields. 相似文献
922.
Using the first-principles methods we compute the electronic structure and the absorption spectra for a wurtzite CdSe (0001) slab covered with zincblende ZnSe and ZnS epilayers. For each structure we compute the DOS and the imaginary part of the dielectric function. We find that the semiconductor passivation shifts the ‘near Fermi-level’ states of the bare CdSe slab down to lower energy levels. The migration suggests the decrease of surface effects and energy loss. We observe the substantial reduction of the abnormal peaks in the absorption spectra of the bare CdSe slab, which seems to be a consequence of the DOS migration. This is consistent with the experimental results that a proper passivation enhance the luminescence efficiency. We also study the case that the epilayer surface is terminated with PH3 and find the PH3 passivation also reduces the surface state to some extent. 相似文献
923.
Jaemin Lee Byung‐Jun Jung Sang Kyu Lee Jeong‐Ik Lee Hoon‐Je Cho Hong‐Ku Shim 《Journal of polymer science. Part A, Polymer chemistry》2005,43(9):1845-1857
We report here the synthesis via Suzuki polymerization of two novel alternating polymers containing 9,9‐dioctylfluorene and electron‐withdrawing 4,4′‐dihexyl‐2,2′‐bithiazole moieties, poly[(4,4′‐dihexyl‐2,2′‐bithiazole‐5,5′‐diyl)‐alt‐(9,9‐dioctylfluorene‐2,7‐diyl)] (PHBTzF) and poly[(5,5′‐bis(2″‐thienyl)‐4,4′‐dihexyl‐2,2′‐bithiazole‐5″,5″‐diyl)‐alt‐(9,9‐dioctylfluorene‐2,7‐diyl)] (PTHBTzTF), and their application to electronic devices. The ultraviolet–visible absorption maxima of films of PHBTzF and PTHBTzTF were 413 and 471 nm, respectively, and the photoluminescence maxima were 513 and 590 nm, respectively. Cyclic voltammetry experiment showed an improvement in the n‐doping stability of the polymers and a reduction of their lowest unoccupied molecular orbital energy levels as a result of bithiazole in the polymers' main chain. The highest occupied molecular orbital energy levels of the polymers were ?5.85 eV for PHBTzF and ?5.53 eV for PTHBTzTF. Conventional polymeric light‐emitting‐diode devices were fabricated in the ITO/PEDOT:PSS/polymer/Ca/Al configuration [where ITO is indium tin oxide and PEDOT:PSS is poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonic acid)] with the two polymers as emitting layers. The PHBTzF device exhibited a maximum luminance of 210 cd/m2 and a turn‐on voltage of 9.4 V, whereas the PTHBTzTF device exhibited a maximum luminance of 1840 cd/m2 and a turn‐on voltage of 5.4 V. In addition, a preliminary organic solar‐cell device with the ITO/PEDOT:PSS/(PTHBTzTF + C60)/Ca/Al configuration (where C60 is fullerene) was also fabricated. Under 100 mW/cm2 of air mass 1.5 white‐light illumination, the device produced an open‐circuit voltage of 0.76 V and a short‐circuit current of 1.70 mA/cm2. The fill factor of the device was 0.40, and the power conversion efficiency was 0.52%. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1845–1857, 2005 相似文献
924.
Microwave-assisted synthesis and electrochemical capacitance of polyaniline/multi-wall carbon nanotubes composite 总被引:1,自引:0,他引:1
Hongyu Mi Xiaogang Zhang Shuying An Xiangguo Ye Sudong Yang 《Electrochemistry communications》2007,9(12):2859-2862
Polyaniline/multi-wall carbon nanotubes composite (PANI/MWNTs) was rapidly synthesized by microwave-assisted polymerization. Transmission electron microscope (TEM) image revealed that this composite was a core–shell structure with PANI layers (50–70 nm). Electrochemical behavior of the composite was evaluated by cyclic voltammetry (CV) and galvanostatic charge–discharge tests with a two-electrode system. An enhanced specific capacitance of 322 F/g with a specific energy density of 22 W h/kg was about 12 times that of MWNTs. This composite also exhibited a good rate capability, retaining up to 87% of initial capacity at a current density of 5 mA/cm2. 相似文献
925.
给水加热型联合循环的变工况性能 总被引:3,自引:0,他引:3
在联合循环改造的各种方案中,给水加热型具有投资少、改动少、耗用优质燃料较少、尤其是简单易行及技术难度小等特点,因此在我国现有的技术经济水平、特别是以煤为主的国情下,有一定应用市场。本文分析比较了多种变工况运行方式的性能及可能出现的问题,并在此基础上提出综合性能较好的运行模式。 相似文献
926.
Sang Eun Shim Sunhye Yang Hyang Hee Choi Soonja Choe 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):835-845
Fully crosslinked, stable poly(styrene‐co‐divinylbenzene) microspheres, which are composed of various concentrations of divilylbenzene from 5 to 75 mol % based on styrene monomer, were prepared without a significant particle coagulation by the precipitation polymerization. The number‐average particle diameter ranged from 3.5 to 2.8 μm and decreased with an increasing concentration of divinylbenzene in monomer. In addition, the coefficient of variation of the microspheres was slightly reduced with the increasing concentration of divinylbenzene. The circularity and the measured specific surface area indicated that lesser particles are coagulated because of the improved stability of individual particles at a high divinylbenzene concentration and that the resulting particles have a smooth surface without micropores. The glass‐transition temperature was not observed for all microspheres formed from the range of divinylbenzene concentrations. In addition, the onset of the thermal‐degradation temperature was increased from 339.8 to 376.9 °C upon higher contents of divinylbenzene. On the basis of the DSC and thermogravimetric data, the polymer microspheres prepared by the precipitation polymerization possessed a fully crosslinked structure and highly enhanced thermal stability. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 835–845, 2004 相似文献
927.
Layered γ-Zirconium phosphate (γ-ZrP) preintercalated with butylamine,tetra(n-butylammonium)hydroxide,dimethylamine respectively,or only ultrasonificated,for preparation of immobilized hemoglobin were in vestigated in this report. 相似文献
928.
929.
The dependence of the cold driving potential on the deformation of the incoming target and projectile is investigated in the case of the synthesis of the superheavy nuclei 256No, 286112, 292114, 296116, and 306122. The occurrence of valleys in the driving potential as a function on the interfragment distance and the mass asymmetry is studied for different fixed orientations of the colliding nuclei such as the pole-pole, pole-equator, equator-equator, and equator-equator-crossed and compared to the case when the nuclei are assumed to be spherical or when the potential is averaged over the orientation. 相似文献
930.
The paper is devoted to the investigation of the electron cyclotron resonance (ECR) discharge in the decreasing magnetic field in the pressure range from 0.02 Pa to 90 Pa and the absorbed microwave power from 50 W to 400 W. For a discharge characterization we used the floating potentialU
fl and the saturated ion current densityi
sat
+
. The influence of the substrate holder presence on the plasma microparameters was studied. It was shown that for the substrate holder located near ECR at pressures below 0.3 Pa mainly the magnitude ofU
fl strongly depends on the pressurep, the absorbed microwave powerP
a, and the position of the substrate holder with respect to ECR. The values ofU
fl in the plasma in which the substrate holder is inserted strongly differ from those in the plasma without the substrate holder.U
fl of low pressuresp<0.05 Pa achieves high positive values of about +50 V and this results in sputtering of chamber walls. 相似文献