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121.
122.
K E Jensen T Grube C Thomsen P G S?rensen P Christoffersen H Karle O Henriksen 《Magnetic resonance imaging》1988,6(3):291-292
In vitro as well as in vivo studies have shown prolonged T1 relaxation times in patients with acute leukemia. The mechanism behind this finding is not known. In order to evaluate if this was specific for leukemia we examined eight patients with polycythemia vera, representing a condition with a rather benign bone marrow neoplasia. In this group of patients we found prolonged T1 relaxation times but normal T2 relaxation times. This may indicate that the prolonged T1 relaxation time seen in leukemic bone marrow is not due to the malignant cell per se. 相似文献
123.
Frontispiece: Enantioselective Organocatalytic Cascade Approach to Different Classes of Benzofused Acetals
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124.
125.
C. R.H. Bahl J. Garde K. Lefmann T. B.S. Jensen P.-A. Lindgård D. E. Madsen S. Mørup 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(1):53-57
In magnetic nanoparticles the uniform precession
(q = 0 spin wave) mode gives the predominant contribution
to the magnetic excitations. We have calculated the energy of the
uniform mode in antiferromagnetic nanoparticles with uncompensated
magnetic moments, using the coherent potential approximation. In
the presence of uncompensated moments, an antiferromagnetic
nanoparticle must be considered as a kind of a ferrimagnet. Two
magnetic anisotropy terms are considered, a planar term confining
the spins to the basal plane, and an axial term determining an
easy axis in this plane. Excitation energies are calculated for
various combinations of these two anisotropy terms, ranging from
the simple uniaxial case to the planar case with a strong
out-of-plane anisotropy. In the simple uniaxial case, the
uncompensated moment has a large influence on the excitation
energy, but in the planar case it is much less important. The
calculations explain recent neutron scattering measurements on
nanoparticles of antiferromagnetic α-Fe2O3 and NiO. 相似文献
126.
Robert Jensen Maciej Kocan Andrzej Swiech 《Proceedings of the American Mathematical Society》2002,130(2):533-542
We introduce the notion of a ``good" solution of a fully nonlinear uniformly elliptic equation. It is proven that ``good" solutions are equivalent to -viscosity solutions of such equations. The main contribution of the paper is an explicit construction of elliptic equations with strong solutions that approximate any given fully nonlinear uniformly elliptic equation and its -viscosity solution. The results also extend some results about ``good" solutions of linear equations.
127.
R.D. SuenramF.J. Lovas D.F. PlusquellicA. Lesarri Y. KawashimaJ.O. Jensen A.C. Samuels 《Journal of Molecular Spectroscopy》2002,211(1):110-118
The rotational spectrum of dimethyl methylphosphonate (DMMP) has been studied using a pulsed molecular beam Fourier transform microwave spectrometer. The spectrum is complicated by the internal rotation motions of the three methyl tops in the molecule as well as an interconversion motion of the two methoxy groups. Here, we present the microwave spectrum, the ab initio calculations, and the assignment of the rigid-rotor A-symmetry state of the molecule. The rotational constants for this state are A=2828.753(2) MHz, B=1972.360(3) MHz, and C=1614.267(2) MHz. In the following paper, a group theoretical analysis is developed for DMMP. The observed conformation of the molecule has no point-group symmetry and all three electric-dipole selection rules are active, with c-type transitions being the most intense. Ab initio calculations were carried out at both the Hartree-Fock 6-31G* and MP2/6-311G* levels of theory. These calculations indicate that two low-energy conformations are possible separated by energies of less than 170 cm−1. Furthermore, the calculated lowest energy conformer is in agreement with the one observed experimentally. The relative energies of the two low-energy conformers rise from 34 cm−1 at the HF level to 170 cm−1 at the MP2 level. 相似文献
128.
Renz M Blasco T Corma A Fornés V Jensen R Nemeth L 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(20):4708-4717
Sn-Beta is used as a heterogeneous catalyst for the Baeyer-Villiger reaction with hydrogen peroxide. Cyclic ketones are transformed into the corresponding lactones, while unsaturated ketones are oxidized to the corresponding unsaturated lactones with very high chemoselectivity. The catalyst is also selective for the oxidation of aromatic aldehydes with H2O2, producing the formate ester or the corresponding hydrolyzed product, that is the alcohol. Shape-selective oxidations are observed for isomeric reactants with different molecular shapes. The catalytic Sn sites have been characterized by 119Sn MAS-NMR spectroscopy, and tetrahedral incorporation into the zeolite framework has been demonstrated. In situ IR spectroscopy and 18O labeling experiments have shown that the oxidation mechanism involves an intermediate of the Criegee type. 相似文献
129.
Li W Nelson DP Jensen MS Hoerrner RS Cai D Larsen RD Reider PJ 《The Journal of organic chemistry》2002,67(15):5394-5397
3-Pyridylboronic acid was prepared in high yield and bulk quantity from 3-bromopyridine via a protocol of lithium-halogen exchange and "in situ quench". This technique was further studied and evaluated on other aryl halides in the preparation of arylboronic acids. 相似文献
130.
The established rates of glycoside hydrolysis reactions were analyzed using free energy relationship plots based on substituent constants that depend on whether the substituent is axial or equatorial. In all cases good correlations were found when assuming either that the transition state had a charged ring-oxygen atom or that it had a charged anomeric carbon atom. The spontaneous hydrolysis of 2,4-dinitrophenyl beta-glycopyranosides and the acidic hydrolysis of methyl beta-D-glycopyranosides were found to give a good correlation, when 100% charge at the ring-oxygen in the transition state of these reactions is assumed. The acidic hydrolysis of methyl alpha-glycopyranosides was found to give good correlations regardless of whether 100% charge at the ring-oxygen or 100% charge at the anomeric carbon was assumed. The findings clearly demonstrate how crucial the stereochemistry of even remote polar substituents is for their electronic effect on chemical reaction. 相似文献