Necessary Conditions for Differentiability of Distance Functions

Necessary conditions for the Gâteaux differentiability of the distance function to a set are considered. A series of characterizing results is obtained.     

Solving the problem of contact equilibrium of a punch and an elastic body

The variational problem of contact equilibrium of a punch and an elastic body is considered. An equivalent formulation of the problem is given in variational inequality form. Existence and uniqueness of the solution is investigated in a particular case. A penalty method is proposed for approximate solution of the problem.Translated from Vychislitel'naya i Prikladnaya Matematika, No. 56, pp. 97–103, 1985.     

Reaction of methyl bromopropiolate with diamines as a method of synthesis of imidazolidine derivatives

A convenient method of synthesis of 2-(methoxycarbonylmethylene)-substituted imidazolidines and imidazolidinium bromides, and also of bicyclic diazo compounds has been developed starting from methyl bromopropiolate and ethylenediamine and its derivatives.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1205–1208, September, 1991.     

Error analysis: a tool for selecting travel demand models

In developing travel demand models it is generally assumed that the base-year data used in developing the parameters, as well as the forecasted data to be used as independent variables for the design year, are of acceptable quality. The purpose of this paper is to present the application of error propagation theory in assesing the predictive quality of one type of travel demand forecasting model (multinomial logit models) and to demonstrate how error considerations can be used as a tool for identifying the optimal model. The general conclusions of this study are that: (1) it is indeed possible to quantify errors in dependent variables in logit models as a consequence of errors in independent variables; and (2) error consideration can be used as a tool for identifying the optimal model from a set of candidate models. Further research is recommended to develop better insights into the phenomenon of error propagation so that the consideration of errors can be a factor in decisions on model selection.     

General strategy for a short and efficient synthesis of 3-hydroxy-4-methylprolines (HMP)

The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy.     

Stereocontrolled spirocyclic bislactams derived from pyroglutamic acid

The synthesis of rigid spirocyclic bislactams derived from pyroglutamic acid has been established.     

Standard enthalpy of formation of La2CoO4(cr)

The enthalpies of reactions of La₂CoO₄(cr) and CoCl₂(cr) with hydrochloric acid were measured with an isothermal-jacket calorimeter. The results obtained and the available literature data were used to calculate the standard enthalpy of formation of La₂CoO₄(cr) at 298.15 K, Δ_f H ^o = ?2179 ± 7 kJ/mol.     

On construction of symmetries from integrals of hyperbolic partial differential systems

An algorithm is proposed which allows one to construct higher symmetries of arbitrary order for some special classes of hyperbolic systems possessing integrals. The Pohlmeyer-Lund-Regge system and the open two-dimensional Toda lattices are shown to belong to the class of systems where our algorithm is applicable. __________ Translated from Fundamental’naya i Prikladnaya Matematika (Fundamental and Applied Mathematics), Vol. 10, No. 1, Geometry of Integrable Models, 2004.