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61.
The crystal and molecular structure of 3-methoxy-estra-1,3,5(10)-triene-14β,17β-diol has been determined by single crystal X-ray analysis. It crystallizes in the orthorhombic space group P212121 with cell parameters a = 8.965(2), b = 30.520(7), and c = 6.031(2) A. The structure was solved by the POSIT system and refined by least-squares calculations to the conventional R factor of 0.075. The steroid rings A, B, and C have planar, 7α, 8β-half chair, and chair conformations, respectively. The ring D is intermediate between 13α, 14β-half chair and 13α-envelope. Rings B and C are trans-fused, and rings C and D are cis-fused. There are intra- as well as intermolecular hydrogen bonds between both hydroxyl groups of the steroid molecule. 相似文献
62.
Electron transport through molecular quantum dots coupled to a single vibrational mode is studied in the Kondo regime. We apply a generalized Schrieffer-Wolff transformation to determine the effective low-energy spin-spin-vibron interaction. From this model we calculate the nonlinear conductance and find Kondo sidebands located at bias voltages equal to multiples of the vibron frequency. Because of selection rules, the side peaks are found to have strong gate-voltage dependences, which can be tested experimentally. In the limit of weak electron-vibron coupling, we employ a perturbative renormalization group scheme to calculate analytically the nonlinear conductance. 相似文献
63.
Stanislas Vertu Jens Flügge Jean-Jacques Delaunay Olivier Haeberlé 《Central European Journal of Physics》2011,9(4):969-974
Tomographic Diffractive Microscopy is a technique, which permits to image transparent living specimens in three dimensions
without staining. It is commonly implemented in two configurations, by either rotating the sample illumination keeping the
specimen fixed, or by rotating the sample using a fixed illumination. Under the first-order Born approximation, the volume
of the frequency domain that can be mapped with the rotating illumination method has the shape of a “doughnut”, which exhibits
a so-called “missing cone” of non-captured frequencies, responsible for the strong resolution anisotropy characteristic of
transmission microscopes. When rotating the sample, the resolution is almost isotropic, but the set of captured frequencies
still exhibits a missing part, the shape of which resembles that of an apple core. Furthermore, its maximal extension is reduced
compared to tomography with rotating illumination. We propose various configurations for tomographic diffractive microscopy,
which combine both approaches, and aim at obtaining a high and isotropic resolution. We illustrate with simulations the expected imaging performances of these configurations. 相似文献
64.
Stutzki F Jansen F Eidam T Steinmetz A Jauregui C Limpert J Tünnermann A 《Optics letters》2011,36(5):689-691
Ytterbium-doped large-pitch fibers with very large mode areas are investigated in a high-power fiber amplifier configuration. An average output power of 294?W is demonstrated, while maintaining robust single-mode operation with a mode field diameter of 62?μm. Compared to previous active large-mode area designs, the threshold of mode instabilities is increased by a factor of about 3. 相似文献
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Panse S Dong L Burian A Carus R Schutkowski M Reimer U Schneider-Mergener J 《Molecular diversity》2004,8(3):291-299
Kinases represent one of the largest enzyme families and key regulatory proteins in the cell. Only a small subset of these enzymes has been characterised so far. We have prepared different types of phosphopeptide and peptide microarrays displaying peptides deduced from annotated human phosphorylation sites and cytoplasmic domains of all annotated human membrane proteins. This approach was enabled by fully-automated high throughput micro-scale synthesis of peptides by the SPOT technology combined with chemo-selective immobilisation on modified glass slides. The phosphopeptide microarrays displaying 2923 peptides in total have been used for the characterisation of commercially available generic anti-phosphopeptide antibodies. This enabled us to detect Abl kinase activity on a microarray with anti-phosphotyrosine antibodies yielding results comparable to those obtained from a radioactive assay. More than 13 000 peptides deposited on six glass slides were used to profile casein kinase 2 (CK2) using a radioactive assay, since no generic antibody for the reliable detection of serine or threonine phosphorylation could be identified. All previously identified substrates were detected in the microarray experiment. In order to confirm whether substrates on the microarray are substrates in solution phase assays, more than 700 peptides were synthesised and tested with CK2 in a solution phase assay. All substrates identified in the solution phase assay were also detected on the microarray. 相似文献
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Dr. Tihomir Solomun Dr. Marc Benjamin Hahn Priv.-Doz. Dr. Jens Smiatek 《Chemphyschem》2020,21(17):1945-1950
Recent crystallographic results revealed conformational changes of zwitterionic ectoine upon hydration. By means of confocal Raman spectroscopy and density functional theory calculations, we present a detailed study of this transformation process as part of a Fermi resonance analysis. The corresponding findings highlight that all resonant couplings are lifted upon exposure to water vapor as a consequence of molecular binding processes. The importance of the involved molecular groups for water binding and conformational changes upon hydration is discussed. Our approach further shows that the underlying rapid process can be reversed by carbon dioxide saturated atmospheres. For the first time, we also confirm that the conformational state of ectoine in aqueous bulk solution coincides with crystalline ectoine in its dihydrate state, thereby highlighting the important role of a few bound water molecules. 相似文献
70.
Mean field calculations of the Peierls instability have been carried out for arbitrary bandfilling both in the case of free electrons as well as for the tightbinding approximation. New expressions for Δ(0) and Tp are derived which change the experimentally derived λ to a more reasonable value. Δ(0)/kBTp may differ significantly from the BCS value 1.76 in the tightbinding approximation. 相似文献