低频室内声散射计算机模拟方法

近年来,声散射的模拟成为室内声场计算机模拟研究的重点。现有的方法一般是依据壁面性质(结构、粗糙度等),利用经验确定散射系数,并基于该系数来模拟室内散射声能的分布。这种方法在低频情况下的精度较差,主要原因是忽略了在低频声场中起重要作用的波动现象。为此,本文提出一种新的计算壁面散射的模型,该模型既可考虑壁面上产生的散射声能,又可计算因壁面边缘衍射而产生的散射声能。文中通过模拟和实测数据的对比,分析验证了该模型的有效性,并给出了表面散射系数的取值规则。     

Coherent underwater communication using passive time reversal over multipath channels

Passive time reversal exploits underwater acoustic channels’ spatial and temporal diversity. It can refocus multipath propagated signal at the receiver and can be realized simply by the passive phase conjugation (PPC) method. By the temporal focusing, time delay spread caused by multipath propagation is mitigated for spectral efficient coherent communications. However, the PPC method is unable to eliminate multipath and is limited by channel variations. An adaptive equalizer is therefore needed to compensate residual multipath after refocusing and to track channel temporal variations. Spatial diversity is obtained by using a vertical receiving array. In this paper we used 4-hydrophone array and demonstrated that the adaptive decision feedback equalization in conjunction with PPC significantly decreased the bit error rate.     

New approaches for a light scattering Internet information portal and categorization schemes for light scattering software

Light scattering is important in a number of scientific fields and thus the efficient collation and exchange of this information becomes essential. The Internet allows information to be easily shared but the required content may be distributed over a number of web pages and thus may be difficult to locate using standard search engines.In this paper the current state of the development of a new light scattering Internet information portal is described. The upcoming technical realization for the web pages as well as the benefits for the users is outlined. One of the key features of the portal will be the comprehensive list of light scattering programs. For this also approaches to categorize light scattering software are investigated. This can help to develop search tools enabling scientists to find the best fitting program to their scattering problem.     

Strontium d‐glutamate hexa­hydrate and strontium di(hydrogen l‐glutamate) penta­hydrate

[Sr(C₅H₇NO₄)]·6H₂O, (I), and [Sr(C₅H₈NO₄)₂]·5H₂O, (II), both crystallize with similar strontium–glutamate–water layers. In (I), the neutral layers are connected through hydrogen bonds by water mol­ecules, while in (II), the positively charged layers are connected through hydrogen bonds and electrostatic inter­actions by inter­leaving layers of hydrogen glutamate anions and water mol­ecules.     

Large N‐Heteroacenes: New Tricks for Very Old Dogs?

Azaacenes have been known for a very long time, either as N,N′‐dihydro compounds or in their oxidized form as 4 n+2π systems, but only recently have processable and charcterizable derivatives been sought. In the last three years synthetic routes to large N‐heteroacenes have been developed. In particular, the Pd‐catalyzed coupling of aromatic diamines with activated aromatic dihalogenides has enabled simple access to numerous new azaacenes. Since 2010, azapentacene and stabile oligoazahexacene have been synthesized, as well as a symmetrical tetraazapentacene, which acts as an excellent electron‐transport material for thin‐film transistors.     

Validation of a simple liquid chromatographic method for determination and quantitation of residual ivermectin and doramectin in pig liver

A rapid and quantitative method for the extraction, derivatization, and liquid chromatography with fluorescence detection of ivermectin (IVM) and doramectin (DOM) residues in porcine liver was developed and validated. IVM and DOM were extracted from the liver samples with acetonitrile, the supernatant was evaporated to dryness at 37 degrees C under nitrogen, and the residue was reconstituted in 1-methylimidazole solution. After 2 min at room temperature, IVM and DOM were converted to a fluorescent derivative and then separated on a Hypersil ODS column. The derivatives of IVM and DOM were detected and quantitated with high specificity by fluorescence (excitation: 365 nm, emission: 475 nm). Abamectin was used as an internal standard. The mean extraction efficiencies from fortified samples (15 ng/g) were 75% for IVM and 70% for DOM. The limit of detection was 0.8 ng/g for both IVM and DOM.     

Evaluation of a high-resolution time-of-flight mass spectrometer for the gas chromatographic determination of selected environmental contaminants

A benchtop high-resolution time-of-flight mass spectrometer (TOF MS) was evaluated for the determination of key organic microcontaminants. The major advantage of the TOF MS proved to be the high mass resolution of about 0.002 Da (10 ppm). Consequently, the detectability of polar pesticides, polynuclear aromatic hydrocarbons and polychlorinated biphenyls is excellent, and detection limits are in the order of 1–4 pg injected mass. Best mass spectral resolution was obtained for medium-scale peaks. It is a disadvantage that the calibration range is rather limited, viz. to about two orders of magnitude. The high mass spectral resolution was especially useful to improve the selectivity and sensitivity when analyzing target compounds in complex samples and to prevent false-positive identifications.