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111.
Buha J Arčon D Niederberger M Djerdj I 《Physical chemistry chemical physics : PCCP》2010,12(47):15537-15543
A simple route to niobium, hafnium and tantalum oxide nanocrystals using a nonaqueous sol-gel route based on the solvothermal reaction of the corresponding metal chlorides with benzyl alcohol is presented. This approach can easily be extended to the preparation of high quality Co-doped HfO(2) nanoparticles of uniform size and shape and with a homogenous distribution of the magnetic ions. The structural characterization of all these nanomaterials as well as the magnetic properties of pure and doped hafnia, with special attention to the doping efficiency, are discussed. The obtained Co-doped hafnia exhibits paramagnetic properties with very weak antiferromagnetic interactions between Co ions moments. 相似文献
112.
Tatjana M. Trtić‐Petrović Ksenija R. Kumrić Jelena S. Đorđević Goran T. Vladisavljević 《Journal of separation science》2010,33(13):2002-2009
Transport behaviour of Lu(III) across a polypropylene hollow fibre‐supported liquid membrane containing di(2‐ethylhexyl)phosphoric acid (DEHPA) in dihexyl ether as a carrier has been studied. The donor phase was LuCl3 in the buffer solution consisting of 0.2 M sodium acetate at pH 2.5–5.0. A miniaturised system with a single hollow fibre has been operated in a batch mode. The concentration of Lu(III) was determined by indirect voltammetric method using Zn–EDTA complex. The effect of pH and volume of the donor phase, DEHPA concentration in the organic (liquid membrane) phase, the time of extraction and the content of the acceptor phase on the Lu(III) extraction and stripping behaviour was investigated. The results were discussed in terms of the pertraction and removal efficiency, the memory effect and the mean flux of Lu(III). The optimal conditions for the removal of 177Lu(III) from labelled 177Lu‐radiopharmaceuticals were discussed and identified. The removal efficiency of Lu(III) greater than 99% was achieved at pH of the donor phase between 3.5 and 5.0 using DEHPA concentration in the organic phase of 0.47 M and the ratio of the donor to the acceptor phase of 182. 相似文献
113.
Applicability of several alkyl-bonded silica stationary phases was tested for gradient RP-HPLC of folates under highly aqueous conditions. High retention of folates was achieved on alternative phases with enhanced polarity and classical phases with higher carbon content. Phases exhibiting polar secondary interactions were found to provide better selectivity for late-eluting folates, whereas selectivity for early-eluting folates was mostly dependent on hydrophobic interactions. Best selectivity in phosphate buffered mobile phase was achieved on polar-endcapped silica phases (Aquasil C18 and HyPurity Aquastar) followed by alternative Atlantis dC18. Classical phases exhibited poorer separation of 10-formyl-folic acid and 5-formyl-tetrahydrofolate, but it could be considerably improved by increasing the buffer pH. Strong secondary interactions of ion-exchange character on polar-embedded phases resulted in marked peak deterioration, loss of recovery and dramatic changes in retention behaviour for early- and late-eluting folates when changing the mobile phase composition and pH. Therefore, polar-embedded phases such as HyPurity Advance were found to be unsuitable for separating folates. Stationary phases exhibited peak deterioration when using volatile buffer of low ionic strength. Better results were obtained with classical phases, whereas alternative phases showed not only peak deterioration but also a decrease in recovery and poorer selectivity due to increased secondary interactions in volatile buffer. 相似文献
114.
Jelena?Aleksi? Stevan?Pilipovi? Ivana?Vojnovi?Email authorView authors OrcID profile 《Mediterranean Journal of Mathematics》2018,15(3):142
We consider microlocal defect distributions associated to a weakly convergent sequences \(u_n\) in \(H^{-s,p}_{\Lambda }\) and \(v_n\) in \(H^{s+m,q}_{\Lambda }\) through the space of pseudo-differential operators with the symbols in \((s^{m,N+1}_\Lambda )_0\). Symbols correspond to a weight function \(\Lambda \) determining a quasi-elliptic symbol. Results are applied to partial differential equations with symbols related to weights of the type \(\Lambda \). 相似文献
115.
Jasmina Simonić Jelena Vukojević Mirjana Stajić Jasmina Glamočlija 《Applied biochemistry and biotechnology》2010,162(2):408-415
Comparison of the potential for laccase and Mn-oxidizing peroxidases synthesis by ten strains of Ganoderma lucidum, originating from different worldwide areas, during solid-state fermentation of selected plant raw materials was the aim
of this study. The great intraspecific variability in the production of analyzed enzymes as well as the dependence of the
enzyme activity on plant raw materials were reported. The strain HAI 957 was the best laccase producer in the presence of
corn stem, as a unique carbon source (129.46 U/L). The highest level of Mn-dependent peroxidase activity was noted after wheat
straw fermentation by G. lucidum HAI 246 (78.64 U/L), while the maximal versatile peroxidase production (59.72 U/L) was observed in strain HAI 957 in the
medium with oak sawdust. 相似文献
116.
Mira Petrovic Marinella Farré Miren Lopez de Alda Sandra Perez Cristina Postigo Marianne Köck Jelena Radjenovic Merixell Gros Damia Barcelo 《Journal of chromatography. A》2010,1217(25):4004-4017
An overview of liquid chromatography–mass spectrometry methods used for the determination of trace organic contaminants in environmental samples is presented. Among the organic contaminants the focus is given on five groups of emerging contaminants that raised most concern as environmental contaminants and therefore attracted attention of a research community: pharmaceuticals, drugs of abuse, polar pesticides, perfluorinated compounds and nanoparticles. Various aspects of current LC–MS methodology, using tandem and hybrid MS instruments, including sample preparation, are discussed. 相似文献
117.
Sigitas Tumkevicius Jelena Dodonova Viktoras Masevicius Saulius Jursenas 《Tetrahedron letters》2010,51(30):3902-339
The palladium-catalyzed Suzuki-Miyaura reaction of 2,4-dichloropyrrolo[2,3-d]pyrimidine with aryl boronic acids has been studied. Pd(OAc)2/dicyclohexyl(2-biphenyl)phosphine/K3PO4 was found to be an efficient catalyst system to prepare 4-aryl-2-chloro- and 2,4-diarylpyrrolo[2,3-d]pyrimidines. Novel non-linear molecules consisting of a pyrrolo[2,3-d]pyrimidine core and aryl branches have been elucidated as blue light-emitters with fluorescence quantum yields ranging from 4% to 67% in THF solution. The impact of an electron-withdrawing t-BuOCO group attached to the pyrrole ring of pyrrolopyrimidine derivatives on optical properties is discussed. 相似文献
118.
Building on our understanding of the superfluid density rho(s)(T), we show how the pseudogap enters the in-plane optical conductivity sigma(omega,T) for temperatures T=T(c). Signatures in sigma(omega,T) associated with competing proposals of a "hidden order" and "superconducting" origin for the pseudogap differ in their qualitative omega,T dependences. For the latter case, as T increases from 0, Re sigma(omega) is enhanced at high and low frequencies. We discuss these theories in light of current experiments. 相似文献
119.
Jelena V. Manojlović 《Czechoslovak Mathematical Journal》2005,55(1):41-60
New oscillation criteria are given for the second order sublinear differential equation
where a C
1 ([t
0, )) is a nonnegative function, , f C() with (x) 0, xf(x) / (x) > 0 for x 0, , f have continuous derivative on \ {0} with [f(x) / #x03C8;(x)] 0 for x 0 and q C([t
0, )) has no restriction on its sign. This oscillation criteria involve integral averages of the coefficients q and a and extend known oscillation criteria for the equation x (t) + q(t)x(t) = 0. 相似文献
120.
Krstić D Stevanović N Milivojević J Nikezić D 《Isotopes in environmental and health studies》2007,43(1):65-73
Transfer coefficients of (137)Cs from soil to grass were determined for the terrain around the city of Kragujevac in central Serbia. Mass activity concentrations of (137)Cs in soil and grass samples were determined with a high-purity Ge-detector (HPGe). The activity concentration at the depth of 20 cm was found to be in the range of 14.92-124.05 Bq kg(-1), whereas the activity in grass for the same location was in the range of 4.60-84.95 Bq kg(-1). Transfer factors (TFs) were in the range of 0.07 up to 1.94. Dependences of TFs on different soil characteristics were presented graphically. Weak dependences were determined between them. Absalom's model was used to predict TFs based on soil characteristics: pH value, contents of clay, exchangeable potassium and humus. A comparison of measured and predicted values from Absalom's model is shown graphically. It has been found that Absalom's model might be carefully used for the prediction of (137)Cs in grass for specific regions. 相似文献