Proton NMR of isomorphous paramagnetic and diamagnetic monohydrates MeSO4.1 H2O Me = Mn2+, Fe2+, Ni2+ AND Mg2+

Nuclear magnetic resonance of protons of crystallization water in isomorphous paramagnetic and diamagnetic monohydrates MeSO₄. 1 H₂O with Me = Mn²⁺, Fe²⁺, Ni²⁺ and Mg²⁺ is studied in the present paper. Proton NMR spectra in paramagnetic hydrates are asymmetric and their second moments, M₂, depend linearly on the square of the induction of the external magnetic field B₀. NMR spectrum of diamagnetic hydrate MgSO₄. 1 H₂O is symmetric and its shape and the second moment do not change with B₀. The parameters M₂₀ andK which characterize nuclear dipole-dipole interaction of protons and interaction of protons and paramagnetic ions, respectively, are derived from experimentally obtained dependences M₂ vs B ₀ ² and on the other hand, they are calculated by means of crystallographic data for substances studied. Calculations were realized in approximation where two nearest neighbour ions Me²⁺ to each water molecule are considered. The influence of the demagnetizing magnetic field of the sample was neglected.     

Model of CW pumped passively Q-switched laser

An analytical model of a CW pumped passively Q-switched laser in plane wave approximation is presented. The model was based on possibility to express the analytical solution of simplified rate equations with the help of LambertW function. The LambertW function is now commonly available in most of mathematical software and became to be easy to use. The significant simplification of saturable absorber dynamics is made and its presence is described only by its initial and saturated transmission. Using this model it is possible to estimate giant pulse parameters, like pulse length and energy density, the pulse repetition rate, and the laser input-output power characteristic. The validity limits of this model were verified using numerical solution of more complicated rate equations model which included nonlinear response of the modulator. The model was compared with experimental results obtained for passively Q-switched diode pumped Nd:YAG/V:YAG microchip laser.     

Computational study of impulsively generated standing slow acoustic waves in a solar coronal loop

We numerically investigated standing slow acoustic waves impulsively excited in a solar coronal loop by gas pressure and mass density perturbations in one-dimensional space. The corresponding computer model is described by the hydrodynamic equations that are solved numerically by means of the so-called flux limiters methods on uniformly structured mesh. We discuss the fundamental mode and the first harmonic mode which are generated in dependence on position of the initial perturbation in the numerical box. We show how the standing slow acoustic waves are generated in the corona, where they are trapped in space between two dense layers as in the resonator, and how their energy leaks from the corona to the dense layers. We found that this leakage increases with the decrease of the density jump at the transition region. We also studied the case when the perturbation is initiated at the transition region. We found that even in this case the standing wave is formed, but their energetics is influenced by the evaporation of the plasma from the transition region into the corona.     

Bond strengths evaluation of laser ceramic bracket debonding

Ceramic brackets often used for an orthodontic treatment can lead to problems such as enamel tear outs because of their low fracture resistance and high bond strengths. Therefore the aim of our study was to investigate the positive laser radiation effect on bracket debonding. Moreover, the influence of the enamel shape surface under the bracket and laser radiation power on the debonding strength was investigated. The source of the radiation was the longitudinally diode-pumped Tm:YAP laser operating at 1997 nm. To eliminate the tooth surface roughness the flat enamel surface was prepared artificially and the bracket was bonded on it. The debonding was accomplished by Tm:YAP laser radiation with different the power value while recording the temperature rise in the pulp. To simulate the debonding process in vivo the actual bond strength was measured by the digital force gauge. The results were analyzed by scanning electron microscope.     

Study of quasicrystalline thin films based on Al–Pd–Mn and Al–Cu–Fe prepared by PLD

Thin films of Al₇₀Pd₂₀Mn₁₀ Al₆₃Cu₂₅Fe₁₂ Al₇₀Pd₂₀Mn₁₀ and Al₆₃Cu₂₅Fe₁₂ were grown by laser ablation on fused silica at set of deposition temperature –196°C, room temperature 165°C and 350°C. Structure, morphology, resistivity and refractive index of prepared layers were studied.     

High-power Nd:YAG laser picosecond pulse delivery by a polymer-coated silver hollow-glass waveguide

An oscillator-amplifier high-power Nd:YAG laser system was used for transmission of a single 50-ps-long pulse or a train of pulses through a cyclic olefin polymer-coated silver hollow-glass waveguide. The maximum energy that was transmitted was 150 mJ for the train of pulses and 40 mJ for the single pulse, from which followed a delivered power of 100 GW/cm(2) . The characteristics that were obtained make these waveguides promising for the delivery of high-power laser pulses in medical as well as other applications.     

Relation between the chemical force and the tunnelling current in atomic point contacts: a simple model

The relation between the tunnelling current I(t) and the interaction energy/force E in an atomic-scale contact is discussed in the framework of a theoretical model established here. According to our model, we predict the existence of two characteristic scaling regimes, where the tunnelling current is either proportional to the interaction energy, I(t) ~ E, or to the square of the interaction energy, I(t) ~ E(2). We show that the existence of a given regime is basically controlled by two parameters: (i) the energy degeneracy Δ and (ii) the hopping t between electronic levels involved in the interaction process. In addition, we discuss the validity of the Bardeen method to determine the tunnelling current in the short tip-sample distances.     

Composition, XRD and morphology study of laser prepared LiNbO3 films

LiNbO₃ films were deposited by PLD from LiNbO₃ crystalline or from three different stoichiometric or Li-enriched LiNbO₃ targets. Polycrystalline films were prepared on SiO₂/Si or sapphire substrates at temperatures T _S ～650–750 °C. Main attention was paid to the influence of targets preparation and the deposition conditions on films composition, morphology and crystallinity. The thin-film morphology was determined by SEM microscopy. The composition was measured by SIMS, RBS, PIXE and PIGE methods. Highly oriented, smooth and stoichiometric LiNbO₃ films were synthesized.     

Study of optical properties and biocompatibility of DLC films characterized by sp3 bonds

Optical and biomedical properties of diamond-like carbon (DLC) films of various sp², sp³ bonds were studied. The layers were prepared by pulsed laser deposition (PLD) for laser energy densities from 4 J?cm^?2 to 14 J?cm^?2. The percentage of sp² and sp³ bonds was calculated using X-ray photoelectron spectroscopy (XPS). In dependence on density the films contained up to 70 % of sp³ bonds. Optical properties were measured using spectroscopic ellipsometry in region from 250 nm to 1000 nm (n=2.6–2.7; k=0.07–0.25) and by transmission measurement (from 200 nm to 1100 nm). The adhesion and growth of human fibroblasts and keratinocytes of DLC films were tested in vitro.