Analyzing dynamic interaction of impulse-loaded strips

The paper considers the dynamic process of contact interaction of infinite impulse-loaded strips arranged with a gap. The behavior of the strips is described by linear elastic dynamics equations. The contact problem is solved by the collocation method. The process of impact of two and three strips is analyzed. The calculation results are compared with data obtained by using the finite-element method.     

回归正交试验设计在水飞蓟素提取工艺中的应用

本文针对水飞蓟素提取工艺利用二次回归正交设计 ,进行了五个变量的正交回归设计 ,获得了最佳的试验工艺参数值以及相应的数学模型     

波长色散X射线荧光光谱法测定钴精矿中钴、铜和锰含量

采用高纯氧化物经四硼酸锂和偏硼酸锂熔融制备人工标准样品,以氧化镱为内标,制作校准曲线,建立了波长色散型X射线荧光光谱法测定钴精矿中钴、铜、锰元素的分析方法。重点研究了混合熔剂、试样稀释比、氧化剂和内标选择、方法检出限、方法准确度和精密度等,结果表明,各元素校准曲线线性范围宽,相关系数均大于0.999, 钴、铜、锰元素检出限分别达到0.002%、0.001%和0.001%,测试准确度和精密度可靠,方法满足行业检测需求。     

反相高效液相色谱法测定棒柄花中反式-4-(1-丙烯基)苯酚-β-D-吡喃葡萄糖苷

用反相高效液相色谱法建立棒柄花中反式-4-(1-丙烯基)苯酚-β-D-吡喃葡萄糖苷的含量测定方法,并测定其含量。色谱柱Reliasil-C18(250 mm×4.6 mm,5μm),流动相乙腈-水(体积比22∶78),流速1.0mL/m in,检测波长257 nm。结果待测组分在0.080 4~0.281 4μg范围内与峰面积线性关系良好,相关系数为0.999 5,平均加标回收率为98%,RSD为1.8%(n=6)。本法简便、快速、重复性好、结果准确可靠。     

蒙药草乌花及其提取物化学成分的红外光谱法整体结构解析

采用傅立叶变换红外光谱法并借助于二阶导数谱以及二维相关红外光谱(2D-FTIR)研究了蒙药草乌花原药材及不同溶剂提取物(依次采用乙醚,乙醇和水提取)所含化学成分的红外谱图整体变化规律.结果显示:在草乌花原药材中具有明显的多糖类化合物的红外特征吸收峰,证明该药材中含有大量多糖类成分.草乌花药材乙醚和醇提物的红外光谱较相似...     

Collision induced dissociations of non‐derivatized and trimethylsilyl‐derivatized estradiols: similarities in fragmentation patterns

Fragmentation mechanisms of estradiol and trimethylsilyl (TMS)‐derivatized estradiol were studied by triple quadrupole tandem mass spectrometry (MSMS) and density functional theory (DFT) at B3LYP/6‐311G(d,p) level. Collision induced dissociations (CID) of estradiol give product ions that are associated with the cleavage of B, C and D rings. Characteristic fragments from the cleavage of the aromatic ring A were not identified, and this was confirmed with both labeled estradiol and trimethylsilyl (TMS)‐derivatized estradiol. The mechanisms are based on charge‐site directed, radical‐directed and charge remote fragmentations that are consistent with previous studies of steroids. CID spectra show ion pairs at m/z: 145/146, 157/158, 185/186, 211/213 and 225/226 with significant intensities, suggesting that these pairs are not from isotopic contributions. The mechanisms show similarities with some minor differences in the fragmentation patterns between the non‐derivatized and the TMS‐derivatized estradiol. Copyright © 2015 John Wiley & Sons, Ltd.     

Analytical Results for the Critical Exponents of Fully Directed Levy Flights

In this paper we generalize the definition of Levy flight (LF). With the help of a useful definition for the critical exponents of LF by introducing the concept of cutoff steplength, we calculate analytically the exponents of FDLFs in arbitrary d dimensions, utilizing the generating function method.     

Low Frequency Circular Polarized Soliton in a Ferromagnetic System Under a Strong Bias Magnetic Field

The derivative nonlinear Schrodinger equation for the low frequency circular polarized wave, propagating parallel to the bias magnetic field in a ferromagnetic system, is derived by the reductive perturbation expansion method.     

表面改性后的SiO2薄膜光学性能研究

用溶胶-凝胶法在酸碱复合催化条件下制备了Si O2溶胶,采用浸渍提拉法在K9玻璃上制备了性能稳定的Si O2薄膜,并用三甲基氯硅烷对Si O2薄膜进行了表面改性。用反射式椭圆偏振光谱仪测试薄膜的椭偏参数,并用Cauchy模型对椭偏参数进行数据拟合,获得了Si O2改性前后在300~700 nm波段的色散关系。讨论了薄膜改性与光学性能间的关系。结果表明:Cauchy模型能较好的描述溶胶-凝胶薄膜在300~650 nm波段的光学性能;表面改性后Si O2薄膜光学常数发生改变,但未影响色散关系的变化趋势;薄膜改性后具有随着膜层数的增加,折射率增加,而最大峰值透光率、孔隙率减小的规律,且薄膜改性后表面更加致密。     

微含水量电解液中高管径比TiO_2纳米管阵列的制备

通过阳极氧化法在微含水量为0.5wt%的NH4F/乙二醇/H2O酸性电解质体系中制备了管径大、高管径比的二氧化钛(TiO2)纳米管阵列。采用SEM、XRD等测试手段对TiO2纳米管阵列形貌及晶相进行表征,探讨了不同氧化时间、电压对纳米管阵列形貌的影响,微含水量下氧化电压可以适当增加,更容易得到规整的长纳米管阵列;通过测定样品的光电流和紫外-可见光漫反射吸收光谱,研究分析了含水量以及超声工艺对纳米管光吸收及光电流特性,微含水量下得到的纳米管阵列可见光吸收边红移至420nm,对480~700nm可见光有明显的光吸收,光电流显著增大;丙酮作为超声介质可有效去除纳米管阵列表面的集束,能进一步提高纳米管阵列的光电性能。