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41.
Afaf M.Abdel Hameed 《中国化学快报》2012,23(4):411-414
Azidation of aminothiophene derivative 1 afforded the corresponding azido derivative 2.The latter reacted with triphenylphosphine to afford iminophosphorane derivatives 3.Reacting 3 with phenylisocyanate gave the highly reactive carbodiimide intermediate 4,which was reacted with different nitrones to afford new l,2,4-oxadiazolidin-5-ylidene-aminothiophenes 5a-c. Treatment of 4 with absolute EtOH at room temperature gave methyleneamino-5-(methylthio)thiophene 7,(methylthio)-3-(3- phenylureidothiophene)-2-carboxylate 8 or thienopyrimidine 9 and 10 at refluxing temperature.Finally reaction of carbodiimide intermediate 4 with different secondary amines gave the new thienopyrimidines 11a-c. 相似文献
42.
AH Karim AA Jalil S Triwahyono SM Sidik NH Kamarudin R Jusoh NW Jusoh BH Hameed 《Journal of colloid and interface science》2012,386(1):307-314
In this work, mesostructured silica nanoparticles (MSN(AP)) with high adsorptivity were prepared by a modification with 3-aminopropyl triethoxysilane (APTES) as a pore expander. The performance of the MSN(AP) was tested by the adsorption of MB in a batch system under varying pH (2-11), adsorbent dosage (0.1-0.5gL(-1)), and initial MB concentration (5-60mgL(-1)). The best conditions were achieved at pH 7 when using 0.1gL(-1) MSN(AP) and 60mgL(-1)MB to give a maximum monolayer adsorption capacity of 500.1mgg(-1) at 303K. The equilibrium data were evaluated using the Langmuir, Freundlich, Temkin, and Harkins-Jura isotherms and fit well to the Freundlich isotherm model. The adsorption kinetics was best described by the pseudo-second order model. The results indicate the potential for a new use of mesostructured materials as an effective adsorbent for MB. 相似文献
43.
A set W of the vertices of a connected graph G is called a resolving set for G if for every two distinct vertices u, v ∈ V (G) there is a vertex w ∈ W such that d(u, w) ≠ d(v, w). A resolving set of minimum cardinality is called a metric basis for G and the number of vertices in a metric basis is called the metric dimension of G, denoted by dim(G). For a vertex u of G and a subset S of V (G), the distance between u and S is the number min s∈S d(u, s). A k-partition Π = {S 1 , S 2 , . . . , S k } of V (G) is called a resolving partition if for every two distinct vertices u, v ∈ V (G) there is a set S i in Π such that d(u, Si )≠ d(v, Si ). The minimum k for which there is a resolving k-partition of V (G) is called the partition dimension of G, denoted by pd(G). The circulant graph is a graph with vertex set Zn , an additive group of integers modulo n, and two vertices labeled i and j adjacent if and only if i-j (mod n) ∈ C , where CZn has the property that C =-C and 0 ■ C. The circulant graph is denoted by Xn, Δ where Δ = |C|. In this paper, we study the metric dimension of a family of circulant graphs Xn, 3 with connection set C = {1, n/2 , n-1} and prove that dim(Xn, 3 ) is independent of choice of n by showing that dim(Xn, 3 ) ={3 for all n ≡ 0 (mod 4), 4 for all n ≡ 2 (mod 4). We also study the partition dimension of a family of circulant graphs Xn,4 with connection set C = {±1, ±2} and prove that pd(Xn, 4 ) is independent of choice of n and show that pd(X5,4 ) = 5 and pd(Xn,4 ) ={3 for all odd n ≥ 9, 4 for all even n ≥ 6 and n = 7. 相似文献
44.
Ali Farooq H. Hamzah Hameed K. Mozaffari Masoud Mehryan S. A. M. Ghalambaz Mohammad 《Journal of Thermal Analysis and Calorimetry》2020,141(5):1801-1816
Journal of Thermal Analysis and Calorimetry - In this study, the heat transfer, fluid flow and heat capacity ratio are analyzed in an annulus enclosure filled with porous and saturated by a... 相似文献
45.
Closed-form relations are derived for the probabilities and performance measures observed at random/arrival/departure epochs in a multi-server queue with group arrivals. 相似文献
46.
47.
Faruk Güder James Zydiak Sohail Chaudhry 《The Journal of the Operational Research Society》1994,45(10):1197-1205
This paper presents a heuristic algorithm for determining order quantities for multiple items given incremental quantity discounts and a single resourse constraint. The heuristic is based on Lagrangian relaxation. The performance of the heuristic is compared, for small problems, with a procedure that generates optimal solutions. Results from computational experiments are given that demonstrate the quality and computational efficiency of the heuristic algorithm. 相似文献
48.
Wajiha Ahmad Sundus Riaz Nasir Mehmood Ahmad Maryam Hameed Ayesha Naeem 《Natural product research》2018,32(8):968-971
Plant phytochemicals, such as flavonoids are in use for the development of optical biosensor. Benzo[a]pyrene (B[a]P), is a pervasive environmental and dietary carcinogen. A fluorescent assay is developed using plant isolated flavonoid for the detection of B[a]P. High content saponins are excluded from the flavonoid-containing methanolic extract of Corchorus depressus by implying reduction of silver ions by saponins resulting in formation of silver nanoparticles. Isolated plant flavonoids are used to develop a spectrofluorometric assay for the detection of B[a]P. Decrease in the flavonoid fluorescence intensity by B[a]P is found to be based on both static and dynamic quenching. Specificity of the assay for B[a]P was tested for other carcinogens belonging to different classes of compounds. Flavonoids-mediated sensing can be implied for the development of new generation of nanoparticle-based biosensors that can be more sensitive and less susceptible to external factors, such as temperature and humidity. 相似文献
49.
Zafar Ali Shah Saba Farooq Syed Abid Ali Abdul Hameed M. Iqbal Choudhary 《合成通讯》2018,48(10):1172-1182
The peptide temporin-LK1 (1) was obtained from the skin secretion of frog Limnonectes kuhlii (Ranidae). It is a unique antimicrobial peptide with 17 residues, including four L-phenylalanines and single glycine. Mass spectrometry and Edmand degradation were used for the determination of sequence of amino acids in temporin-LK 1 (1), and confirmed by cDNA cloning. We report here the synthesis and structural studies of temporin-LK1 (1) and its analogs 2–4. Peptides 2–4 were prepared by substitution of achiral glycine residue of temporin-LK1 (1) with D-alanine, L-phenylglycine, and L-naphthylalanine, respectively. Peptides 1–4 were evaluated against multidrug-resistant (MDR) strains of Staphylococcus aureus and Pseudomonas aeruginosa. Analog 2 was found active against all MDR strains of S. aureus and P. aeruginosa at a much lower dose than the clinically used antibiotics. 相似文献
50.
The differential pulse polarographic behaviour of benzoylhydrazine, m-methoxy benzoyl-hydrazine, and o-methoxy benzoylhydrazine has been investigated in Britton-Robinson buffer. The peaks obtained at pH 5 are recommended for the microdetermination of these compounds. The benzoylhydrazine can be obtained with high degrees of accuracy with an experimental detection limit of 4 × 10−6 M in simple aqueous and aqueous ethanol mixtures. 相似文献