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111.
    
Redox-switchable polymerizations of lactide and epoxides were extended to the solid state by anchoring an iron-based polymerization catalyst to TiO2 nanoparticles. The reactivity of the molecular complexes and their redox-switching characteristics were maintained in the solid-state. These properties resulted in surface-initiated polymerization reactions that produced polymer brushes whose chemical composition is dictated by the oxidation state of the iron-based complex. Depositing the catalyst-functionalized TiO2 nanoparticles on fluorine-doped tin oxide resulted in an electrically addressable surface that could be used to demonstrate spatial control in redox-switchable polymerization reactions. By using a substrate that contained two electrically isolated domains wherein one domain was exposed to an oxidizing potential, patterns of surface-bound polyesters and polyethers were accessible through sequential application of lactide and cyclohexene oxide. The differentially functionalized surfaces demonstrated distinct physical properties that illustrated the promise for using the method to pattern surfaces with multiple, chemically distinct polymer brushes.

Patterns of multiple polymer brushes on surfaces are obtained through application of an electrical potential to a surface functionalized with redox-switchable polymerization catalysts.  相似文献   
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We demonstrate that backscatter data processed by the two-point method can provide spatial loss results in a form that allows the immediate interpretation of joint loss. Furthermore, all the joints in a typical repeater span can be compared from the same base line and a threshold level introduced for the rejection or acceptance of joints, a feature which facilitates field measurement.  相似文献   
114.
The relationship between measurement accuracy and signal-to-noise ratio for attenuation, joint loss, link loss and fault location measurements is established for both coherent and incoherent OTDRs. For each parameter, range is defined as the maximum distance over which a minimum acceptable measurement accuracy, or corresponding minimum acceptable signal-to-noise ratio, is attained. Range, defined in this way, serves as a basis for the comparison of different OTDRs. Results are presented which verify the theory.  相似文献   
115.
We study an integrable modification of the focusing nonlinear Schrödinger equation from the point of view of semiclassical asymptotics. In particular, (i) we establish several important consequences of the mixed-type limiting quasilinear system including the existence of maps that embed the limiting forms of both the focusing and defocusing nonlinear Schrödinger equations into the framework of a single limiting system for the modified equation, (ii) we obtain bounds for the location of the discrete spectrum for the associated spectral problem that are particularly suited to the semiclassical limit and that generalize known results for the spectrum of the nonselfadjoint Zakharov-Shabat spectral problem, and (iii) we present a multiparameter family of initial data for which we solve the associated spectral problem in terms of special functions for all values of the semiclassical scaling parameter. We view our results as part of a broader project to analyze the semiclassical limit of the modified nonlinear Schrödinger equation via the noncommutative steepest descent procedure of Deift and Zhou, and we also present a selfcontained development of a Riemann-Hilbert problem of inverse scattering that differs from those given in the literature and that is well adapted to semiclassical asymptotics.  相似文献   
116.
Changes in the specific diet of earthworms with time in relation to landuse changes and two different climates were studied by analysing (13)C and (15)N natural abundance in soils and animals. Soil samples from three depths (0-10, 10-20 and 20-30 cm) and earthworms were collected from two sites: Santiago (Northwest Spain) and North Wyke (Southwest England) both consisting of replicated long-term grasslands and recently converted to maize plots. Earthworms were hand-sorted in the field at the peak of the maize growth and after harvesting at both sites. In the Spanish plots, nine and eight earthworm species, all belonging to the three ecological categories (epigeic, anecic and endogeic), were found under maize and permanent pasture, whereas at the English site five and seven different species were, respectively, identified. At both sites (13)C isotopic values of the earthworm tissues reflected changes in diet from C(3) to C(4) with epigeic and epi/anecic worms in the maize plots showing one delta unit difference in relation to the ones found in the grassland plots. Anecic worms seemed to be less responsive to landuse changes. The higher (13)C values of the Spanish soils were also reflected in the earthworm tissues when compared with the English samples. (15)N values showed no clear relationship with the cropping treatments but were clearly related to the ecological grouping, with endogeic worms reaching the highest values whereas for the epigeic and epi/anecic species the lowest values were obtained. This finding was also previously recorded by other authors1 and suggests that, in the future, stable isotope techniques could also be a useful tool in taxonomic studies. Copyright 1999 John Wiley & Sons, Ltd.  相似文献   
117.
A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd.  相似文献   
118.
A projectile ion-recoil ion coincidence technique has been employed to study the multiple ionization and the charge transfer processes in collisions of 60–120 MeV Si q+ (q = 4−14) ions with neutral argon atoms. The relative contribution of different ionization channels, namely; direct ionization, electron capture and electron loss leading to the production of slow moving multiply charged argon recoil ions have been investigated. The data reported on the present collision system result from a direct measurement in the considered impact energy for the first time. The total ionization cross-sections for the recoil ions are shown to scale as q 1.7/E p 0.5 , where E p is the energy in MeV of the projectile and q its charge state. The recoil fractions for the cases of total- and direct ionizations are found to decrease with increasing recoil charge state j. The total ionization fractions of the recoils are seen to depend on q and to show the presence of a ‘shell-effect’ of the target. Further, the fractions are found to vary as 1/j 2 upto j = 8+. The average recoil charge state 〈j〉 increases slowly with q and with the number of lost or captured electrons from or into the projectile respectively. The projectile charge changing cross-sections σ qq are found to decrease with increasing q for loss ionization and to increase with q for direct-and capture ionization processes respectively. The physics behind various scaling rules that are found to follow our data for different ionization processes is reviewed and discussed.  相似文献   
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Homoepitaxial growth of GaN by metal organic vapor phase epitaxy (MOVPE) was systematically evaluated using nominal c‐plane and various vicinal GaN(0001) wafers: 1°, 2°, 4°, and 8° offcut in the directions of 〈10 0〉 and 〈11 0〉. It was found that a hillock morphology formed on the nominal c‐plane substrate whereas smooth epi films were formed on vicinal substrates. Silicon‐doped films showed similarly improved surface morphology with offcut angle, however Mg‐doped films exhibited a rougher microstructure. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
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