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421.
The ring‐opening polymerization (ROP) of ε‐caprolactone (ε‐CL), 4‐methyl‐ε‐caprolactone (4‐MeCL), and 6‐methyl‐ε‐caprolactone (6‐MeCL) with a single‐site chiral initiator, R,R′‐(salen) aluminum isopropoxide (R,R′‐[1]), was investigated. The kinetic data for the ROP of the three monomers at 90° in toluene corresponded to first‐order reactions in the monomer and propagation rate constants of kε‐CL > k4‐MeCL ? k6‐MeCL. A notable stereoselectivity with a preference for the R‐enantiomer was observed in the ROP of 6‐MeCL with R,R′‐[1], whereas for 4‐MeCL, no stereoselectivity was found. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 429–436, 2007.  相似文献   
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Summary: The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one‐pot enzymatic procedure by using 2‐hydroxyethyl α‐bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).

Enzymatic synthesis of heterotelechelic macromonomers and subsequent self condensing vinyl polymerization by ATRP.  相似文献   

425.
A compact open-path optical ammonia detector is developed. A tunable external-cavity diode laser operating at 1.5 μm is used to probe absorptions of ammonia via the cavity-enhanced absorption (CEA) technique. The detector is tested in a climate chamber. The sensitivity and linearity of this system are studied for ammonia and water at atmospheric pressure. A cluster of closely spaced rovibrational overtone and combination band transitions, observed as one broad absorption feature, is used for the detection of ammonia. On these molecular transitions a detection limit of 100 ppb (1 s) is determined. The ammonia measurements are calibrated independently with a chemiluminescence monitor. Compared to other optical open-path detection methods in the 1–2 μm region, the present result shows an improved sensitivity for contactless ammonia detection by over one order of magnitude. Using the same set-up, a detection limit of 100 ppm (1 s) is determined for the detection of water at atmospheric pressure. Received: 19 January 2000 / Revised version: 6 March 2000 / Published online: 7 June 2000  相似文献   
426.
The strong coupling limit is studied for a Pekar-Fröhlich polaron confined to a one-dimensional (1D) structure. The non-linear effective Schrödinger equation is solved exactly in the case of two different external potentials which imitate a finite size 1D sample: an infinite and a finite deep rectangular well. The ground state and excited states are calculated. We found that taking the limit of a finite size box to an infinitely large box leads to additional solutions which are not found in a treatment on an infinite axis. The additional solutions, which have a 1/n 2 discrete spectrum, correspond to polaron states in which the wave function is split up in identical parts which are infinitely apart from each other.  相似文献   
427.
Edge operational regimes in tokamaks are described using mostly experimental results of ASDEX Upgrade. Emphasis is put on high confinement mode (H-mode) at medium and high densities up to the density limit. Implications for the physics of H-mode and the density limit are discussed.  相似文献   
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We compare two dual-based procedures for solving the p-median problem. They rely upon alternative Lagrangean relaxations of the problem. We describe the algorithms and report on our computational experiments.  相似文献   
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The short-time behavior of viscoelastic materials has been traditionally studied on the millisecond time scale using steady sinusoidal excitation to measure the complex modulus and optical functions. A technique has now been developed for determining the short-time inverse optical-creep function on the microsecond time scale, using wave propagation in a rod. The method is demonstrated by characterizing an epoxy material in the time regime from 1 μs to 100μs.  相似文献   
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