Simple pyridylmethylamines: efficient and robust N,N-ligands for Suzuki-Miyaura coupling reactions

A series of pyridylmethylamines have been synthesized in one step from commercially available starting material and identified as effective ligands for Pd-catalyzed carbon-carbon bond formation through Suzuki-Miyaura coupling reaction. The N,N-pyridylmethylamine-Pd catalytic systems appeared as an interesting and robust compromise between catalytic efficiency, substrate compatibility, and practical aspects.     

Non-invasive single bunch monitoring for ps pulse radiolysis

A single-shot electro-optic (EO) diagnostic has been installed on the ELYSE photocathode RF gun accelerator to monitor the electron bunch at the place and under the conditions of the ps pulse radiolysis experiments. The EO signal is due to the coulombic field of the electron bunch and to a contribution of a free-space THz radiation generated by the same electron pulse. This signal is recorded shot-to-shot at the repetition rate of the accelerator. The jitter of the arrival time of the electron bunch is characterized for the first time with a non-invasive method and is confirmed to be around 1 ps.     

Sea-ice thickness measurement based on the dispersion of ice swell

The dispersion of flexural waves propagating in the Arctic sea ice cover is exploited in order to locally measure the ice thickness. The observed dispersion, for waves filtered in the 4-20 s period interval, at up to 4 broad-band seismometers deployed in Spring 2007 near the North Pole, is compared to a parameterized model that accounts for a complex wavefield made of a superposition of independent plane waves with different amplitudes and back-azimuth angles. The parameterization, that includes finding the best modeled ice thickness, is performed by using the cross-correlation functions between the seismometers. The ice thickness is estimated to 2.5 ± 0.2 m for the ~1 km-large floe the seismic stations were deployed on, which is coherent with other, independent measurements at this site. This study thus demonstrates the feasibility of using broad-band seismometers deployed on the sea-ice in order to passively measure the ice thickness, without requiring active sources nor human intervention.     

A mode matching approach for modeling two dimensional porous grating with infinitely rigid or soft inclusions

This work investigates the acoustical properties of a multilayer porous material in which periodic inclusions are embedded. The material is assumed to be backed by a rigid wall. Most of the studies performed in this field used the multipole method and are limited to circular shape inclusions. Here, a mode matching approach, more convenient for a layered system, is adopted. The inclusions can be in the form of rigid scatterers of an arbitrary shape, in the form of an air-filled cavity or in the form of a porous medium with contrasting properties. The computational approach is validated on simple geometries against other numerical schemes and with experimental results obtained in an anechoic room on a rigid grating embedded in a porous material made of 2 mm glass beads. The method is used to study the acoustic absorption behavior of this class of materials in the low frequency range and at a range of angles of incidence.     

Analysis of the impact degree distribution in metabolic networks using branching process approximation

Theoretical frameworks to estimate the tolerance of metabolic networks to various failures are important to evaluate the robustness of biological complex systems in systems biology. In this paper, we focus on a measure for robustness in metabolic networks, namely, the impact degree, and propose an approximation method to predict the probability distribution of impact degrees from metabolic network structures using the theory of branching process. We demonstrate the relevance of this method by testing it on real-world metabolic networks. Although the approximation method possesses a few limitations, it may be a powerful tool for evaluating metabolic robustness.     

Peeling of Dirac and Maxwell fields on a Schwarzschild background

We study the peeling of Dirac and Maxwell fields on a Schwarzschild background following the approach developed by the authors in Mason and Nicolas (2009) [12] for the wave equation. The method combines a conformal compactification with vector field techniques in order to work out the optimal space of initial data for a given transverse regularity of the rescaled field across null infinity. The results show that analogous decay and regularity assumptions in Minkowski and Schwarzschild produce the same regularity across null infinity. The results are valid also for the classes of asymptotically simple spacetimes constructed by Corvino–Schoen/Chru?ciel–Delay.