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101.
Sub-ppm multi-gas photoacoustic sensor 总被引:1,自引:0,他引:1
Besson JP Schilt S Thévenaz L 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(5):899-904
A photoacoustic multi-gas sensor using tuneable laser diodes in the near-infrared region is reported. An optimized resonant configuration based on an acoustic longitudinal mode is described. Automatic tracking of the acoustic resonance frequency using a piezo-electric transducer and a servo electronics is demonstrated. Water vapour, methane and hydrogen chloride have been measured at sub-ppm level in different buffer gas mixtures. The importance of the system calibration in presence of several diluting gases is discussed. Finally, trace gas measurements have been assessed and detection limits (signal-to-noise ratio=3) of 80 ppb at 1651.0 nm for CH(4), 24 ppb at 1368.6 nm for H(2)O and 30 ppb at 1737.9 for HCl have been demonstrated. 相似文献
102.
In this paper we extend the ideas of the so-called validated continuation technique to the context of rigorously proving the existence of equilibria for partial differential equations defined on higher-dimensional spatial domains. For that effect we present a new set of general analytic estimates. These estimates are valid for any dimension and are used, together with rigorous computations, to construct a finite number of radii polynomials. These polynomials provide a computationally efficient method to prove, via a contraction argument, the existence and local uniqueness of solutions for a rather large class of nonlinear problems. We apply this technique to prove existence and local uniqueness of equilibrium solutions for the Cahn-Hilliard and the Swift-Hohenberg equations defined on two- and three-dimensional spatial domains. 相似文献
103.
It is well-known that an element of the linear group is semisimple if and only if its conjugacy class is Zariski closed. The aim of this paper is to show that the same result holds for the group of complex plane polynomial automorphisms. 相似文献
104.
Sergey S. Mikhailichenko Jean-Philippe Bouillon Thierry Besson 《Tetrahedron letters》2010,51(6):990-993
This Letter presents the first examples of hetero-Diels-Alder reactions of polyfluoroalkanethiocarboxylic acid amides and 2,3-dimethylbutadiene under microwave heating. Cycloaddition reactions proved to be dependent on the nature of perfluoroalkyl chain and on the substituents attached to the nitrogen atom. Formation of ammonium salts was also performed by simple treatment of the corresponding cycloadducts with trifluoromethanesulfonic acid. In the case of octafluorobutyl-substituted derivative, one spontaneous desamination reaction took place leading to new 2H-thiopyran. 相似文献
105.
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107.
Ebran JP Jensen CM Johannesen SA Karaffa J Lindsay KB Taaning R Skrydstrup T 《Organic & biomolecular chemistry》2006,4(19):3553-3564
In this perspective, an overview of our experiences on the application of samarium diiodide in organic synthesis for the preparation of amino acid and peptide analogues is presented. Three different carbon-carbon bond forming reactions are discussed, including side chain introductions, gamma-amino acid synthesis and acyl-like radical additions for the construction of C-C mimics of the peptidic bonds. 相似文献
108.
Jaffel H Korb JP Ndobo-Epoy JP Morin V Guicquero JP 《The journal of physical chemistry. B》2006,110(14):7385-7391
We report a comprehensive proton NMR relaxation study of the water confined in the evolving porous structure of hardened gypsum prepared with different water-to-plaster ratios (w/p) and increasing additions of crushed gypsum. This study gives some new information on the microstructure, the water distribution, and the hydration kinetics without any drying or perturbing preparation. The bi-exponential transverse magnetization decay reveals the existence of two water populations in slow exchange. However, the different behaviors of these populations during saturation and desaturation experiments show evidence of a fast exchange of each population with the surface. Two modes of organization of the microstructure of this material are identified through an original model of exchange as a function of the water-to-plaster ratio (0.4 < or = w/p < or = 0.6 and 0.7 < or = w/p < or = 1). A clear gap is shown in the exchange rate value above w/p = 0.6 that could be representative of a percolation threshold. Both the method and the theory presented can be applied more widely to other porous media with reactive surface areas. 相似文献
109.
Jaffel H Korb JP Ndobo-Epoy JP Guicquero JP Morin V 《The journal of physical chemistry. B》2006,110(37):18401-18407
A new multi-scale experimental approach is proposed to continuously relate the microstructure and the macroscopic mechanical properties of plaster pastes during their settings. (1)H NMR relaxometry is used to follow continuously and not destructively, the degree of hydration and the microstructure evolution during the setting and hardening of plaster paste. Transmission of shear and compressional ultrasonic velocities enable the determination of macroscopic mechanical properties of the material during the setting. On the basis of similar behaviors of Young's modulus and NMR-population of confined water as function of the degree of hydration, we conclude that NMR gives a better understanding of the evolution of the microstructure at the origin of a better control of the macroscopic mechanical properties. 相似文献
110.
Pierre-Alexandre Paquet-Côté Kellie L. Tuck Jean-Philippe Paradis Bim Graham Normand Voyer 《Tetrahedron letters》2017,58(50):4672-4676
Seeking to increase the selectivity of antimicrobial peptides for prokaryotic cells, we incorporated a bis-dipicolyl amine (bis-DPA) ligand at the N-terminus of de novo designed model peptides. The Zn2·bisDPA complex increases the interaction of peptides with anionic model membranes, while decreasing interactions with zwitterionic model membranes. Further, it improves the peptides’ antimicrobial activity and decreases their hemolytic activity without substantial changes to their secondary structure. Therefore, incorporating a Zn2·bisDPA complex is a useful strategy to enhance the selectivity of antimicrobial peptides. 相似文献