全文获取类型
收费全文 | 903篇 |
免费 | 5篇 |
国内免费 | 11篇 |
专业分类
化学 | 579篇 |
晶体学 | 10篇 |
力学 | 34篇 |
数学 | 176篇 |
物理学 | 120篇 |
出版年
2020年 | 10篇 |
2019年 | 6篇 |
2018年 | 5篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 14篇 |
2014年 | 4篇 |
2013年 | 35篇 |
2012年 | 48篇 |
2011年 | 60篇 |
2010年 | 32篇 |
2009年 | 22篇 |
2008年 | 52篇 |
2007年 | 62篇 |
2006年 | 46篇 |
2005年 | 59篇 |
2004年 | 46篇 |
2003年 | 51篇 |
2002年 | 34篇 |
2001年 | 13篇 |
2000年 | 10篇 |
1999年 | 12篇 |
1998年 | 12篇 |
1997年 | 21篇 |
1996年 | 19篇 |
1995年 | 11篇 |
1994年 | 12篇 |
1993年 | 9篇 |
1992年 | 12篇 |
1991年 | 7篇 |
1990年 | 6篇 |
1989年 | 8篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 13篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 9篇 |
1981年 | 17篇 |
1980年 | 16篇 |
1979年 | 8篇 |
1978年 | 18篇 |
1977年 | 8篇 |
1976年 | 14篇 |
1975年 | 9篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1971年 | 4篇 |
1931年 | 3篇 |
排序方式: 共有919条查询结果,搜索用时 46 毫秒
71.
Mitzel F Boudon C Gisselbrecht JP Seiler P Gross M Diederich F 《Chemical communications (Cambridge, England)》2003,(14):1634-1635
A novel class of planar, highly conjugated all-carbon macrocycles, which we christened "radiaannulenes", have been prepared based on acetylenic scaffolding using tetraethynylethene (TEE) building blocks; these structures are powerful electron acceptors and, upon peripheral substitution with electron-donating N,N-dialkylanilino groups, display intense intramolecular charge-transfer. 相似文献
72.
Bianco A Pantarotto D Hoebeke J Briand JP Prato M 《Organic & biomolecular chemistry》2003,1(23):4141-4143
A peptide analogue from a histone H3 protein containing the L-fulleropyrrolidino-glutamic acid has been prepared by a solid-phase approach and has been fully characterized. By molecular modelling it was verified that this peptide derivative is able to retain a binding capacity to the MHC (major histocompatibility complex) molecule similar to that of the cognate epitope. 相似文献
73.
Poschalko A Rohr T Gruber H Bianco A Guichard G Briand JP Weber V Falkenhagen D 《Journal of the American Chemical Society》2003,125(44):13415-13426
A novel SUcrose-Based Polymer support (SUBPOL) with tailored morphology suitable for the use in solid-phase peptide synthesis (SPPS) is described, and its application as a hydrophilic affinity matrix for the specific removal of fibrinogen from human plasma is demonstrated. After suspension polymerization of partly methacrylated 2,1':4,6-di-O-isopropylidene sucrose and subsequent removal of the protecting groups, hydrophilic spherical polymer beads were obtained. The morphology of the resulting resin was controlled by variation of the porogen as well as the average degree of substitution with respect to the methacryloyl groups of the monomer mixture. After introduction of amino groups for a permanent attachment of immobilized peptide ligands, prevention of unintended esterification during SPPS was achieved by silylation of remaining hydroxy groups. Alternatively, a Rink amide linker was introduced prior to SPPS to allow cleavage and subsequent analysis of the peptide assembled on the SUBPOL resins. Two hexapeptides of sequence kwiivw and hffflw, consisting of d-amino acids, as well as a 19-mer peptide corresponding to the sequence GSGVRGDFGSLAPRVARQL of the VP1 protein from the foot-and-mouse disease virus (FMDV) were successfully prepared both manually or in a semi-automated process on SUBPOL resins according to the Fmoc/tBu strategy. Yields and purities were comparable to peptides prepared on commercially available polystyrene resins. A specific affinity adsorbent containing the fibrinogen-binding pentapeptide GPRPK was prepared by SPPS on SUBPOL resins of different morphology, and the strong impact of the affinity matrix on adsorption performance was demonstrated. 相似文献
74.
Christopher W. Doble Jean-Paul Doignon Jean-Claude Falmagne Peter C. Fishburn 《Order》2001,18(4):295-311
One of the standard axioms for semiorders states that no three-point chain is incomparable to a fourth point. We refer to asymmetric relations satisfying this axiom as almost connected orders or ac-orders. It turns out that any relation lying between two weak orders, one of which covers the other for inclusion, is an ac-order (albeit of a special kind). Every ac-order is bracketed in a natural way by two weak orders, one the maximum in the set of weak orders included in the ac-order, and the other minimal, but not necessarily the minimum, in the set of weak orders that include the ac-order. The family of ac-orders on a finite set with at least five elements is not well graded (in the sense of Doignon and Falmagne, 1997). However, such a family is both upgradable and downgradable, as every nonempty ac-order contains a pair whose deletion defines an ac-order on the same set, and for every ac-order which is not a chain, there is a pair whose addition gives an ac-order. 相似文献
75.
Mbarka Mabrouki Marc Aiguier Jean-Paul Comet Pascale Le Gall Adrien Richard 《Mathematics in Computer Science》2011,5(3):263-288
In the course of understanding biological regulatory networks (BRN), scientists usually start by studying small BRNs that
they believe to be of particular importance to represent a biological function, and then, embed them in a larger network.
Such a reduction can lead to neglect relevant regulations and to study a network whose properties can be very different from
the properties of this network viewed as a part of the whole. In this paper we study, from a logical point of view, on which
conditions concerning both networks, properties can be inherited by BRNs from sub-BRNs. We give some conditions on the nature
of the network embeddings ensuring that dynamic properties on the embedded sub-BRNs are preserved at the level of the whole
BRN. 相似文献
76.
Aurore Richel Pascal Laurent Bernard Wathelet Jean-Paul Wathelet Michel Paquot 《Comptes Rendus Chimie》2011,14(2-3):224-234
The valorisation of carbohydrates arising from the hydrolysis of renewable feedstocks (i.e., lignocellulosic biomass) is nowadays an area of utmost interest. In this context, the implementation of fast, expeditious and cost-effective methodologies for the modification of these naturally occurring compounds is becoming a prerequisite. With this aim, the application of microwaves has gained progressive attention in laboratories for making a range of high-added value sugars derivative scaffolds. The advantages of microwaves are numerous, and include enhancement of reaction rates and yields, combined with improved regio-, chemo- and anomeric selectivities. 相似文献
77.
78.
79.
D. Akitt H. J. J. Seguin M. R. Cervenan S. K. Nikumb 《Applied physics. B, Lasers and optics》1990,51(5):326-328
An on-line, electronic feedback approach for automatic alignment of a laser resonator is described. A measure of the resonator alignment error is derived by partitioning a 1% sample of the laser output into quadrants, and using standard electronic circuits to compare the average power present in each quadrant. A motorized X — Y alignment system is then used to implement the alignment changes required to maintain optimum output quality from the laser. The system is shown capable of stabilizing the output power in each quadrant of the beam to within about 2% of the optimum level. 相似文献
80.
Frédéric Lagoutière Nicolas Seguin Takéo Takahashi 《Journal of Differential Equations》2008,245(11):3503-3544
We analyze a one-dimensional fluid-particle interaction model, composed by the Burgers equation for the fluid velocity and an ordinary differential equation which governs the particle movement. The coupling is achieved through a friction term. One of the novelties is to consider entropy weak solutions involving shock waves. The difficulty is the interaction between these shock waves and the particle. We prove that the Riemann problem with arbitrary data always admits a solution, which is explicitly constructed. Besides, two asymptotic behaviors are described: the long-time behavior and the behavior for large friction coefficients. 相似文献