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991.
A new theoretical model describing the emission and absorption dynamics in an ensemble of molecules under intense coherent pulsed pumping is developed on the basis of the concepts of cooperative light-induced luminescence (CLIL). The CLIL development is described within the framework of formalism of the system density matrix in the space of photon wave functions. It is shown that the fast growth of CLIL relates to the development of coherent states of the quantum field in the area of efficient cooperative interactions of molecules (coherence volume). A system of equations for the calculation of CLIL energy, population of excited states, and optical absorption of the system in dependence on the laser pump energy density is solved. The theoretical results obtained are in good agreement with the experimental data. 相似文献
992.
R. Euler B. Fricke T. Morović W. -D. Sepp A. Rosén 《Zeitschrift für Physik A Hadrons and Nuclei》1980,297(2):101-104
Total energy SCF calculations were performed for noble gas difluorides in a relativistic procedure and compared with analogous non-relativistic calculations. The discrete variational method with numerical basis functions was used. Rather smooth potential energy curves could be obtained. The theoretical Kr-F and Xe-F bond distances were calculated to be 3.5 a.u. and 3.6 a.u. which should be compared with the experimental values of 3.54 a.u. and 3.7 a.u. Although the dissociation energies are off by a factor of about five it was found that ArF2 may be a stable molecule. Theoretical ionization energies for the outer levels reproduce the experimental values for KrF2 and XeF2 to within 2 eV. 相似文献
993.
Pure adaptive search constructs a sequence of points uniformly distributed within a corresponding sequence of nested regions of the feasible space. At any stage, the next point in the sequence is chosen uniformly distributed over the region of feasible space containing all points that are equal or superior in value to the previous points in the sequence. We show that for convex programs the number of iterations required to achieve a given accuracy of solution increases at most linearly in the dimension of the problem. This compares to exponential growth in iterations required for pure random search. 相似文献
994.
The differential systems satisfied by orthogonal polynomials with arbitrary semiclassical measures supported on contours in
the complex plane are derived, as well as the compatible systems of deformation equations obtained from varying such measures.
These are shown to preserve the generalized monodromy of the associated rank-2 rational covariant derivative operators. The
corresponding matrix models, consisting of unitarily diagonalizable matrices with spectra supported on these contours are
analyzed, and it is shown that all coefficients of the associated spectral curves are given by logarithmic derivatives of
the partition function or, more generally, the gap probabilities. The associated isomonodromic tau functions are shown to
coincide, within an explicitly computed factor, with these partition functions.
Research supported in part by the Natural Sciences and Engineering Research Council of Canada, the Fonds FCAR du Québec and
EC ITH Network HPRN-CT-1999-000161. 相似文献
995.
B. I. Suleimanov 《Journal of Experimental and Theoretical Physics》2002,95(5):944-956
Solutions of the equations v x+v 3?tv+x=0 and v xx=v 3? tv+x, which describe the nucleation of domain walls occurring in the neighborhood of cusps of slowly varying equilibriums, are analyzed. Examples related to the diffusion in smoothly inhomogeneous media are considered. 相似文献
996.
997.
We build explicitly an infinite number of equilibrium solutions of unloaded Marguerre–von Kármán membrane shells. This construction is based upon the existence of three elementary solutions, together with the solution of a Monge–Ampère equation associated with a partition of the reference configuration of the shell. To cite this article: A. Léger, B. Miara, C. R. Acad. Sci. Paris, Ser. I 335 (2002) 649–654. 相似文献
998.
M. Piana M. Arrabito S. Bodoardo A. D'Epifanio D. Satolli F. Croce B. Scrosati 《Ionics》2002,8(1-2):17-26
Solid State Reaction was employed to prepare phospho-olivines LiMPO4 (where M=Fe, Co) as pure phase and LiNiPO4 in presence of foreign phases, as cathodic materials for lithiumions batteries. The relationship between structural, morphological
and electrochemical properties were investigated in the case of LiFePO4. Structural investigation has been carried out by means of X-ray powder diffraction (XRPD) and Rietveld refinement. The influence
on the morphology of annealing temperature, different flowing gas mixture and addition of ascorbic acid during the synthesis,
has been analysed via scanning electron microscopy. The electrochemical cycling performances on LiFePO4 showed to be positively affected by the modifications of the experimental conditions. Cyclic voltammetry showed a good reversibility
during insertion-extraction mechanism, in particular in presence of additives. LiCoPO4 and LiNiPO4 are interesting as high voltage cathode materials for Li-ion batteries and have been taken into account, but their electrochemical
operating conditions are still to be optimised. In the case of LiNiPO4 it is very difficult to obtain, by solid state synthesis, suitable purity powders, having a grain size small enough to exploit
it usefully as cathodic material for Li-ion cells.
Paper presented at the 8th EuroConference on Ionics, Carvoeiro, Algarve, Portugal, Sept. 16 – 22, 2000. 相似文献
999.
Juan E. Nápoles Valdés 《Results in Mathematics》2002,41(3-4):337-345
Qualitative behavior of second order nonlinear differential equations of type y″+p(t)y+q(t)f(y)=0, is studied. It includes properties such as positivity, number of zeros, oscillating nature, boundedness and monotonicity of the solutions. 相似文献
1000.