Reversible hydrocarbon/perfluorocarbon phase-switching of [Ru(bipy)3]2+ driven by supramolecular heteromeric fluorous carboxylate-carboxylic acid H-bond interactions

The Ru(bipy)(3) dication is efficiently and reversibly transferred into perfluorocarbons due to the formation of a highly fluorophillic hydrogen-bonded fluorous carboxylate-carboxylic acid counter-anion, whilst retaining key luminescence and photosensitizer characteristics, for example in singlet oxygen production.     

Selective conversion of {Mo132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative [Te5Mo15O57](8-). A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst

{Mo(132)} Keplerate anion reacts with tellurites to give a soluble precursor to produce in hydrothermal conditions single-phase M1 MoVTeO light-alkanes oxidation catalyst. Characterization of this Te-containing intermediate by single-crystal X-ray diffraction, (125)Te NMR, UV-visible and redox titration reveals a molybdotellurite anion as a crown-capped Keggin derivative.     

The accuracy of tomographic particle image velocimetry for measurements of a turbulent boundary layer

To investigate the accuracy of tomographic particle image velocimetry (Tomo-PIV) for turbulent boundary layer measurements, a series of synthetic image-based simulations and practical experiments are performed on a high Reynolds number turbulent boundary layer at Re_θ = 7,800. Two different approaches to Tomo-PIV are examined using a full-volume slab measurement and a thin-volume “fat” light sheet approach. Tomographic reconstruction is performed using both the standard MART technique and the more efficient MLOS-SMART approach, showing a 10-time increase in processing speed. Random and bias errors are quantified under the influence of the near-wall velocity gradient, reconstruction method, ghost particles, seeding density and volume thickness, using synthetic images. Experimental Tomo-PIV results are compared with hot-wire measurements and errors are examined in terms of the measured mean and fluctuating profiles, probability density functions of the fluctuations, distributions of fluctuating divergence through the volume and velocity power spectra. Velocity gradients have a large effect on errors near the wall and also increase the errors associated with ghost particles, which convect at mean velocities through the volume thickness. Tomo-PIV provides accurate experimental measurements at low wave numbers; however, reconstruction introduces high noise levels that reduces the effective spatial resolution. A thinner volume is shown to provide a higher measurement accuracy at the expense of the measurement domain, albeit still at a lower effective spatial resolution than planar and Stereo-PIV.     

Global modes in a confined impinging jet: application to heat transfer and control

We investigate the stability and control of a plane, laminar jet impinging on a flat plate in a channel, a geometry used to cool down a hot wall with a cold air jet in many industrial configurations. The global stability analysis indicates that, even for a strong confinement, the two-dimensional (2-D) steady flow is unstable to three-dimensional (3-D), steady perturbations. In the simplest limit case where dilatation effects are neglected, we show that the development of the instability induces a significant spanwise modulation of the heat flux at the impacted wall. To control the leading global mode, we propose adjoint-based 3-D harmonic and 2-D steady forcing in the bulk or at the wall. We show for instance that the unstable mode is controllable using a spanwise uniform blowing at the upper wall, in a specific domain corresponding to the footprint of the upper recirculating bubble. These techniques are applied to a novel open-loop control, in which we introduce into the flow a small airfoil, modelled by the lift force it exerts on the flow.     

A Simple Procedure for the Preparation of Chiral ‘Tris(hydroxymethyl)methane’ Derivatives

The aldol adducts 1a – 13a of R,R-2(tertbutyl)-6-methyl-1,3-dioxan-4-one (from 3-hydroxybutanoic acid) to aldehydes, single diastereoisomers obtained as described previously, are acetylated or benzoylated to the corresponding esters 1b – 5b and 6c – 13c , respectively, which in turn are reduced with LiAlH₄ to the title compounds 14 – 24 . The enantiomerically pure triols thus available may be useful as chiral building blocks, as auxiliaries for enantioselective reactions, and as center pieces for chiral dendrimers.     

Periodic Duffing delay equations with state dependent impulses

Conditions are obtained for the Duffing equation with delay and state dependent impulses to admit a periodic solution.     

Metallic glasses: Mössbauer contribution, physical properties and applications

We report first on the essential contributions of Mössbauer spectrometry to investigate iron-based metallic glasses. In addition to the analysis of the distributions of hyperfine data in terms of Fe coordination and neighbours, Mössbauer spectrometry is able to estimate the magnetic anisotropy from the magnetic texture, which can be correlated to the solidification process. After an overview of the different physical properties of the amorphous metallic alloys we also present their most advanced applications.