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31.
We report on an innovative configuration of a supercontinuum laser based on an Yb-doped nonlinear microstructured fiber. Due to this particular fiber design combining amplification and nonlinear properties, a wideband output spectrum is generated in the fiber under the Q-switched regime. By exploiting stimulated Brillouin scattering, high peak power pulses are achieved and contribute to a spectral broadening due to a nonlinear wavelength conversion process. Both infrared (1000-1200 nm) and visible (650-750 nm) spectra are generated with an average power of 200 mW. 相似文献
32.
33.
Ganjehi L Marchiano R Coulouvrat F Thomas JL 《The Journal of the Acoustical Society of America》2008,124(1):57-71
The influence of the planetary boundary layer on the sonic boom received at the ground level is known since the 1960s to be of major importance. Sonic boom propagation in a turbulent medium is characterized by an increase of the mean rise time and a huge variability. An experiment is conducted at a 1:100,000 scale in water to investigate ultrasonic shock wave interaction with a single heterogeneity. The experiment shows a very good scaling with sonic boom, concerning the size of the heterogeneities, the wave amplitude, and the rise time of the incident wave. The wave front folding associated with local focusing, and its link to the increase of the rise time, are evidenced by the experiment. The observed amplification of the peak pressure (by a factor up to 2), and increase of the rise time (by up to about one magnitude order), are in qualitative agreement with sonic boom observations. A nonlinear parabolic model is compared favorably to the experiment on axis, though the paraxial approximation turns out less precise off axis. Simulations are finally used to discriminate between nonlinear and linear propagations, showing nonlinearities affect mostly the higher harmonics that are in the audible range for sonic booms. 相似文献
34.
Raquel Antón Hercilio Rivas Jean-Louis Salager 《Journal of Dispersion Science and Technology》2013,34(6):553-566
Anionic and nonionic surfactants exhibit opposite changes in hydrophilicity with a change of temperature. This antagonism can be harnessed by the use of mixtures. The phase behavior and emulsion type are mapped on a temperature water-oil/ratio diagram for different anionic-nonionic mixtures. It is shown that the mixing can result in insensitivity to temperature of different kinds of emulsions. 相似文献
35.
Thomas F Gellon G Gautier-Luneau I Saint-Aman E Pierre JL 《Angewandte Chemie (International ed. in English)》2002,41(16):3047-3050
36.
The predictions of a nonequilibrium schematic mode-coupling theory developed to describe the nonlinear rheology of soft glassy materials have been numerically tested in a sheared binary Lennard-Jones mixture. In this Letter, we focus on the existence, behavior, and properties of an effective temperature T(eff) for the slow modes of the fluid, as defined from a generalized fluctuation-dissipation theorem. New, simple experimental protocols to access T(eff) are proposed, and one such experiment is numerically performed. Our results give strong support to the thermodynamic interpretation of T(eff) and make it experimentally accessible in a very direct way. 相似文献
37.
Marcel Baiwir Gabriel Llabrs Lon Christiaens Jean-Louis Piette 《Magnetic resonance in chemistry : MRC》1982,18(1):33-37
The 1H, 13C and 77Se chemical shifts have been measured for mononitrobenzo[ b ]selenophenes. For the homocyclic nuclei, the observed 1H- and 13C-values calculated from the empirical increments of nitrobenzene. Anomalous effects are observed in the 2- and 3-substituted derivatives and the nature of the Se? NO2 interactions in the former is discussed. 77Se chemical shifts of the 4-, 5- and 7-nitro derivatives are approximately correlated with the CNDO calculated electron densities; they also compare well with those of selenoanisoles and other phenyl alkyl selenides. The chemical shifts are also compared with the corresponding values in other heterocycles containing a selenophene moiety. 相似文献
38.
Andr Laurent Alain Marsura Et Jean-Louis Pierre 《Journal of heterocyclic chemistry》1980,17(5):1009-1017
A facile synthesis of aziridine is describe. It is the reaction between Grignard regents and α-hydroxoximes in toluene. The aziridine alchohols are cyclised into 2-oxo-oxathiazolidines. The use of the nuclear Overhauser effect allows the assignment of the relative configurations of these latter compounds and also the configuration of the aziridine alcohols. A proof of the Grignard reagent complex with the alcoolate id given by action of methylmagensium bromide with 2-phenyl 3-methanol azirine. The asymetrie insuction observed is discussed with a transition state involving this complex. 相似文献
39.
40.
Eve-Marie Rivoirard Paul Raret Andr Boucherle Claude Gey Jean-Louis Pierre 《Journal of heterocyclic chemistry》1979,16(2):327-332
Aziridines bearing a functionality on a ring carbon and an alkyl or deuteriomethyal group on nitrogen have been quaternized at different temperatures. The configurations of the resulting, stable, diastereomeric aziridinium ions have been assigned by Nuclear Overhauser effect. The stereoselectivity in quaternization is discussed. 相似文献