全文获取类型
收费全文 | 144篇 |
免费 | 0篇 |
专业分类
化学 | 103篇 |
力学 | 6篇 |
数学 | 21篇 |
物理学 | 14篇 |
出版年
2023年 | 1篇 |
2022年 | 1篇 |
2021年 | 2篇 |
2020年 | 2篇 |
2018年 | 1篇 |
2015年 | 1篇 |
2014年 | 4篇 |
2013年 | 6篇 |
2012年 | 10篇 |
2011年 | 13篇 |
2010年 | 1篇 |
2009年 | 4篇 |
2008年 | 4篇 |
2007年 | 6篇 |
2006年 | 8篇 |
2005年 | 17篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 3篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 1篇 |
1973年 | 1篇 |
1971年 | 6篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有144条查询结果,搜索用时 0 毫秒
51.
Bonnet-Ben Dhia Anne-Sophie; Mercier Jean-Francois 《The Quarterly Journal of Mechanics and Applied Mathematics》2007,60(4):397-421
We present a theoretical study of the resonances of a fluid–structureproblem, an elastic plate placed in a duct in the presence ofa compressible fluid. The case of a rigid plate has been largelystudied. Acoustic resonances are then associated to resonantmodes trapped by the plate. Due to the elasticity of the plate,we need to solve a quadratic eigenvalue problem in which theresonance frequencies k solve the equations (k) = k2, where are the eigenvalues of a self-adjoint operator of the formA + kB. First, we show how to study the eigenvalues locatedbelow the essential spectrum by using the min–max principle.Then, we study the fixed-point equations. We establish sufficientconditions on the characteristics of the plate and of the fluidto ensure the existence of resonances. Such conditions are validatednumerically. 相似文献
52.
Cantin K Rondeau-Gagné S Néabo JR Daigle M Morin JF 《Organic & biomolecular chemistry》2011,9(12):4440-4443
An amide-containing phenylacetylene macrocycle (PAM) has been synthesized and its gelation properties were studied in different solvents. Surprisingly, this macrocycle forms organogels at low concentration in many polar and apolar solvents. XRD and FTIR analysis suggest that this macrocycle forms stable supramolecular assemblies owing to H-bonding. Scanning electron microscopy analyses show the formation of bundles of nanofibrils, demonstrating the long-range organization of this material. 相似文献
53.
54.
Tran Thanh Tung Mickael Castro Tae Young Kim Kwang S. Suh Jean-Francois Feller 《Analytical and bioanalytical chemistry》2014,406(16):3995-4004
Hybrids of silver nanoparticle-decorated reduced graphene oxide (Ag-RGO) have been prepared with the use of poly(ionic liquid) (PIL) as a versatile capping agent to develop volatile organic compound (VOC) sensors. The hybrid materials of Ag-RGO/PIL were assembled into three-dimensional-laminated nanostructures, where spherical Ag nanoparticles with diameters between 50 and 300 nm were homogeneously distributed on the graphene sheets and interspaced between them. Ag-RGO/PIL sensors were fabricated by spray layer-by-layer technique and used to detect a set of polar (methanol, ethanol, methyl acetate, acetone and water) and non-polar (chloroform, dichlorobenzene, toluene and styrene) organic vapours. Much higher sensitivity and discriminability were obtained for polar vapours although non-polar ones could also be detected. In comparison with either simple reduced graphene oxide or carbon nanotubes (CNT) functionalised by PIL, the hybrid Ag-RGO/PIL-based sensors showed superior performances in terms of sensitivity, selectivity, stability and high reliability. For example, a signal-to-noise ratio up to 168 was obtained for 1 ppm of methanol and signals drift between two experiments spaced out in the time of 3 months was less than 3 %. It is expected that by extrapolation, a limit of detection at the parts per billion level can be reached. These results are promising to design e-noses based on high stability chemoresistive sensors for emerging applications such as anticipated diagnostic of food degradation or diseases by the analysis of VOC, some of them being in this case considered as biomarkers. 相似文献
55.
Alain Rolland Laurent Pedesseau Jacky Even Samy Almosni Cedric Robert Charles Cornet Jean Marc Jancu Jamal Benhlal Olivier Durand Alain Le Corre Pierre Rale Laurent Lombez Jean-Francois Guillemoles Eric Tea Sana Laribi 《Optical and Quantum Electronics》2014,46(10):1397-1403
In this paper, we present a comprehensive study of high efficiencies tandem solar cells monolithically grown on a silicon substrate using GaAsPN absorber layer. InGaAs(N) quantum dots and GaAsPN quantum wells have been grown recently on GaP/Si susbstrate for applications related to light emission. For photovoltaic applications, we consider the GaAsPN diluted nitride alloy as the top junction material due to both its perfect lattice matching with Si and ideal bandgap energy for current generation in association with the Si bottom cell. Numerical simulation of the top cell is performed. The effect of layer thicknesses and doping on the cell efficiency are evidenced. In these structures a tunnel junction (TJ) is needed to interconnect both the top and bottom sub-cells. We compare the simulated performances of different TJ structures and show that the GaP(n+)/Si(p+) TJ is promising to improve performances of the current–voltage characteristic. 相似文献
56.
57.
We develop simple rigorous techniques to estimate the behavior of general one-dimensional diffusion processes. Any one-dimensional diffusion process (with drift) can be mapped onto a symmetric diffusion through an explicit change of variable. For such processes we can estimate explicitly the diffusion exponent, the recurrence properties, and the large fluctuations. In a second part, we apply these results to different models (including the Sinaï random walk: diffusion in a random drift) and we show how the main features of the diffusion can be readily handled. 相似文献
58.
59.
Edward A. Nodiff Noriichi Oda Takanori Hayazaki Shuichiro Ina Toshiyuki Ito Sansei Nishibe Taisei Ueda Kenji Suzuki Martin Hausman Albert A. Manian 《Journal of heterocyclic chemistry》1968,5(2):165-177
The title compounds have been prepared as analytical standards for the identification of chlorpromazine metabolites in biological materials. Unequivocal structural proof of key compounds was accomplished by using at least two unrelated syntheses for each one. Resistance of some phenothiazines to preparation via classic Smiles rearrangement is discussed. More examples are offered of halogen-induced Smiles rearrangement. A rare example of phenothiazine polymorphism is presented. 相似文献
60.
Anthony Loussouarn Ali OuadiLaurence Morandeau Patricia RemaudRobin Giles Jean-Francois GestinJohn Webb 《Tetrahedron letters》2003,44(17):3539-3541
This study describes a simple, efficient synthesis pathway from trans-1,2-diaminocyclohexane that provides access to a new class of semi-rigid polyamine, polycarboxylic, and polyphosphonic ligands. The key steps in synthesis were the functionalisation (with an appropriate branching group) of a bisphosphonate diaminocyclohexane derivative and the introduction of methanephosphonic functions by a rarely used method. 相似文献