New measurement of the beta decay rate of the16N(0−)-16O(0+) transition

The beta decay rate of the¹⁶N(0^?; 120keV) →¹⁶O(0⁺, G.S.) transition has been remeasured. Our result (Λ _β =0.48±0.024 s^?1) is in excellent agreement with a previous measurement but strongly disagrees with another experimental value. The two agreeing results provide an experimental verification of the importance of meson exchange currents in 0⁺-0^? weak transitions. A value ofg _p/g _A～11–12 can be inferred from the correspondingΛ _μ rate.     

Etude des aldimines lithiees: II. Preparation d'aldehydes a groupement halogenovinylique. Application a la synthese d'oxo-3 cyclopentenes et d'aldehydes γ acetyleniques

The condensation of metallated aldimines, prepared from activated lithium dialkylamides, with different dihalogenoalkenes gives aldehydes with a halogenovinylic group. Acidic hydrolysis of these aldehydes leads directly to cyclopentenones. When treated with an excess of activated amide, halogenovinylic aldimines give γ-acetylenic aldehydes.     

Measurement of the beta spectrum of the 0− (120 keV) state of16N

We have measured the beta spectrum of the 0^?(120 keV,t _1/2=5.25 μs) state of¹⁶N. The response function of our detector has been measured, parameterized and then fitted to known spectral shapes taken under conditions close to those in the actual experiment. Using this response function and subtracting a 56 μs half-life background due to neutron capture in the detector, the measured 0^? spectrum compares well with the allowed shape for the 0^?→0⁺ spectrum plus a small contribution from the allowed 0^?→1^? transition.     

Study of vector mesons in dimuon production in a large kinematic region in p-W and S-W interactions at 200 GeV/c/nucleon

Results are presented on and production in p–W and S–W interactions at 200 GeV/c/nucleon measured via the dimuon decay in a large kinematic region. The data are normalized to the charged particle multiplicity in the same rapidity interval. They have been collected using the HELIOS/3 muon spectrometer at the CERN SPS. The ratio , where is the relevant resonance branching fraction, increases between proton and sulphur projectiles, and is somewhat enhanced going from peripheral to central S–W interactions. This results from an increase in the number of produced 's per charged particle. The ratio is measured in different intervals of p and rapidity. It is not clearly dependent on p, but is larger at higher rapidities. production, likewise normalized to charged multiplicity, is significantly lower in S–W compared to p–W interactions. Received: 27 October 1997 / Revised version: 5 March 1998 / Published online: 13 July 1998     

Iodide ion promotion of benzyl chloride-borate ester carbonylation reactions

Esters are isolated in fine yields from the rhodium(I) catalyzed reaction of benzyl chlorides with borate esters and carbon monoxide, in the presence of potassium iodide.     

Controlled chemical functionalization of multiwalled carbon nanotubes by kiloelectronvolt argon ion treatment and air exposure

The chemical and morphological modifications of multiwalled carbon nanotubes (MWCNTs), by 2 keV Ar(+) treatment, have been followed by field emission scanning (FESEM) and high-resolution transmission (HRTEM) electron microscopies and by X-ray photoelectron (XPS) and Raman spectroscopies. Morphological changes were followed, both in situ and on subsequent air exposure, and the data indicate that free radical defects, initially produced under low Ar(+) treatment doses ( approximately 10(13) ions/cm(2)), act as the nuclei for the formation of localized asperities that form along the walls of the CNTs. Continued treatment results in their stublike elongation that continues with further treatment, forming extensions under heavy treatment doses. The chemical changes that occur, on reaction with air, reveal that the defects initially created are secondary C atoms, formed when a single bond breaks; further treatment breaks an additional bond to form primary C atoms; free radical fragments, lost when the third bond breaks, condense on the free radical defects to form the asperities. The extent of primary and secondary C atoms, and thus their functionalization on air exposure, may be controlled by the extent of treatment, offering a method for the controlled surface functionalization of CNTs by low-energy Ar(+) treatment.     

Application of solution techniques for rapid growth of organic crystals

Single crystals of a pure hydrocarbon, 1,3,5-triphenylbenzene, with properties suitable for high-energy neutron detection were grown from toluene solutions using slow evaporation and temperature reduction methods with growth rates up to 10 mm/day. Application of the rapid growth technique developed earlier for growth of large water-soluble crystals shows that crystals of aromatic compounds can be successfully grown from solutions in large volumes required for their use as scintillator materials for radiation detection.     

Extended Picard complexes for algebraic groups and homogeneous spaces

For a smooth geometrically integral algebraic variety X over a field k of characteristic 0, we define the extended Picard complex $\mathrm{UPic}(\overline{X})$. It is a complex of length 2 which combines the Picard group $\mathrm{Pic}(\overline{X})$ and the group $U(\overline{X}):=\overline{k}{[\overline{X}]}^{\times }/{\overline{k}}^{\times }$, where $\overline{k}$ is a fixed algebraic closure of k and $\overline{X}=X{\times }_k\overline{k}$. For a connected linear k-group G we compute the complex $\mathrm{UPic}(\overline{G})$ (up to a quasi-isomorphism) in terms of the algebraic fundamental group ${\pi }_1(\overline{G})$. We obtain similar results for a homogeneous space X of a connected k-group G. To cite this article: M. Borovoi, J. van Hamel, C. R. Acad. Sci. Paris, Ser. I 342 (2006).