Correction of self-absorption spectral line and ratios of transition probabilities for homogeneous and LTE plasma

Expressions for fundamental spectral line parameters are reported for Gaussian and Lorentzian shape profiles for homogeneous plasma at equilibrium in presence of the self-absorption. These expressions for Lorentzian profiles are applied to the determination of the ratios of transition probabilities and the ratios of optical thicknesses by a new method that we propose in this article. The self-absorption is computed by spectral line profiles with a Simplex algorithm program fitting. Applications to some experimental lines illustrate the appropriate corrections.     

Structural changes in data communication in wireless sensor networks

Wireless sensor networks are an important technology for making distributed autonomous measures in hostile or inaccessible environments. Among the challenges they pose, the way data travel among them is a relevant issue since their structure is quite dynamic. The operational topology of such devices can often be described by complex networks. In this work, we assess the variation of measures commonly employed in the complex networks literature applied to wireless sensor networks. Four data communication strategies were considered: geometric, random, small-world, and scale-free models, along with the shortest path length measure. The sensitivity of this measure was analyzed with respect to the following perturbations: insertion and removal of nodes in the geometric strategy; and insertion, removal and rewiring of links in the other models. The assessment was performed using the normalized Kullback-Leibler divergence and Hellinger distance quantifiers, both deriving from the Information Theory framework. The results reveal that the shortest path length is sensitive to perturbations.     

应用多核固体核磁共振光谱与量子化学计算的方法研究层状的过渡金属硫化物

层状的过渡金属硫化物及其衍生物在许多领域内有着广泛的应用前景. 具体应用包括催化、陶瓷、润滑、能量储存、半导体、电子与光学器件. 该文报道了作者最近用固体核磁共振光谱的方法来表征几种有代表性的过渡金属硫化物(MS₂: M=Zr, Ti, W, Mo和Ta)的结果. 并在不同的磁场强度下（21.1、14.1、9.4 T）成功地获取了³³S, ^47/49Ti,⁹¹Zr,⁹5Mo 在天然丰度下的固体核磁共振光谱. 为了帮助解释实验结果,同时还进行了量子化学计算. 实验及理论计算的结果都表明³³S, ^47/49Ti, ⁹¹Zr, ⁹⁵Mo 的固体核磁共振参数对于这些核的局部几何与电子环境非常敏感.     

Synthesis of the 1,2-Dihydro 1,2-Δ3−azaphosphorines

Abstract

1,2-Dihydro 1,2-Δ³? azaphosphorines were prepared by reaction of dichlorophenylphosphine with two equivalents of imines. 2-Oxo 1,2-azaphospholenes were also obtained in some cases.     

Nonlinear optical polymers. Second harmonic generation in corona-poled thin films

The synthesis and second harmonic coefficients, d_3,1 and d_3,3 as well as the related susceptibilities χ⁽²⁾_zzz of five series of (NLO-dye methacrylate)-(methyl methacrylate) copolymers were investigated. The NLO-chromophores bound covalently to the polymer backbone were 5-(2,2-dicyanovinyl)-or 4-(2-cyano-2-methoxycarbonyl)vinyl-1-piperidino-2-thiophene (P₁ and P₂), 4-nitro-4′-alkoxy-stilbene (P₃), 4-nitro-3′-methoxy-4′-alkoxystilbene (P₄) and 4-nitro-4′-alkoxy-α-cyano stilbene (P₅). The second order nonlinear optical properties of corona-poled aligned thin polymer films, using a needle electrode in order to induce noncentrosymmetry, were evaluated. Nonlinear susceptibilities, χ⁽²⁾_zzz, of the films were derived from the analysis of full-angle Maker fringe patterns at 1064 nm, χ⁽²⁾_zzz values as high as 1.98×10⁻⁷ esu for P₂ copolymers and of 1.19×10⁻⁷ esu for P₃ copolymers could be achieved.     

Phosphorus donors in highly strained silicon

The hyperfine interaction of phosphorus donors in fully strained Si thin films grown on virtual Si(1-x)Ge(x) substrates with x< or =0.3 is determined via electrically detected magnetic resonance. For highly strained epilayers, hyperfine interactions as low as 0.8 mT are observed, significantly below the limit predicted by valley repopulation. Within a Green's function approach, density functional theory shows that the additional reduction is caused by the volume increase of the unit cell and a relaxation of the Si ligands of the donor.     

Exsolution of Nickel Nanoparticles from Mixed-Valence Metal Oxides: A Quantitative Evaluation by Magnetic Measurements

A fast and accurate experimental method is demonstrated to assess the fraction of exsolved metallic nanoparticles using magnetic measurements. As a benchmark, nanometric metallic nickel exsolved from (La_1−xSr_x)(Cr_1−yNi_y)O_3−δ is used for its high relevance as a solid oxide fuel cell component. The method is based on the difference in the magnetic response of the exsolved metallic nickel (ferromagnetic) and Sr-doped lanthanum chromite ceramic matrix (paramagnetic). The exsolved nickel results in coherent nanoparticles pinned on the surface of the Sr-doped lanthanum chromite ceramic matrix, as evidenced by electron microscopy analyses. The results obtained indicate the procedure as a fast and sensitive method to study the exsolution of ferromagnetic nanoparticles.