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41.
Jean-Baptiste Guilbaud Linda Cummings Yaroslav Z. Khimyak 《Macromolecular Symposia》2007,251(1):41-46
Summary: 13C solid-state NMR and 1H relaxation time measurements have been used to determine the structure of the crystalline and amorphous forms of the pharmaceutical drug indomethacin. Cross-polarization dynamics parameters were calculated for individual NMR resonances providing an insight into the mobility of functional groups in two forms of indomethacin. The changes of mobility in indomethacin/polyvinylpyrrolidone (PVP) formulation have been investigated via1H-13C solid-state NMR methods. Differences between the amorphous material and its crystalline counterpart have been observed. The γ-amorphous indomethacin rapidly crystallizes with time. It has been shown that encapsulation in the PVP stabilizes the amorphous form of the drug by preventing crystallization due to reduced mobility of the guest in the formulation. 相似文献
42.
Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alkenes is summarized. Mechanisms of rhenium-catalyzed hydrosilylation are discussed. 相似文献
43.
Jean-Baptiste d'Espinose de la Caillerie Christian Fretigny 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,133(2):273-280
An inversion of the REDOR signal to recover the dipolar couplings has been recently proposed [K. T. Muelleret al., Chem. Phys. Lett.242, 535 (1995)]: The corresponding integral transform was performed by tabulation of the kernel followed by numerical integration. After explicit determination of the inverse REDOR kernel by the Mellin transform method, we propose an alternative inversion method based on Fourier transforms. Representation of the inverse REDOR kernel by its asymptotic expansion reveals that the inverse REDOR operator is essentially a weighted sum of a cosine transform and of its derivative. Consequently, known properties of Fourier transforms can easily be transposed to the REDOR inversion, allowing for a precise discussion of the value of the method. Moreover, the first term of the asymptotic expansion leading to a derivative of a cosine transform, the REDOR inversion is found to be extremely sensitive to noise, thus considerably reducing the useful part of the theoretical dipolar window. 相似文献
44.
Jean-Baptiste Meilhan 《Topology and its Applications》2006,153(14):2709-2729
We study the Goussarov-Habiro finite type invariants theory for framed string links in homology balls. Their degree 1 invariants are computed: they are given by Milnor's triple linking numbers, the mod 2 reduction of the Sato-Levine invariant, Arf and Rochlin's μ invariant. These invariants are seen to be naturally related to invariants of homology cylinders through the Milnor-Johnson correspondence: in particular, an analogue of the Birman-Craggs homomorphism for string links is computed. The relation with Vassiliev theory is studied. 相似文献
45.
We derive a simple sufficient condition for a point a∈S?X be a local minimum of f: X → R on S. This condition is of the first order in its nature and takes into account the derivative (or some generalization of it) in a neighborhood of a. Applications like a sufficient condition for (a, b)∈ S × T ? X × Y be a saddle-point of a bivariate function f: X × Y ? R are also proposed. 相似文献
46.
This article deals with the use of computer algebra systems in mathematics secondary education. First, we present the global framework of a research project carried out in France with pupils of grades 9 to 12, from 1993 through 1995. Then we focus on a specific part of this project concerning two grade 9 classes of different mathematical ability taught by the same teacher. We briefly present the aims and organisation of DERIVE's use in the two classes, before embarking with more details on a specific topic: systems of linear equations. Finally, we present the data provided by the pupils' answers to a questionnaire taken at the end of the academic year; we use them for investigating pupils' assumptions about DERIVE's potential for mathematics learning, and compare these representations with those emerging from the entire population. 相似文献
47.
We discuss the dynamics of a bilayer membrane with partial slip boundary conditions between the monolayers and the bulk fluid. Using Onsager’s variational principle to account for the associated dissipations, we derive the coupled dynamic equations for the membrane height and the excess lipid density. The newly introduced friction coe?cients appear in the renormalized fluid viscosities. For ordinary lipid bilayer membranes, we find that it is generally justified to ignore the e?ects of permeation and parallel slip at the membrane surface. 相似文献
48.
Jean-Baptiste Baugros Cécile Cren-Olivé Barbara Giroud Jean-Yves Gauvrit Pierre Lantéri Marie-Florence Grenier-Loustalot 《Journal of chromatography. A》2009,1216(25):4941-4949
The study proposes an analytical method to quantify 10 alkylphenols and 12 pesticides at ultra-trace levels by liquid chromatography in reverse mode coupled to positive electrospray ionisation–tandem mass spectrometry. The extraction procedure from environmental solids was optimised by pressurised liquid extraction using acetonitrile:isopropanol (1:1, v/v). The influence of several extraction experimental factors, temperature, pressure, duration and number of cycles, related to the PLE was investigated by an original and efficient chemometric approach. The optimised extraction method (80 °C, 40 bar, 10 min, 1 cycle) exhibited recoveries between 67 and 127% with RSD mostly under 13%. The whole method was applied to real samples: sludge, suspended materials, atmospheric fallouts and roof deposit. Pollutant levels were between 1 μg kg−1 and 5.9 mg kg−1. 相似文献
49.
Kpotin Gaston A. Bédé Affoué Lucie Houngue-Kpota Alice Anatovi Wilfried Kuevi Urbain A. Atohoun Guy S. Mensah Jean-Baptiste Gómez-Jeria Juan S. Badawi Michael 《Structural chemistry》2019,30(6):2301-2310
Structural Chemistry - Malaria is an important disease causing many death in several countries of Africa and Asia. In these continents, some plants such as Garcinia cola are used to fight against... 相似文献
50.