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11.
Poullet JB Sima DM Van Huffel S Van Hecke P 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2007,186(2):293-304
Accurate and efficient filtering techniques are required to suppress large nuisance components present in short-echo time magnetic resonance (MR) spectra. This paper discusses two powerful filtering techniques used in long-echo time MR spectral quantitation, the maximum-phase FIR filter (MP-FIR) and the Hankel-Lanczos Singular Value Decomposition with Partial ReOrthogonalization (HLSVD-PRO), and shows that they can be applied to their more complex short-echo time spectral counterparts. Both filters are validated and compared through extensive simulations. Their properties are discussed. In particular, the capability of MP-FIR for dealing with macromolecular components is emphasized. Although this property does not make a large difference for long-echo time MR spectra, it can be important when quantifying short-echo time spectra. 相似文献
12.
Philippe Pinel Bertrand Thirion Sébastien Meriaux Antoinette Jobert Julien Serres Denis Le Bihan Jean-Baptiste Poline Stanislas Dehaene 《BMC neuroscience》2007,8(1):91
Background
Although cognitive processes such as reading and calculation are associated with reproducible cerebral networks, inter-individual variability is considerable. Understanding the origins of this variability will require the elaboration of large multimodal databases compiling behavioral, anatomical, genetic and functional neuroimaging data over hundreds of subjects. With this goal in mind, we designed a simple and fast acquisition procedure based on a 5-minute functional magnetic resonance imaging (fMRI) sequence that can be run as easily and as systematically as an anatomical scan, and is therefore used in every subject undergoing fMRI in our laboratory. This protocol captures the cerebral bases of auditory and visual perception, motor actions, reading, language comprehension and mental calculation at an individual level. 相似文献13.
Morgane Rosendale Jonathan Daniel Frdric Castet Paolo Pagano Jean-Baptiste Verlhac Mireille Blanchard-Desce 《Molecules (Basel, Switzerland)》2022,27(7)
Molecular-based Fluorescent Organic Nanoparticles (FONs) are versatile light-emitting nano-tools whose properties can be rationally addressed by bottom-up molecular engineering. A challenging property to gain control over is the interaction of the FONs’ surface with biological systems. Indeed, most types of nanoparticles tend to interact with biological membranes. To address this limitation, we recently reported on two-photon (2P) absorbing, red to near infrared (NIR) emitting quadrupolar extended dyes built from a benzothiadiazole core and diphenylamino endgroups that yield spontaneously stealth FONs. In this paper, we expand our understanding of the structure-property relationship between the dye structure and the FONs 2P absorption response, fluorescence and stealthiness by characterizing a dye-related series of FONs. We observe that increasing the strength of the donor end-groups or of the core acceptor in the quadrupolar (D-π-A-π-D) dye structure allows for the tuning of optical properties, notably red-shifting both the emission (from red to NIR) and 2P absorption spectra while inducing a decrease in their fluorescence quantum yield. Thanks to their strong 1P and 2P absorption, all FONs whose median size varies between 11 and 28 nm exhibit giant 1P (106 M−1.cm−1) and 2P (104 GM) brightness values. Interestingly, all FONs were found to be non-toxic, exhibit stealth behaviour, and show vanishing non-specific interactions with cell membranes. We postulate that the strong hydrophobic character and the rigidity of the FONs building blocks are crucial to controlling the stealth nano-bio interface. 相似文献
14.
Jean-Baptiste Hiriart-Urruty Jérôme Malick 《Journal of Optimization Theory and Applications》2012,153(3):551-577
Engineering sciences and applications of mathematics show unambiguously that positive semidefiniteness of matrices is the
most important generalization of non-negative real numbers. This notion of non-negativity for matrices has been well-studied
in the literature; it has been the subject of review papers and entire chapters of books. 相似文献
15.
Global Optimality Conditions in Maximizing a Convex Quadratic Function under Convex Quadratic Constraints 总被引:2,自引:0,他引:2
Jean-Baptiste Hiriart-Urruty 《Journal of Global Optimization》2001,21(4):443-453
For the problem of maximizing a convex quadratic function under convex quadratic constraints, we derive conditions characterizing a globally optimal solution. The method consists in exploiting the global optimality conditions, expressed in terms of -subdifferentials of convex functions and -normal directions, to convex sets. By specializing the problem of maximizing a convex function over a convex set, we find explicit conditions for optimality. 相似文献
16.
Sarah Djabarouti Pierre Duffau Fabien Xuereb Estibaliz Lazaro Carine Greib Jean-Baptiste Gordien Olivier Caubet Marie-Claude Saux Jean-François Viallard Jean-Luc Pellegrin Dominique Breilh 《Chromatographia》2009,70(5-6):939-945
Liquid chromatography coupled with mass spectrometry for the determination of total and unbound mycophenolic acid and its major metabolite in human plasma has been developed. Sample preparations were based on a fully automated solid-phase extraction process and ultrafiltration. Mass spectrometric data were acquired in a single-ion monitoring method. The analytes and nevirapine (internal standard) were well separated in an isocratic mode over 8 min. Validation study exhibited excellent linearity, with intra- and inter-day precision and accuracy of less than 12%. The assay was successfully applied to the pharmacokinetic study of mycophenolic acid in patients with autoimmune diseases. 相似文献
17.
The problem of estimating the number of hidden states in a hidden Markov model is considered. Emphasis is placed on cross-validated
likelihood criteria. Using cross-validation to assess the number of hidden states allows to circumvent the well-documented
technical difficulties of the order identification problem in mixture models. Moreover, in a predictive perspective, it does
not require that the sampling distribution belongs to one of the models in competition. However, computing cross-validated
likelihood for hidden Markov models for which only one training sample is available, involves difficulties since the data
are not independent. Two approaches are proposed to compute cross-validated likelihood for a hidden Markov model. The first
one consists of using a deterministic half-sampling procedure, and the second one consists of an adaptation of the EM algorithm
for hidden Markov models, to take into account randomly missing values induced by cross-validation. Numerical experiments
on both simulated and real data sets compare different versions of cross-validated likelihood criterion and penalised likelihood
criteria, including BIC and a penalised marginal likelihood criterion. Those numerical experiments highlight a promising behaviour
of the deterministic half-sampling criterion. 相似文献
18.
Mirvatte Francis Jean-Baptiste Renard 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(11):1766-1775
New polarization and brightness curves as a function of scattering angle are studied at λ=632.8 and 543.5 nm using PROGRA2 instruments (Propriétés Optiques des Grains Astronomiques et Atmosphériques) for four different kinds of soot and for two samples of carbon-black levitating in the cloud. The soot samples are also studied on the deposited surface. Two of the soot samples are issued from incomplete combustion of Toluene liquid solvent under two different combustion conditions. Two others are issued from a solid polymer. Polymethyl Methacrylate or PMMA under two different combustion conditions. These new studies are done using new more sensitive cameras than previous ones, allowing darker agglomerates to be detected. 相似文献
19.
Vincent Danos Jean-Baptiste Joinet Harold Schellinx 《Archive for Mathematical Logic》1995,33(6):387-412
Summary We define an optimal proof-by-proof embedding of intuitionistic sequent calculus into linear logic and analyse the (purely
logical) linearity information thus obtained.
CNRS URA 753
Supported by the Netherlands Organization for Scientific Research (NWO) 相似文献
20.