Dynamic behavior of photoablation products of corneal tissue in the mid-IR: a study with FELIX

2 . Dynamic parameters such as the extension of the ablation cloud, the initial velocity and momentum of the ablated particles as well as the ablation threshold, the ablated mass, and the particle size were investigated. The ablation plume was made visible with a stroboscopic technique. For a fluence of 3.1 J/cm² the average initial velocity of the ejected particles was deduced from the extension of the plume to range from 120–400 m/s. Measurements of the recoil momentum using a sensitive pendulum led to values between 0.5 and 2.0 mm g/s. All measured properties were related to the spectroscopically determined absorption coefficient of cornea α_cornea. Where absorption due to proteins is high (at λ=6.2 and 6.5 μm), ablated mass, velocity and recoil momentum behave according to α_cornea. For the first time, variations of the ablation plume from pulse to pulse were observed. Those, as well as the particle size, not only depend on the absorption coefficient, but also on the predominant absorber. Received: 4 November 1997/Revised version: 7 September 1998     

F/Si distance determination in fluoride-containing octadecasil by Hartmann–Hahn cross-polarization under fast magic-angle spinning

¹⁹F/²⁹Si Hartmann–Hahn continuous wave cross-polarization (CP) has been applied under fast magic-angle spinning (MAS) to a powder sample of octadecasil. Strong oscillations occur during CP on a sideband matching condition between the isolated ²⁹Si–¹⁹F spin pairs formed by the silicons in the D4R units and the fluoride anions. The magnitude of the dipolar coupling constant was deduced directly from the line-splitting between the intense singularities of the Pake-like patterns obtained by Fourier transformation of the oscillatory polarization transfer. The corresponding Si–F internuclear distance, r=2.62±0.05 Å, is found to be in very good agreement with the X-ray crystal structure and the value of 2.69±0.04 Å recently reported from rotational echo double resonance (REDOR) and transferred echo double resonance (TEDOR) nuclear magnetic resonance (NMR) experiments. Furthermore, the CP technique is still reliable under fast MAS where both REDOR and TEDOR sequences suffer from severe artefacts due to finite pulse lengths. In octadecasil, a spinning frequency of 14 kHz is shown to be necessary for an effective suppression of ¹⁹F–¹⁹F spin diffusion. The influences of experimental missettings and radiofrequency (RF) field inhomogeneity are taken into account.     

Tenth Peregrine breather solution to the NLS equation

In this paper we construct a particularly important solution to the focusing NLS equation, namely a Peregrine breather of the rank 10 which we call, P₁₀$P_{10}$ breather. The related explicit formula is given by the ratio of two polynomials of degree 110 with integer coefficients times trivial exponential factor. This formula drastically simplifies for the “initial values” namely for t=0$t=0$ or x=0$x=0$. This formula confirms a general conjecture saying that between all quasi-rational solutions of the rank N$N$ fixed by the condition that its absolute value tends to 1 at infinity and its highest maximum is located at the point (x=0,t=0)$(x=0,t=0)$, the P_N$P_N$ breather is distinguished by the fact that P_N(0,0)=2N+1$P_N(0,0)=2N+1$ and, in the aforementioned class of quasi-rational solutions, it is an absolute maximum. At the end we also make a few remarks concerning the rational deformations of P₁₀$P_{10}$ breather involving 2N−2$2N-2$ free real parameters chosen in a way that P_N$P_N$ breather itself corresponds to the zero values of these parameters although we have no intention to discuss the properties of these deformations here.     

Perturbation about the mean field critical point

We consider two models that are small perturbations of Gaussian or mean field models: the first one is a double well /4⁴ — /2² perturbation of a massless Gaussian lattice field in the weak coupling limit (0, proportional to ). The other consists of a spin 1/2 Ising model with long-range Kac type interactions; the inverse range of the interaction, , is the small parameter. The second model is related to the first one via a sine-Gordon transformation. The lattice ^d has dimensiond3.In both cases we derive an asymptotic estimate to first order (in or ²) on the location of the critical point. Moreover, we prove bounds on the remainder of an expansion in or around the Gaussian or mean field critical points.The appendix, due to E. Speer, contains an extension of Weinberg's theorem on the divergence of Feynman graphs which is used in the proofs.Supported by NSF Grant # MCS 78-01885Supported by NSF Grant # PHY 78-15920     

Epitaxial relationships between Al,Ag and GaAs{001} surfaces

Detailed results concerning the orientation of Al and Ag layers grown by MBE onto GaAs{001} surfaces are reported. The observed crystallographic relationships have been found to depend only on the growth temperature in the case of Ag, while for Al the situation is more complex. Possible effects of other parameters such as structure and stoichiometry of the starting GaAs surface and growth rate, are discussed and compared with other results recently reported.     

The Boolean Prime Ideal Theorem Plus Countable Choice Do Not Imply Dependent Choice

Two Fraenkel-Mostowski models are constructed in which the Boolean Prime Ideal Theorem is true. In both models, AC for countable sets is true, but AC for sets of cardinality 2 and the 2m = m principle are both false. The Principle of Dependent Choices is true in the first model, but false in the second. Mathematics Subject Classification: 03E25, 03E35, 04A25.     

Un théorème de représentation pour les martingales discontinues

We consider a fixed integer-valued random measure (also called a random point process). We represent any local martingale as the sum of a stochastic integral with respect to this random measure, and of a local martingale which does not jump on the support of the random measure.     

First excitations of the spin 1/2 Heisenberg antiferromagnet on the kagomé lattice

We study the exact low energy spectra of the spin 1/2 Heisenberg antiferromagnet on small samples of the kagomé lattice of up to N=36 sites. In agreement with the conclusions of previous authors, we find that these low energy spectra contradict the hypothesis of Néel type long range order. Certainly, the ground state of this system is a spin liquid, but its properties are rather unusual. The magnetic () excitations are separated from the ground state by a gap. However, this gap is filled with nonmagnetic () excitations. In the thermodynamic limit the spectrum of these nonmagnetic excitations will presumably develop into a gapless continuum adjacent to the ground state. Surprisingly, the eigenstates of samples with an odd number of sites, i.e. samples with an unsaturated spin, exhibit symmetries which could support long range chiral order. We do not know if these states will be true thermodynamic states or only metastable ones. In any case, the low energy properties of the spin 1/2 Heisenberg antiferromagnet on the kagomé lattice clearly distinguish this system from either a short range RVB spin liquid or a standard chiral spin liquid. Presumably they are facets of a generically new state of frustrated two-dimensional quantum antiferromagnets. Received: 27 November 1997 / Accepted: 29 January 1998     

Characterization of nonstoichiometric nickel manganite spinels NixMn3−x□3δ/4O4+δ by temperature programmed reduction

Cation deficient spinels Ni_xMn_3−x□_3δ/4O_4+δ (0≤x≤1) have been prepared by thermal decomposition of mixed oxalates Ni_x/3Mn_(3−x)/3(C₂O₄)·nH₂O in air at 623 K. They have been characterised by temperature programmed reduction (TPR) under H₂, the reaction being followed by gravimetric and powder X-ray diffraction measurements. It has been shown that TPR proceeds in several steps. The first steps correspond to the loss of nonstoichiometric oxygen leading to the formation of a stoichiometric oxide. During the following stages the manganese cations are reduced, causing the spinel structure to be destroyed, and the formation of solid solution of NiO in a cubic MnO. Subsequently, Ni²⁺ cations undergo a reduction to metallic nickel, and, finally, a mixture of nonstoichiometric MnO_1−δ and metallic nickel is formed. These oxides contain a high level of vacancies which vary with the nickel content with a maximum of δ≈1 near x=0.6. This nonstoichiometry is ascribed both to the presence of Ni³⁺ and excess of Mn⁴⁺.     

On the Distribution of Free Path Lengths¶for the Periodic Lorentz Gas

Consider the domain