Conductivite electrique des magnetites finement divisees substituees a l'aluminium et au chrome

The magnetites substituted for aluminium and chromium show a high conductivity decrease as well as a change in the conduction type under vacuum when passing from the inverse to the normal spinel during substitution. This type of conduction is confirmed by the study of oxygen chemisorption at temperatures close to room temperature. At higher temperatures, volume oxidation is accompanied by a sharp change in conductivity, which differs depending on whether the spinel is inverse or normal.     

Heterocycles contenant du phosphore-XXI. Etude par RMP de déeriveés de l'oxazaphospholane-l,3,2: I-Analyse des spectres des composksés non substitués en 4 et 5.

The PMR spectra of the title 1,3,2-oxazaphospholane derivatives present an ABKLX pattern. The subspectral analysis of such a system shows that there are eight solutions. INDOR experiments permit the establishment of the energy diagram and the selection of the correct solution.     

FTIR study of the reaction of ethyl radicals with O2 and Cl2 in air at 295 K

Using Fourier transform infrared spectroscopy, the ethene yield from the reaction of C₂H₅ radicals with O₂ has been determined to be 1.50 ± 0.09%, 0.85 ± 0.11%, and <0.1% at total pressures of 25, 50, and 700 torr, respectively. Additionally, the rate constant of the reaction of C₂H₅ radicals with molecular chlorine was measured relative to that with molecular oxygen. (1) A ratio k₆/k₇ = 1.99 ± 0.14 was measured at 700 torr total pressure which, together with the literature value of k₇ = 4.4 × 10^?12 cm³ molecule^?1s^?1, yields k₆ = (8.8 ± 0.6) × 10^?12 cm³ molecule^?1s^?1. Quoted errors represent 2σ. These results are discussed with respect to previous kinetic and mechanistic studies of C₂H₅ radicals.     

Electromagnetic annihilation of e+e− into quarkonium states with even charge conjugation

We calculate the production of narrow resonances with even charge conjugation ${}^3\text{P}{}_{\mathrm{J}}\text{=1,2}$ in e⁺e^? annihilation in the quarkonium and vectordominance models. We give unitarity bounds for $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{)}$ in terms of $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ γγ)}$ and $\text{Γ(}{}^3\text{P}{}_{\mathrm{J}}\text{→ e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{?}}\text{)}$. The electromagnetic production dominates through the neutral current at low energies independent of details of the model. For masses above 10 GeV the situation is reversed.     

Dilute solution studies of nitrogen-substituted polyurethanes

A high molecular weight linear polyurethane was prepared by the polyaddition of equimolar amounts of ethylene glycol and methylene bis(4-phenyl isocyanate). Varying amounts of the labile carbamate protons of the polyurethane backbone were substituted by a number of groups of varying length and composition. The resultant grafted or nitrogen-substituted polyurethanes were then studied viscometrically in both polymer solvent and in a polymer solvent—nonsolvent mixture. The configuration of the nitrogen-substituted polyurethane was found to be dependent upon the number and length of pendent branches.     

Multipion production below 1.1 GeV by e+e− annihilation

The production of multipion events by e⁺e^? annihilation has been measured at centre of mass energies 915,990 and 1076 MeV. Both channels e⁺e^?→π⁺π^?π^o and e⁺e^?→π⁺π^?π⁺π^? have been analysed. An energy threshold effect analysed. An energy threshold effect around 919 MeV (m_ω + m_π^o) has been evidenced for the π⁺π^?π^oπ^o channel and the cross section is consistent with the quasi two-body process e⁺e^?→ωπ^o. The cross section for π⁺π^?π⁺π^? is lower by an order of magnitude and increases with the energy.     

Etude Conformationnelle par Résonance Magnétique Nucléaire Protonique des Dérivés de la O-Isopropylidène-2′,3′ Adénosine

Conformational analysis using ¹H n.m.r. data (δ, ³J and NOE) has been carried out on several derivatives of 2′,3′,-O-isopropylideneadenosine bearing various substituents at positions C-5′, C-8 and N-6. Conformational modifications are assigned to specific interactions between the sugar and purine moieties and also to solvent effects.