排序方式: 共有34条查询结果,搜索用时 375 毫秒
21.
R. E. Ansorge B. ?sman C. N. Booth L. Burow P. Carlson R. S. DeWolf B. Eckart G. Ekspong C. Fuglesang J. Gaudaen C. Geich-Gimbel B. Holl R. Hospes K. Jon-And D. P. Johnson F. Lotse N. Manthos D. J. Munday J. E. V. Ovens W. Pelzer J. G. Rushbrooke H. Schmickler F. Triantis L. Van Hamme C. Walck C. P. Ward D. R. Ward C. J. S. Webber T. O. White G. Wilquet N. Yamdagni UA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,37(2):191-213
We present data on two-particle pseudorapidity and multiplicity correlations of charged particles for non single-diffractive \(p\bar p - collisions\) at c.m. energies of 200, 546 and 900 GeV. Pseudorapidity correlations interpreted in terms of a cluster model, which has been motivated by this and other experiments, require on average about two charged particles per cluster. The decay width of the clusters in pseudorapidity is approximately independent of multiplicity and of c.m. energy. The investigations of correlations in terms of pseudorapidity gaps confirm the picture of cluster production. The strength of forward-backward multiplicity correlations increases linearly with ins and depends strongly on position and size of the pseudorapidity gap separating the forward and backward interval. All our correlation studies can be understood in terms of a cluster model in which clusters contain on average about two charged particles, i.e. are of similar magnitude to earlier estimates from the ISR. 相似文献
22.
The influence of particle size on near-infra red (NIR) spectra is typically considered a 'nuisance factor' which many scatter correction methods attempt to eliminate, e.g., multiplicative scatter correction. However, particle size is a key issue in the formulation of many pharmaceutical products and has a profound effect on the behaviour of both raw materials and drug substances during formulation. NIR has already been demonstrated as a potential alternative particle sizing technique to current accepted methodology. This investigation assessed several chemometric approaches that model this information, using lactose monohydrate as the raw material. A variety of modelling techniques were applied to both zero order and second derivative spectra namely multiple linear regression, partial least squares, principal component regression and artificial neural networks. One further data transformation evaluated was polar coordinates, although no statistical data were generated. Typically, cross-validation root mean square errors of calibration and cross-validation root mean square errors of prediction of approximately 5 microns were calculated for all of the modelling techniques. These values are comparable to those associated with the reference technique (laser diffractometry). Correlation coefficients of approximately 0.98 for all techniques were also calculated. The predictive abilities for models generated using second derivative spectra were found to be comparable to those obtained using zero order spectra. 相似文献
23.
The contributions made to the Working Group activities on neutrinos and astrophysics are summarized in this article. The topics
discussed were inflationary models in Raman-Sundrum scenarios, ultra high energy cosmic rays and neutrino oscillations in
4 flavour and decaying neutrino models. 相似文献
24.
Isuri U. Jayasooriya Abolghasem Bakhoda Rachel Palmer Kristi Ng Nour L. Khachemoune Jeffery A. Bertke Timothy H. Warren 《Chemical science》2021,12(47):15733
Commercially available benzophenone imine (HN CPh2) reacts with β-diketiminato copper(ii) tert-butoxide complexes [CuII]–OtBu to form isolable copper(ii) ketimides [CuII]–N CPh2. Structural characterization of the three coordinate copper(ii) ketimide [Me3NN]Cu–N CPh2 reveals a short Cu-Nketimide distance (1.700(2) Å) with a nearly linear Cu–N–C linkage (178.9(2)°). Copper(ii) ketimides [CuII]–N CPh2 readily capture alkyl radicals R˙ (PhCH(˙)Me and Cy˙) to form the corresponding R–N CPh2 products in a process that competes with N–N coupling of copper(ii) ketimides [CuII]–N CPh2 to form the azine Ph2C N–N CPh2. Copper(ii) ketimides [CuII]–N CAr2 serve as intermediates in catalytic sp3 C–H amination of substrates R–H with ketimines HN CAr2 and tBuOOtBu as oxidant to form N-alkyl ketimines R–N CAr2. This protocol enables the use of unactivated sp3 C–H bonds to give R–N CAr2 products easily converted to primary amines R–NH2via simple acidic deprotection.Commercially available benzophenone imine (HN CPh2) reacts with β-diketiminato copper(ii) tert-butoxide complexes [CuII]–OtBu to form isolable copper(ii) ketimides [CuII]–N CPh2 that serve as intermediates in catalytic sp3 C−H amination via radical relay. 相似文献
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Dr. Joseph A. Wright Dr. Jamie N. T. Peck Dr. Stephen P. Cottrell Dr. Aušra Jablonskytė Dr. Vasily S. Oganesyan Prof. Christopher J. Pickett Dr. Upali A. Jayasooriya 《Angewandte Chemie (International ed. in English)》2016,55(47):14580-14583
The chemistry of metal hydrides is implicated in a range of catalytic processes at metal centers. Gaining insight into the formation of such sites by protonation and/or electronation is therefore of significant value in fully exploiting the potential of such systems. Here, we show that the muonium radical (Mu.), used as a low isotopic mass analogue of hydrogen, can be exploited to probe the early stages of hydride formation at metal centers. Mu. undergoes the same chemical reactions as H. and can be directly observed due to its short lifetime (in the microseconds) and unique breakdown signature. By implanting Mu. into three models of the [FeFe]‐hydrogenase active site we have been able to detect key muoniated intermediates of direct relevance to the hydride chemistry of these systems. 相似文献
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Ceacero-Vega AA Ruiz TP Gómez MF Roldán JM Navarro A Fernández-Liencres MP Jayasooriya UA 《The journal of physical chemistry. A》2007,111(28):6406-6419
The molecular structure of 2,6-dichlorostyrene has been analyzed at MP2 and DFT levels using different basis sets concluding in a nonplanar geometry. The influence of either the level of theory or the nature of the substituent has been assessed. The vinyl-phenyl torsion barrier has also been investigated as a function of level of theory. The ultimate factors responsible for the torsion barrier have been studied using two different partitioning schemes, i.e., the total electronic potential energy and the natural bond orbital, NBO. A topological analysis of the electron density within the atom-in-molecule, AIM, theory predicts soft intramolecular chlorine (ring)-hydrogen (vinyl) contacts when the system becomes planar. A first complete vibrational study has been performed using theoretical data and experimental vibrational frequencies from IR, Raman and, for the first time, inelastic neutron scattering, INS, spectra. The new assignment proposed is based on a scaled quantum mechanical, SQM, force field and the wavenumber linear scaling, WLS, approach. 相似文献
28.
Logeeshan Velmanickam Vidura Jayasooriya Dharmakeerthi Nawarathna 《Electrophoresis》2021,42(9-10):1060-1069
The detection and quantification of nucleic acid and proteomic biomarkers in bodily fluids is a critical part of many medical screening and diagnoses. However, majority of the current detection platforms are not ideal for routine, rapid, and low-cost testing in point-of-care settings. To address this issue, we developed a concept for a disposable universal point-of-care biosensor that can detect and quantify nucleic acid and proteomic biomarkers in diluted serum samples. The central tenet of sensing is the use of dielectrophoresis, electrothermal effects, and thermophoresis to selectively and rapidly isolate the biomarkers of interest in electrodes and then quantify using electrical impedance. When the sensor was applied to quantify microRNA and antigen biomarker molecules directly in diluted serum samples, it produced a LOD values in the fM range and sensitivity values from 1012 to 1015 Ω/M with a 30 min assay time and assay cost of less than $50 per assay. 相似文献
29.
Band splitting can be observed in the infrared spectra of metal complexes arising from the naturally occurring mixture of isotopes, and the use of these splittings in assigning metal-ligand vibrational modes is described. 相似文献
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