Synthesis and X-ray analysis of 1-((1S)-phenylethyl)-azetidine-(2R)-piperidinamide

The crystal and molecular structure of a new azetidine-2-carboxylic amide derivative is described. The structure was solved by direct methods and refined by least squares methods toR1=0.0393 for 4264 reflections (withI>2(I)) The structure consists of two independent molecules which are chemically the same with slight differences in geometry. Crystal data: C₁₇H₂₄N₂O, monoclinic, space groupP2₁,a=8.3782(4),b=20.0342(13),c=9.7769(8) Å, =109.687(6)°,V=1545.1(2)ų,Z=4.     

On the spectrum of the sum of generators for a finitely generated group

Let Γ be a finitely generated group. In the group algebra ℂ[Γ], form the averageh of a finite setS of generators of Γ. Given a unitary representation π of Γ, we relate spectral properties of the operator π(h) to properties of Γ and π. For the universal representationπ _un of Γ, we prove in particular the following results. First, the spectrum Sp(π _un (h)) contains the complex numberz of modulus one iff Sp(π _un (h)) is invariant under multiplication byz, iff there exists a character such that η(S)={z}. Second, forS ⁻¹=S, the group Γ has Kazhdan’s property (T) if and only if 1 is isolated in Sp(π _un (h)); in this case, the distance between 1 and other points of the spectrum gives a lower bound on the Kazhdan constants. Numerous examples illustrate the results.     

An in vitro investigation of human enamel wear by restorative dental materials

A radiometric method was applied to assess enamel wear by another enameland by restorative materials. The radioactive enamel was submitted to wearin a machine which allows sliding motion of an antagonistic surface in contactwith the radioactive enamel. The enamel wear was evaluated by measuring thebeta-activity of ³²P transferred to water from this irradiatedtooth. Results obtained indicated that dental porcelains cause pronouncedenamel wear when compared with that provoked by another natural enamel orby resin materials. Resin materials caused less enamel wear than another naturalenamel. Vickers microhardness data obtained for antagonistic materials showeda correlation with the wear caused to the enamel.     

Construction of functional porphyrin polystyrene nano-architectures by ATRP

A series of mono-functionalized metallo-porphyrin polystyrenes have been synthesized using atom transfer radical polymerization and their self-assembling behavior was studied by electron microscopy showing that the polystyrene tail-length influences the aggregate architecture.     

Spectroelectrochemical characterisation of poly[Ni(saltMe)]-modified electrodes

Electrogenerated polymers based on the nickel(II) complex 2,3-dimethyl-N,N'-bis(salicylidene)butane-2,3-diaminatonickel(II), poly[Ni(saltMe)], were characterised by in situ FTIR and UV/Vis spectroscopy and ex-situ EPR spectroscopy in order to gain insights into film structure, electronic states and charge conduction. The role of the nickel ions during film oxidation was probed by using EPR to study naturally abundant Ni and 61Ni-enriched polymers. The data from all the spectroscopic techniques are consistent, and clearly indicate that polymerisation and redox switching are associated with oxidative ligand based processes; coulometry suggests that one positive charge was delocalised through each monomer unit. EPR provided evidence for the non-direct involvement of the metal in polymer oxidation: the polymer is best described as a polyphenylene-type compound (conducting polymer), rather than an aggregation of nickel complexes (redox polymer), and the main charge carriers are identified as polarons. An explanation for the high electrochemical stability and conductivity of poly[Ni(saltMe)] with respect to that of poly[Ni(salen)] is proposed. based on stereochemical repulsion between monomeric units; this can impose a less compact supramolecular structure on polymers with bulkier substituents.