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51.
CuII immobilized on aminated ferrite nanoparticles by 2‐aminoethyl dihydrogen phosphate (Fe3O4@AEPH2‐CuII) was prepared and characterized using FT‐IR, TGA, TEM, EDX, VSM, XRD, CHN and ICP techniques. The easily prepared heterogeneous nanocatalyst demonstrated a significant catalytic performance for the transformation of aldoximes to nitriles that is far superior to previously reported methods. The reaction allows for the conversion of a wide variety of aldoximes including aromatic, aliphatic and heterocyclic aldoximes in good to excellent yields (50–98%). High efficiency, mild reaction conditions, easy work‐up, operational simplicity, simple purification of products and safe handling of the catalyst are important advantages of this method. In addition, the environmentally benign heterogeneous nanocatalyst can be easily recovered from reaction mixtures using an external magnet and reused several times without any loss of activity. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
52.
Soodabeh Rezazadeh Batool Akhlaghinia Elaheh K. Goharshadi Hossein Sarvari 《中国化学会会志》2014,61(10):1108-1114
The selective reduction of nitro compounds by treatment with bimetallic Fe‐Ni nanoparticles (NPs) and tungestophosphoric acid hydrate (H3PW12O40.×H2O) in H2O is reported. The method has been applied to a broad range of nitro compounds with different sensitive functionalities, including halides, carbonyl, hydroxyl, aldehyde, methyl, acetyl, nitrile, and ester substituents with excellent yields. The reaction yielded single product in all cases with very high yield. The simple experimental procedure and easy purification make the protocol advantageous. 相似文献
53.
Majid Khan Muhammad Asif Gondal Syeda Iram Batool 《Computational & Mathematical Organization Theory》2013,19(4):446-459
In this article, we suggest modified Laplace decomposition method for analytical solution of eighth-order boundary value problems (BVPs). The numerical application indicates the effectiveness and stability of the proposed algorithm. The efficiency of proposed method is examined with the help of linear and nonlinear problems. 相似文献
54.
Muhammad Akhyar Farrukh Iqra Muneer Komal Mehmood Butt Sadaf Batool Nazia Fakhar 《中国化学会会志》2016,63(12):952-959
Lanthanum (La) supported on tin oxide‐titanium oxide (SnO2‐TiO2 ) nanoparticles were prepared by a sol–gel method followed by a hydrothermal method. Effect of different solvents (ethyl acetate, benzyl alcohol, ethylene glycol) on the particle size and catalytic activity was investigated. The nanomaterial was characterized by transmission electron microscopy, powder X‐ray diffraction, scanning electron microscopy, fourier transform infrared spectroscopy, and energy dispersive X‐ray. The catalytic and optical properties were studied using solid‐phase spectrophotometry and ultraviolet–visible spectroscopy, respectively. Gas chromatography‐mass spectrometry (GC‐MS) was used to detect the intermediates during the catalytic degradation of methylene blue. It was observed that with decrease in the dielectric constant (ε) of the solvent, the bandgap and particle size decrease and catalytic efficiency increases. Hence, the highest catalytic activity was observed with the solvent having the least dielectric constant. 相似文献
55.
In this paper, we consider the problem on minimizing sums of the largest eigenvalues of a symmetric matrix which depends on the decision variable affinely. An important application of this problem is the graph partitioning problem, which arises in layout of circuit boards, computer logic partitioning, and paging of computer programs. Given 0, we first derive an optimality condition which ensures that the objective function is within error bound of the solution. This condition may be used as a practical stopping criterion for any algorithm solving the underlying problem. We also show that, in a neighborhood of the minimizer, the optimization problem can be equivalently formulated as a smooth constrained problem. An existing algorithm on minimizing the largest eigenvalue of a symmetric matrix is shown to be applicable here. This algoritm enjoys the property that if started close enough to the minimizer, then it will converge quadratically. To implement a practical algorithm, one needs to incorporate some technique to generate a good starting point. Since the problem is convex, this can be done by using an algorithm for general convex optimization problems (e.g., Kelley's cutting plane method or ellipsoid methods), or an algorithm specific for the optimization problem under consideration (e.g., the algorithm developed by Cullum, Donath, and Wolfe). Such union ensures that the overall algorithm has global convergence with quadratic rate. Finally, the results presented in this paper are readily extended on minimizing sums of the largest eigenvalues of a Hermitian matrix.Some of results in this paper were given in [19] without proofs. 相似文献
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57.
Nonparametric regression is commonly used for summarizing the relationship between variables without requiring the assumptions of model. Generalized linear model and linear regression model are usually used to examine the relationship of variables, but both are badly affected by influential observations. Due to this, detection and removal of outliers attain a lot of attention of researchers to obtain reliable estimates. We focus on such robust technique whose performance is acceptable in the presence of outliers. The present article empirically compared the performance of linear regression model and generalized linear model with multivariate nonparametric kernel regression. Here, multivariate nonparametric kernel regression is used with Gaussian kernel and six different bandwidths on Aerial biomass data. The performance of nonparametric regression with Bayesian bandwidth was found to be better as compared with other methods. 相似文献
58.
Nayab Batool Rizvi Samina Aleem Mohammad Rizwan Khan Sadia Ashraf Rosa Busquets 《Molecules (Basel, Switzerland)》2022,27(3)
Protein scarcity is the most vital cause of long-lasting diseases and even untimely deaths in some developing nations. The application of protein in food is advantageous from the point of view of non-toxicity, biocompatibility, and dietary benefits. This study aimed to determine the protein contents of the sprouts of Vigna radiates (mung beans), Lens culinaris (lentils), and Cicer arietinum (chickpeas) using the Kjeldahl and Lowry methods. The results obtained from the Kjeldahl method identified protein concentrations of 2.54, 2.63, and 2.19%, whereas the Lowry method results identified protein concentrations of 2.96%, 4.10%, and 1.6% in mung beans, lentils, and chickpeas, respectively. In both the methods, lentils were found to have the highest amount of protein followed by mung beans and chickpeas. Both the Kjeldahl and Lowry methods demonstrated good protein values and low variation in the protein amount in the analyzed samples. Furthermore, the methods had greater sensitivity and comparable experimental variability. The outcomes revealed that assays can be applied for protein analysis in legumes. In the context of a lack of suitable standard procedures for evaluating legumes’ compositions, the present study is suitable for food control laboratories. In addition, the studied samples represent a significant source of protein and can be used to fulfil the daily requirements for protein intake and other food applications. 相似文献
59.
Romaisa Arshad Waleed A. Ismail Batool Zara Rabia Naseer Sadia Minhas Moeez Ansari Fatema Akhter Saria A. Khokhar Abdullah Ali Alqahtani Huda Abutayyem Haytham Jamil Alswairki Mohammad Khursheed Alam 《Molecules (Basel, Switzerland)》2022,27(7)
Chronic periodontitis and diabetes mellitus share a two-way relationship, the common factor being the inflammatory-mediated pathway, and various cytokines are released during this inflammatory cascade, one of which being matrix metalloproteinase-9. The aim of this study was to identify whether the levels of matrix metalloproteinase-9 are increased due to type-II diabetes mellitus in chronic periodontitis patients. It was an observational, analytical, case-control study. Thirty subjects were recruited in the test group, who were suffering from type-II diabetes mellitus and chronic periodontitis, and 30 subjects in the control group, who were subjects with chronic periodontitis but systemically healthy. Periodontal parameters, including the plaque score, gingival bleeding index, probing pocket depth and clinical attachment level of the subjects, were measured, saliva samples of all of the subjects were collected and salivary matrix metalloproteinase-9 levels were analyzed by an enzyme-linked immunosorbent assay (ELISA) technique. The statistical analysis was performed using SPSS 24. Overall, the matrix metalloproteinase-9 levels of the diabetic patients with chronic periodontitis were increased almost twofold (156.95 ± 29.80 ng/mL) compared to the levels in the controls (74.96 ± 6.32 ng/mL) (p < 0.001). Similarly, the periodontal parameters were far worse in diabetics with chronic periodontitis compared to the controls. The average gingivitis score for the test subjects was 78.45 ± 8.93%), compared to 29.32 ± 12.96% in the controls (p < 0.001). The mean probing pocket depth for the test group was 5.39 ± 0.60 mm, and, for the control group, it was 4.35 ± 0.31 mm (p < 0.001). For the test subjects, the average clinical attachment level was 5.86 ± 0.58 mm, and it was 4.66 ± 0.32 mm for the controls (p < 0.001). It was ascertained that there is a two-fold increase in the levels of salivary matrix metalloproteinase-9 in the test group compared to the control group. In addition, the level of periodontal apparatus destruction was greater in the test group. This proved that type-II diabetes mellitus influences the levels of matrix metalloproteinase-9 in humans and elevates them, causing further periodontal destruction. 相似文献
60.
Batool Nisa Fazal Ullah Iqbal Nisa Mushtaq Ahmad Muhammad Zafar Mamoona Munir Shazia Sultana Wajid Zaman Hakim Manghwar Farman Ullah Muhammad Nauman Khan Diaa O. El-Ansary Hosam O. Elansary 《Molecules (Basel, Switzerland)》2022,27(15)
We confined the formation and characterization of heterogenous nano-catalysts and then used them to produce biodiesel from the novel non-edible seed oil of Prunus aitchisonii. P. aitchisonii seeds’ oil content was extracted at about 52.4 ± 3% with 0.77% FFA. Three different heterogenous nano-catalysts—calcined (CPC), KPC, and KOH-activated P. aitchisonii cake Titanium Dioxide (TiO2)—were synthesized using calcination and precipitation methods. The mentioned catalysts were characterized through XRD, SEM, and EDX to inspect their crystallin dimension, shape, and arrangement. Titanium dioxide has morphological dimensions so that the average particle size ranges from 49–60 nm. The result shows that the crystal structure of TiO2 is tetragonal (Anatase). The surface morphology of CPC illustrated that the roughness of the surface was increased after calcination, many macropores and hollow cavities appeared, and the external structure became very porous. These changes in morphology may increase the catalytic efficiency of CPC than non-calcined Prunus aitchisonii oil cake. The fuel belonging to PAOB stood according to the series suggested by ASTM criteria. All the characterization reports that P. aitchisonii is a novel and efficient potential source of biodiesel as a green energy source. 相似文献