全文获取类型
收费全文 | 655篇 |
免费 | 41篇 |
国内免费 | 17篇 |
专业分类
化学 | 480篇 |
晶体学 | 1篇 |
力学 | 46篇 |
数学 | 101篇 |
物理学 | 85篇 |
出版年
2023年 | 4篇 |
2022年 | 17篇 |
2021年 | 23篇 |
2020年 | 28篇 |
2019年 | 43篇 |
2018年 | 40篇 |
2017年 | 29篇 |
2016年 | 68篇 |
2015年 | 38篇 |
2014年 | 40篇 |
2013年 | 102篇 |
2012年 | 58篇 |
2011年 | 45篇 |
2010年 | 39篇 |
2009年 | 28篇 |
2008年 | 25篇 |
2007年 | 28篇 |
2006年 | 7篇 |
2005年 | 15篇 |
2004年 | 8篇 |
2003年 | 8篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1992年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1980年 | 1篇 |
1937年 | 1篇 |
排序方式: 共有713条查询结果,搜索用时 0 毫秒
61.
Azadi Mahboobeh Olya Mohammad Javad Vahedi Samaneh Sangani Neda Fazeli 《Russian Journal of Applied Chemistry》2017,90(7):1181-1187
Russian Journal of Applied Chemistry - Titanium dioxide (TiO2) is widely used in the paint industry as a white pigment. To reduce the high cost of TiO2, mineral fillers such as different calcites... 相似文献
62.
Mehdi Kalhor Akbar Mobinikhaledi Javad Jamshidi 《Research on Chemical Intermediates》2013,39(7):3127-3133
A simple and practical procedure for synthesis of 2-arylbenzimidazoles by a one-pot condensation of o-phenylenediamine with aromatic aldehydes in the presence of a catalytic amount of M(NO3)2·6H2O (M = Mn, Fe, Co, Ni, Cu) in ethanol at room temperature is described. Major advantages of this practical procedure are use of a readily available catalyst, high yields, short reaction times, and simplicity of the reaction and workup. 相似文献
63.
The objective of this study is to investigate the possibility of using Co-CNTs as a green reaction medium and a catalyst for the cyclo-condensation of o-aminobenzamide with various aldehydes. This inexpensive, non-toxic, and readily available catalyst efficiently catalyzes the above condensation for the synthesis of 2-aryl-2,3-dihydroquinazolin-4(1H)-ones. Compared to the classical reaction, this is a simple, highly yielding, time saving, and environmentally friendly method. 相似文献
64.
S. F. Mirshojaei M. Gandomkar R. Najafi S. E. Sadat Ebrahimi M. H. Babaei A. Shafiei M. H. Talebi 《Journal of Radioanalytical and Nuclear Chemistry》2011,287(1):21-25
Cefotaxime, a cephalosporin antibiotic, used to treat bacterial infections was investigated to label with 99mTc. Labeling was performed using sodium dithionite as a reducing agent at 100 °C for 10 min and radiochemical analysis involved
ITLC and HPLC methods. The stability of labeled antibiotic was checked in the presence of human serum at 37 °C up to 24 h.
The maximum radiolabeling yield was 92 ± 2%. Bacterial binding assay was performed with S. aureus and the in vivo distribution was studied in mice. Images showed minimal accumulation in non-target tissues, with an average
target/non-target ratio of 2.89 ± 0.58. 相似文献
65.
A simple flow injection spectrophotometric method for the determination of nitrite is described. Nitrite injected into the flow system reacts with thiourea in acidic medium and the generated thiocyanate ion reacts with Fe(III) in the reagent solution to produce a highly colored product. The influences of chemical and physical parameters including reagent concentrations, sample volume injected, flow rates of the carrier and reagent solutions, reaction coil length and reaction temperature, were studied and optimum values of these parameters were established. Under the optimum conditions, the calibration curve for nitrite was linear over the concentration range 0.36 - 90 microg ml(-1) without preconcentration and over the range 3.8 - 500 ng ml(-1) with a simple online preconcentration step using an anion exchange column. The corresponding detection limits were 0.36 micro ml(-1) and 3.8 ng ml(-1), respectively. Up to 25 samples can be analyzed per hour, with an average relative standard deviation of < or = 1.2%. Interferences by various foreign ions were studied and the method was applied to the determination of nitrite in water and spiked water samples. 相似文献
66.
Javad?SafariEmail author Soheila?Gandomi-Ravandi 《Journal of the Iranian Chemical Society》2015,12(1):147-154
A supported carbon material is shown to be a highly efficient, eco-friendly and recyclable solid acid catalyst for the Biginelli reaction of aldehyde, β-ketoester and urea or thiourea under microwave irradiation in the absence of solvent. This method offers significant advantages such as efficiency, the excellent yield, avoidance of the organic solvents, mild reaction conditions, easy separation and simple operation. In addition, because of employing microwave as heating source and reducing use of organic solvents, this novel method emerges as a green-approach leading to less harmful residues. Furthermore, a mechanism was proposed to rationalize the reaction and the role of NiO–MWCNTs was also investigated in these transformations. 相似文献
67.
68.
Abedini-Torghabeh Javad Eshghi Hossein Bakavoli Mehdi Rahimizadeh Mohammad 《Research on Chemical Intermediates》2015,41(6):3649-3658
Research on Chemical Intermediates - PPh3 was used as an efficient catalyst for the one-pot three-component Mannich reactions of acetophenone with different aromatic amines and aromatic aldehydes... 相似文献
69.
Bahram Hemmateenejad Javad Tashkhourian Mohammad Mahdi Bordbar Nabiollah Mobaraki 《Journal of the Iranian Chemical Society》2017,14(3):595-604
Today, traditional systems of medicines (such as herbal distillates) become important resources for providing healthcare benefits. The ability to discriminate among closely similar herbal products is critical to ensure their efficacy. This article proposes a pattern-based recognition approach for the rapid discrimination of herbal distillates using a low-cost and sensitive colorimetric sensor array composed of 25 indicators. The color changes of the sensor exposed to the vapor of the herbal distillates can be monitored easily with an ordinary flatbed scanner. The digital representation of the array response was analyzed with hierarchical clustering analysis (HCA) and principal component analysis (PCA). Using new variable selection strategy, 6 indicators among the 25 employed indicators were selected as discriminant elements of the array. So, a complete discrimination (with 100% accuracy) of 46 herbal distillates was achieved. The proposed sensor represented a better resolution when analytes were placed in an oven at 85 °C for 45 min. This colorimetric sensor array demonstrates excellent potential for quality assurance/control applications of herbal distillates. 相似文献
70.
Javad Jamalzadeh 《代数通讯》2017,45(3):1187-1188