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91.
Abedi A Safari N Amani V Khavasi HR 《Dalton transactions (Cambridge, England : 2003)》2011,40(26):6877-6885
The complexes [Fe(dm4bt)(3)][FeCl(4)](2) (1) and [Fe(dm4bt)(3)][FeBr(4)](2) (2) were prepared from the reaction of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) with FeCl(3)·6H(2)O and FeBr(3), respectively, in methanol. Both complexes were characterized by IR, UV-Vis and (1)H NMR spectroscopy and their structures were studied by single-crystal diffraction. The methylated bithiazole led to high spin Fe(II) centers in the octahedral cation part of complexes 1 and 2 with Fe-N distance of 2.220 ?, in spite of the low spin octahedral Fe(II) complexes with unsubstituted bithiazole ligands. Crystal structure determination of 2 was performed at 90, 120 and 298 K. Temperature reduction to 90 K resulted in a decrease in the Fe-N bond length to 2.206 ? which is still in the range of high spin Fe(II). Complex 1 shows a reversible mechanochromic effect from the crystalline phase to powder form from red to yellow; it also displays reversible photochromism from yellow to green in solution under sunlight. The magnetic behaviour of the complexes was also studied at 2-300 K. The temperature dependence of χ(m)T curves for the two forms of 1, crystal and powder, demands some changes in their magnetic behavior, causing different colors i.e. red and yellow. At low temperatures, χ(m)T decreases where the decrease starts at around 65 K for compound 1, and at around 100 K for compound 2, due to different counterions. The two complexes exhibit antiferromagnetism at around 4 K. 相似文献
92.
Let T be a Wakamatsu tilting module. A module M is called (n, T)-copure injective (resp. (n, T)-copure flat) if ɛ
T
1 (N, M) = 0 (resp. Γ1
T
(N, M) = 0) for any module N with T-injective dimension at most n (see Definition 2.2). In this paper, it is shown that M is (n, T)-copure injective if and only if M is the kernel of an I
n
(T)-precover f: A → B with A ∈ Prod T. Also, some results on Prod T-syzygies are presented. For instance, it is shown that every nth Prod T-syzygy of every module, generated by T, is (n, T)-copure injective. 相似文献
93.
Dialkyl 2‐(alkylamino)‐4,9‐dihydro‐9‐oxocyclohepta[b]pyran‐3,4‐dicarboxylates are prepared in a one‐pot three‐component reaction of alkyl isocyanide, dialkyl acetylenedicarboxylate, and α‐tropolone (=2‐hydroxycyclohepta‐2,4,6‐trienone). The reaction proceeds smoothly at room temperature and under neutral conditions to afford tropolone derivatives in high yield. 相似文献
94.
95.
Nonlinear vibration mitigation of a flexible rotor shaft carrying a longitudinally dispositioned unbalanced rigid disc 总被引:1,自引:0,他引:1
Nonlinear Dynamics - This study is dedicated to investigate the nonlinear dynamics of a system composed of a flexible rotor shaft carrying a longitudinally dispositioned unbalanced rigid disc. The... 相似文献
96.
Abedini Masoumeh Shirini Farhad Mohammad-Alinejad Omran Javad Seddighi Mohadeseh Goli-Jolodar Omid 《Research on Chemical Intermediates》2016,42(5):4443-4458
Research on Chemical Intermediates - Succinimidinium N-sulfonic acid hydrogen sulfate ([SuSA-H]HSO4) as a new ionic liquid is prepared and characterized using a variety of techniques, including... 相似文献
97.
Mohammad Ali Karimi Rasul Shahin Sayed Zia Mohammadi Abdolhamid Hatefi‐Mehrjardi Javad Hashemi Javad Yarahmadi 《中国化学会会志》2013,60(11):1339-1346
A new solid phase extraction (SPE) method has been developed for the speciation of Cr(III) and Cr(VI). This method is based on the adsorption of Cr(VI) on modified alumina‐coated magnetite nanoparticles (ACMNPs). Total chromium in different samples was determined as Cr(VI) after oxidation of Cr(III) to Cr(VI) using H2O2. The chromium concentration has been determined by flame atomic absorption spectrometric (FAAS) technique and amount of Cr(III) was calculated by substracting the concentration of Cr(VI) from total chromium concentration. The effect of parameters such as pH, amount of adsorbent, contact time, sample volume, eluent type, H2O2 concentration and cetyltrimethylammonium bromide (CTAB) concentration as modifier on the quantitative recovery of Cr(VI) were investigated. Under the optimal experimental conditions, the preconcentration factor, detection limit, linear range and relative standard deviation (RSD) of Cr(VI) were 140 (for 350 mL of sample solution), 0.083 ng mL?1, 0.1‐10.0 ng mL?1 and 4.6% (for 5.0 ng mL?1, n = 7), respectively. This method avoided the time‐consuming column‐passing process of loading large volume samples in traditional SPE through the rapid isolation of CTAB@ACMNPs with an adscititious magnet. The proposed method was successfully applied to the determination and speciation of chromium in different water and wastewater samples and suitable recoveries were obtained. 相似文献
98.
Safari Sinegani AA Emtiazi G Shariatmadari H 《Journal of colloid and interface science》2005,290(1):39-44
The interaction of organic molecules with mineral surfaces is a subject of interest in a variety of disciplines. Enzymes are able to be sorbed and immobilized by clay minerals and humic colloids in soil environment. The present study was done to elucidate some aspects of sorption and immobilization of cellulase on soil components by analysis of the sorption, and immobilization of cellulase on Avicel, a soil sample, illite, kaolinite, montmorillonite, and palygorskite. Palygorskite displayed the highest sorption capacity. Sorbents coated with hydroxyaluminum displayed significantly higher capacity than uncoated sorbents. The positive effects of Al(OH)(x) coating on sorption capacities of the different sorbents were not equal. The effect decreased in the order soil > palygorskite > kaolinite > Avicel > montmorillonite > illite. The amount of sorbed cellulase desorbed from external surfaces of soil was quite low (about 16%), especially in coated samples (about 6%). X-ray diffraction analysis of K-montmorillonite and Ca-montmorillonite showed that Al(OH)(x) was intercalated between the montmorillonite layers. Immobilization of cellulase on the sorbents did not result in expansion of their crystal structures. Therefore, it may be concluded that the amount of cellulase immobilized on internal surfaces of the sorbents was negligible. 相似文献
99.
Let (an)n0 be a sequence of complex numbers, and, for n0, let
A number of results are proved relating the growth of the sequences(bn) and (cn) to that of (an). For example, given p0, if bn= O(np and for all > 0,then an=0 for all n > p. Also, given 0 < p < 1, then for all > 0 if and onlyif . It is further shown that, given rß > 1, if bn,cn=O(rßn), then an=O(n),where , thereby proving a conjecture of Chalendar, Kellay and Ransford. The principal ingredientsof the proogs are a Phragmén-Lindelöf theorem forentire functions of exponential type zero, and an estimate forthe expected value of e(X), where X is a Poisson random variable.2000 Mathematics Subject Classification 05A10 (primary), 30D15,46H05, 60E15 (secondary). 相似文献
100.
Javad Mashreghi Mostafa Nasri 《Nonlinear Analysis: Theory, Methods & Applications》2010,72(3-4):2086-2099
We develop a variant of Korpelevich’s method for solving variational inequality problems with pseudomonotone operators in Banach spaces. We establish the strong convergence of the sequence generated by the method under reasonable assumptions on the problem data. Finally, we justify the motivation of our theory by including compelling examples of infinite dimensional variational inequality problems for which our method is applicable. 相似文献