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41.
Majid Kolahdoozan Roozbeh Javad Kalbasi Zohreh S. Shahzeidi 《Monatshefte für Chemie / Chemical Monthly》2012,38(2):325-334
Abstract
Poly(4-vinylpyridine)/SBA-15 (P4VP/SBA-15) composites with various amounts of SBA-15 were prepared and characterized. The physical and chemical properties of P4VP/SBA-15 were investigated by XRD, BET, FT-IR, TGA, and SEM techniques. The catalytic performance of each material was determined for the Knoevenagel condensation reaction between carbonyl compounds and ethyl cyanoacetate in the presence of water as a solvent. The effects of reaction temperature, the amount of catalyst, amount of support, solvent, and the amount of benzoyl peroxide during the synthesis of P4VP/SBA-15 were investigated, as well as the recyclability of the heterogeneous composite. The catalyst used for this synthetically useful transformation showed a considerable level of reusability as well as very good activity. This reaction occurred rapidly when water was used as a solvent, so we assume it to be a green reaction. 相似文献42.
Iodine‐Catalyzed Synthesis of Spiro[1,3,4‐benzotriazepine‐2,3′‐indole]‐2′,5(1H,1′H)‐diones under Mild Conditions 下载免费PDF全文
The I2‐catalyzed preparation of spiro[1,3,4‐benzotriazepine‐2,3′‐indole]‐2′,5(1H,1′H)‐diones from 2‐aminobenzohydrazide and isatins in MeCN at room temperature in good‐to‐excellent yields is described. The structure of 3 was corroborated spectroscopically (IR, 1H‐ and 13C‐NMR, and EI‐MS data). A plausible mechanism for this type of reaction is proposed (Scheme 2). 相似文献
43.
Amir Reza Jalilian Mahdokht Jouiaei Alireza Doroudi Javad Garousi Sedigheh Moradkhani 《Journal of Radioanalytical and Nuclear Chemistry》2010,285(3):555-561
In this work, recently prepared 67Ga-labeled glucagon (67Ga-DTPA-GCG) for imaging studies (radiochemical purity >94%; HPLC, S.A. 296–370 GBq/mM) was used in biological studies. The wild-type rat biodistribution results, 2 h post injection, demonstrated high tissue:muscle ratios for target tissues (liver, kidney, heart, spleen, fat intestine stomach and pancreas), 234, 18.45, 7.12, 1.75, 128.7, 4.9, 6.3 and 1.11, respectively. The tracer binding capacity using freshly prepared rat brain homogenate demonstrated significant specific binding of the tracer to neuronal GCG receptors (67Ga-DTPA-GCG/67Ga:3 and 67Ga-DTPA-GCG/67GaDTPA:2.2 at 90 min). SPECT images also demonstrated target specific binding of the tracer at 4 h. The data suggests the tracer is accumulated in GCGR rich tissues 2–4 h post injection, suggesting potentials of the tracer for future imaging studies in glocagonoma models. 相似文献
44.
In this paper a multi-input, multi-output (MIMO) active noise control system with the aim of global reduction of broadband noise in a telephone kiosk is addressed. The model selected for this optimization problem is the acoustic environment of an enclosure taking into account the effect of coupling of secondary sources used for control purpose. This optimization involves finding the best locations for loudspeakers and microphones inside the enclosure as well as optimizing the control signals considering secondary source coupling.Previous results show that in order to be able to reduce acoustic noise globally inside the enclosure, the frequency range of 50-300 Hz must be selected for control purpose. The mean of acoustic potential energy of the enclosure, when excited in this frequency range, is adopted as a performance measure. This performance index is penalized with the power of the signal required to excite secondary loudspeakers, in order to avoid placements that may need high voltage power amplifier for a desired performance. To find the solution of this problem, i.e. the global minimum of the performance index, several genetic algorithms are proposed and compared. In order to attain the best achievable performance in reaching the global minimum, the parameters of these genetic algorithms are tuned, and used for optimization purpose. Numerical simulations of the acoustical potential energy as well as the sound pressure at different heights of the kiosk, when active noise control (ANC) system operates, confirm the optimality of the locations proposed by the genetic algorithm. 相似文献
45.
An efficient approach for the preparation of functionalized 2‐aryl‐2,5‐dihydro‐5‐oxo‐4‐[2‐(phenylmethylidene)hydrazino]‐1H‐pyrroles is described. The four‐component reaction between aldehydes, NH2NH2?H2O, dialkyl acetylenedicarboxylates, and 1‐aryl‐N,N′‐bis(arylmethylidene)methanediamines proceeds in EtOH under reflux in good‐to‐excellent yields (Scheme 1). The structures of 4 were corroborated spectroscopically (IR, 1H‐ and 13C‐NMR, and EI‐MS, and, in the case of 4f , by X‐ray crystallography). A plausible mechanism for this type of reaction is proposed (Scheme 2). 相似文献
46.
Javad?AzizianEmail author Ali R.?Karimi Hamedeh?Arefrad Ali A.?Mohammadi Mohammad R.?Mohammadizadeh 《Monatshefte für Chemie / Chemical Monthly》2004,135(6):729-733
Summary. We report on the addition of dialkyl acetylenedicarboxylate to 1-alkylisatins or tryptanthrine in the presence of triphenylphosphine which leads to highly functionalised novel unsaturated -spirolactones. 相似文献
47.
This paper proposes a tunable zeroth-order resonator on a composite right/left-handed transmission line consisting of a transversely magnetized ferrite substrate periodically loaded by microstrip inductors. Based on the propagation theory of edge guided modes, the analysis procedure of this structure is introduced. The numerical results demonstrate the tunability of the resonant frequency by changing the DC bias magnetic field applied to the ferrite. In contrast to previous work, the proposed structure is easy to design and fabricate and does not require a chip component. 相似文献
48.
Robabeh Baharfar Mohammad Javad Taghizadeh Majid Ahmadian Seyed Meysam Baghbanian 《中国化学快报》2010,21(2):175-178
<正>The addition of 2,4-dihydroxyaceto(and benzo)phenone to propiolic ester is catalyzed by triphenylphosphine or tert-butyl isocyanide to form O-vinyl aryl derivatives in fairly good yields. 相似文献
49.
Using Auslander’s G-dimension, we assign a numerical invariant to any group Γ. It provides a refinement of the cohomological dimension and fits well into the well-known hierarchy of dimensions assigned already to Γ. We study this dimension and show its power in reflecting the properties of the underlying group. We also discuss its connections to relative and Tate cohomology of groups. 相似文献
50.
Azadi Mahboobeh Olya Mohammad Javad Vahedi Samaneh Sangani Neda Fazeli 《Russian Journal of Applied Chemistry》2017,90(7):1181-1187
Russian Journal of Applied Chemistry - Titanium dioxide (TiO2) is widely used in the paint industry as a white pigment. To reduce the high cost of TiO2, mineral fillers such as different calcites... 相似文献