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131.
In a previous publication (part I) it has been shown that for an arbitrary statistically isotropic and homogeneous medium the parabolic equation for the two-frequency mutual coherence function can be separated and thereby expressed as a superposition of modes. A parameterization based on the longitudinal part of this representation has also been treated. This paper explores the transverse structure and parameterization of the field solution by employing dimensional, variational and the modified WKB procedures for solving the eigenfunction/eigenvalue problem. General expressions are derived first for a general structure function and then specialized for a power-law structure function with emphasis on quadratic and Kolmogorov media. 相似文献
132.
Marco JA Sanz-Cervera JF Yuste A Jakupovic J Lex J 《The Journal of organic chemistry》1996,61(5):1707-1709
A methanolic extract of Euphorbia terracina L. has been shown to contain two peracylated polyhydroxy terpenoid lactones with a novel C(22) carbon framework. These metabolites, which have been named terracinolides A (1) and B (2), are based on the same parent compound, but differ in the nature of one of the acyl residues. This novel skeletal system is formally derived from the jatrophane framework by addition of a two-carbon fragment on C-17 (jatrophane numbering). 相似文献
133.
The analysed Ekman layer is generated in a fluid layer rotating around an axis normal to its two bounding rigid plates. One of the plates is stationary, the other moving at certain Reynolds numbers. An additional oscillation is added to the moving plate at different amplitudes and frequencies. The linear stability of this system is determined via a Floquet analysis and a Galerkin-approximation of the corresponding Navier-Stokes-Equations. If the frequencies of the oscillations are small the critical Reynolds numbers of the Type I and Type II instabilities do not differ much from steady Ekman layers. Also for a purely oscillating system the critical values of the instabilities are almost consistent with those for a steady system. Interestingly, for higher frequencies the Type II instability does not appear any more. Instead the boundary layer becomes unstable only in terms of a Type I instability. In comparison with findings of other authors these results seem to be quite reasonable. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
134.
Zinc Oxide–Porphyrin Hybrid Rhombuses: Catalytically Active Microstructures via Self‐Assembly
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Jasmin Düring Sarah Bernhardt Franziska Gröhn 《Particle & Particle Systems Characterization》2017,34(10)
A novel self‐assembled organic–inorganic hybrid structure consisting of zinc oxide and two oppositely charged porphyrins, showing significantly enhanced photocatalytic activity, is presented. Electrostatic self‐assembly of the cationic tetra‐(N‐methyl‐4‐pyridyl)porphyrin (TMPyP) with preformed assemblies of ZnO nanorods and the anionic tetra‐(4‐sulfonatophenyl)porphyrin (TPPS) in ethanol results in porphyrin microrhombuses decorated with ZnO nanorods. The structure formation is followed spectroscopically. The shape of the microrhombuses and the number of attached ZnO nanoparticles can be tuned through the porphyrin ratio TMPyP/TPPS. An enhanced and selective catalytic activity is found, giving insight into the degradation mechanism. Due to the tool‐box principle and its versatility, the concept may have great impact in fields such as solar‐energy conversion and optoelectronics. 相似文献
135.
Christian E. Halbig Roman Lasch Jasmin Krüll Anna S. Pirzer Zhenping Wang Jan N. Kirchhof Kirill I. Bolotin Markus R. Heinrich Siegfried Eigler 《Angewandte Chemie (International ed. in English)》2019,58(11):3599-3603
The development of versatile functionalization concepts for graphene is currently in the focus of research. Upon oxo‐functionalization of graphite, the full surface of graphene becomes accessible for C?C bond formation to introduce out‐of‐plane functionality. Herein, we present the arylation of graphene with arylazocarboxylic tert‐butyl esters, which generates aryl radicals after activation with an acid. Surprisingly, the degree of functionalization is related to the concentration of lattice vacancy defects in the graphene material. Consequently, graphene materials that are free from lattice defects are not reactive. The reaction can be applied to graphene dispersed in solvents and leads to bitopic functionalization as well as monotopic functionalization when the graphene is deposited on surfaces. As the arylazocarboxylic tert‐butyl ester moiety can be attached to various molecules, the presented method paves the way to functional graphene derivatives, with the density of defects determining the degree of functionalization. 相似文献
136.
A simple, sensitive and accurate method has been developed for spectrofluorimetric determination of cefixime in pure form
and pharmaceutical preparations. The method is based on the reaction of cefixime with 2-cyanoacetamide in the presence of
21% ammonia at 100 °C. The fluorescent reaction product showed maximum fluorescence intensity at λ 378 nm after excitation
at λ 330 nm. The factors affecting the derivatization reaction were carefully studied and optimized. The fluorescence intensity
versus concentration plot was rectilinear over the range of 0.02 to 4 μg mL−1 with correlation coefficient of 0.99036. The limit of detection (LOD) and limit of quantification (LOQ) was found to be 2.95 ng mL−1 and 9.84 ng mL−1, respectively. The proposed method was validated statistically and through recovery studies. The method was successfully
applied for the determination of cefixime in pure and dosage form with percent recoveries from 98.117% to 100.38%. The results
obtained from the proposed method have been compared with the official HPLC method and good agreement was found between them. 相似文献
137.
A new spectrofluorimetric method has been developed and validated for the quantification of ceftriaxone in bulk powder, pharmaceutical
formulations and spiked human plasma. The developed method is reproducible, accurate, sensitive and cost effective. In this
method, ceftriaxone was converted into a fluorescent compound by reacting with 0.8 M ethyl acetoacetate and 25% formaldehyde
in a buffered medium (pH = 4.2) at 90 °C. The excitation and emission wavelengths of the fluorescent reaction product are
316 nm and 388 nm respectively. Optimization of the experimental conditions affecting the condensation reaction were carefully
carried out and the optimum experimental conditions were incorporated in the procedure. The developed method has a broad linear
range (0.2–20 μg mL−1) with a correlation coefficient of 0.9992. The limit of detection (LOD) and limit of quantification (LOQ) was found to be
1.94 × 10−2 μg mL−1 and 6.47 × 10−2 μg mL−1 respectively. The common excipients and co-administered drugs were investigated for their interferences effect in the assay.
The developed method was validated statistically through recovery studies and successfully applied to ceftriaxone determination
in bulk powder, pharmaceutical formulations and spiked human plasma samples. The percent recoveries were found to be in the
range of 99.04–100.26% for bulk powder, 98.88–99.92% for pharmaceutical formulations and 94.22–98.48% for spiked human plasma.
The results were verified by comparing with reference literature HPLC method and were found in good agreement. 相似文献
138.
We prove that a backward orbit with bounded Kobayashi step for a hyperbolic, parabolic or strongly elliptic holomorphic self-map of a bounded strongly convex C2 domain in Cd necessarily converges to a repelling or parabolic boundary fixed point, generalizing previous results obtained by Poggi-Corradini in the unit disk and by Ostapyuk in the unit ball of Cd. 相似文献
139.
140.
Biocatalytic organic synthesis of optically pure (S)-scoulerine and berbine and benzylisoquinoline alkaloids 总被引:1,自引:0,他引:1
Schrittwieser JH Resch V Wallner S Lienhart WD Sattler JH Resch J Macheroux P Kroutil W 《The Journal of organic chemistry》2011,76(16):6703-6714
A chemoenzymatic approach for the asymmetric total synthesis of the title compounds is described that employs an enantioselective oxidative C-C bond formation catalyzed by berberine bridge enzyme (BBE) in the asymmetric key step. This unique reaction yielded enantiomerically pure (R)-benzylisoquinoline derivatives and (S)-berbines such as the natural product (S)-scoulerine, a sedative and muscle relaxing agent. The racemic substrates rac-1 required for the biotransformation were prepared in 4-8 linear steps using either a Bischler-Napieralski cyclization or a C1-Cα alkylation approach. The chemoenzymatic synthesis was applied to the preparation of fourteen enantiomerically pure alkaloids, including the natural products (S)-scoulerine and (R)-reticuline, and gave overall yields of up to 20% over 5-9 linear steps. 相似文献