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81.
Nancy J. Phillips Constance M. John Gary A. Jarvis 《Journal of the American Society for Mass Spectrometry》2016,27(7):1263-1276
Lipooligosaccharides (LOS) are major microbial virulence factors displayed on the outer membrane of rough-type Gram-negative bacteria. These amphipathic glycolipids are comprised of two domains, a core oligosaccharide linked to a lipid A moiety. Isolated LOS samples are generally heterogeneous mixtures of glycoforms, with structural variability in both domains. Traditionally, the oligosaccharide and lipid A components of LOS have been analyzed separately following mild acid hydrolysis, although important acid-labile moieties can be cleaved. Recently, an improved method was introduced for analysis of intact LOS by MALDI-TOF MS using a thin layer matrix composed of 2,4,6-trihydroxyacetophenone (THAP) and nitrocellulose. In addition to molecular ions, the spectra show in-source “prompt” fragments arising from regiospecific cleavage between the lipid A and oligosaccharide domains. Here, we demonstrate the use of traveling wave ion mobility spectrometry (TWIMS) for IMS-MS and IMS-MS/MS analyses of intact LOS from Neisseria spp. ionized by MALDI. Using IMS, the singly charged prompt fragments for the oligosaccharide and lipid A domains of LOS were readily separated into resolved ion plumes, permitting the extraction of specific subspectra, which led to increased confidence in assigning compositions and improved detection of less abundant ions. Moreover, IMS separation of precursor ions prior to collision-induced dissociation (CID) generated time-aligned, clean MS/MS spectra devoid of fragments from interfering species. Incorporating IMS into the profiling of intact LOS by MALDI-TOF MS exploits the unique domain structure of the molecule and offers a new means of extracting more detailed information from the analysis. 相似文献
82.
The Multiple Facets of Iodine(III) Compounds in an Unprecedented Catalytic Auto‐amination for Chiral Amine Synthesis 下载免费PDF全文
Dr. Julien Buendia Gwendal Grelier Dr. Benjamin Darses Dr. Amanda G. Jarvis Dr. Frédéric Taran Dr. Philippe Dauban 《Angewandte Chemie (International ed. in English)》2016,55(26):7530-7533
Iodine(III) reagents are used in catalytic one‐pot reactions, first as both oxidants and substrates, then as cross‐coupling partners, to afford chiral polyfunctionalized amines. The strategy relies on an initial catalytic auto C(sp3)?H amination of the iodine(III) oxidant, which delivers an amine‐derived iodine(I) product that is subsequently used in palladium‐catalyzed cross‐couplings to afford a variety of useful building blocks with high yields and excellent stereoselectivities. This study demonstrates the concept of self‐amination of the hypervalent iodine reagents, which increases the value of the aryl moiety. 相似文献
83.
Schaaf O Jarvis AP van der Esch SA Giagnacovo G Oldham NJ 《Journal of chromatography. A》2000,886(1-2):89-97
Based on reversed-phase high-performance liquid chromatography (RP-HPLC) and atmospheric pressure chemical ionization (APCI) mass spectrometry, a HPLC-MS method was developed to permit the rapid qualitative and quantitative analysis of azadirachtin and related tetranortriterpenoids from seeds and tissue cultures of Neem (Azadirachta indica). APCI+ standard scanning mass spectra of the major Neem triterpenoids were recorded and utilized to select suitable ions for selected ion monitoring (SIM). Transitions for selective reaction monitoring (SRM) were based on MS-MS experiments. Using SIM, major Neem triterpenoids were detected in callus culture material and seed kernels of A. indica. The limit of detection for azadirachtin in extract samples (approximately 1 ng ml(-1) or 10 pg in SIM mode) was determined to be (with respect to injected absolute amounts) approximately 1000-times lower than values quoted in the literature for existing HPLC methods (approximately 200 ng ml(-1) or 10 ng). In addition to high sensitivity, the HPLC-MS method is able to tolerate minimal sample preparation and purification, dramatically reducing total analysis time. 相似文献
84.
85.
We introduce W‐spin structures on a Riemann surface Σ and give a precise definition to the corresponding W‐spin equations for any quasi‐homogeneous polynomial W. Then we construct examples of nonzero solutions of spin equations in the presence of Ramond marked points. The main result of the paper is a compactness theorem for the moduli space of the solutions of W‐spin equations when W = W(x1, …, xt) is a nondegenerate, quasi‐homogeneous polynomial with fractional degrees (or weights) qi < ½ for all i. In particular, the compactness theorem holds for the superpotentials E6, E7, E8 or An ? 1, Dn + 1 for n ≥ 3. © 2008 Wiley Periodicals, Inc. 相似文献
86.
Craig J. Kennedy Adriana Šturcová Michael C. Jarvis Timothy J. Wess 《Cellulose (London, England)》2007,14(5):401-408
Celery collenchyma cell walls are typical of primary plant cell walls in their composition but contain unusually well-oriented
cellulose microfibrils that are packed with more regularity than normal, permitting small-angle X-ray scattering (SAXS) experiments
that would not otherwise be possible. Small-angle scattering data were obtained for the cell walls in essentially their native
state and for isolated cellulose, in a fibrous form that retained the physical shape and microfibril orientation of the native
cell walls. The scattering patterns showed a distinct peak attributed to the interference contribution to the convolution
of form and interference functions. The position of the peak attributed to the interference function implied a mean centre-to-centre
microfibril spacing of approximately 3.2 nm in dry isolated cellulose and 3.8 nm in dry cell walls. Hydration increased the
mean microfibril spacing in the cell walls to 5.4 nm but had only a small effect on the mean microfibril spacing of isolated
cellulose. In the scattering profile from intact, hydrated cell walls it was just possible to discern the position of the
first Bessel minimum, from which a microfibril diameter in the range 3.1–3.6 nm may be estimated. This estimate is likely
to include attached hemicellulose chains. Porod plots of scattering intensity indicated a relatively sharp interface between
microfibrils and their immediate surroundings. The SAXS data imply that cellulose microfibrils 2.6–3.0 nm in diameter are
not quite in lateral contact with one another in the isolated cellulose and are augmented by hemicelluloses and separated
by readily hydrated matrix polysaccharides in the native plant cell wall. 相似文献
87.
Bhansali SH Jarvis JM Aksay IA Carbeck JD 《Langmuir : the ACS journal of surfaces and colloids》2006,22(15):6676-6682
We present a strategy to increase the sensitivity of resonators to the presence of specific molecules in the gas phase, measured by the change in resonant frequency as the partial pressure of the molecule changes. We used quartz crystals as the resonators and coated them with three different thin films (<1 microm thick) of porous silica: silica xerogel, silica templated by an ordered hexagonal phase of surfactant micelles, and silica templated by an isotropic L3 phase surfactant micellar system. We compared the sensitivity of coated resonators to the presence of water vapor. The crystals coated with hexagonal phase-templated silica displayed a sensitivity enhancement up to 100-fold compared to an uncoated quartz crystal in the low-pressure regime where adsorption played a dominant role. L3 phase-templated silica displayed the highest sensitivity (up to a 4000-fold increase) in the high partial pressure regimes where capillary condensation was the main accumulation mechanism. Three parameters differentiate the contributions of these coatings to the sensitivity of the underlying resonator: (i) specific surface area per unit mass of the coating, (ii) accessibility of the surfaces to a target molecule, and (iii) distribution in the characteristic radii of curvature of internal surfaces, as measured by capillary condensation. 相似文献
88.
W. C. Koskinen H. H. Cheng L. J. Jarvis B. A. Sorenson 《International journal of environmental analytical chemistry》2013,93(1-4):379-385
Abstract This research determined the relative effectiveness of supercritical fluid extraction (SFE) in extracting atrazine and its metabolites from soils which had been treated with atrazine for varying periods of time in order to characterize binding mechanisms. Aqueous methanol extraction was more effective than SFE in removing 14C atrazine residues from “aged” soils. The more polar the solvent system, the more 14C-atrazine residues were extracted. The order of polarity and extractability was aqueous methanol > SF-CO2/5% methanol > SF-CO2. Atrazine extraction efficiency using SF-CO2, and SF-CO2/.5% methanol decreased as samples “aged” in the field. The less than complete recovery of atrazine residues using the SFE technique could be seen as an indication that different binding mechanisms were involved in the retention of atrazine as well as its metabolites and that the binding mechanisms changed with time. 相似文献
89.
Richard J. C. Brown Kym E. Jarvis Benoit A. Disch Sharon L. Goddard Elke Adriaenssens Natacha Claeys 《Accreditation and quality assurance》2010,15(9):493-502
A comparison study of the measurement of metals in ambient particulate matter collected on air filters, using energy-dispersive X-ray fluorescence (ED-XRF), laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) and wet chemical digestion followed by ICP-MS analysis according to the European ‘reference method’ EN14902, is presented. Whilst it is shown that the methods have a low systematic bias with respect to each other, overall they do show a high random variability, and when considered individually using regression methods, some analytes have shown bias with respect to the EN14902 method. The low systematic bias observed is not unexpected since both the ED-XRF and LA-ICP-MS methods have been calibrated using results from the EN14902 technique. The uncertainty of each analysis has been estimated and compared with the data quality objectives for uncertainty specified in the relevant European air quality legislation. This has tentatively shown that approximately 75% of the analyses using ED-XRF and LA-ICP-MS meet the requirements of the legislation. However, improvements in repeatability and calibration methods for both ED-XRF and LA-ICP-MS would be needed before these methods were truly applicable for routine use in air quality measurements of this type. 相似文献
90.
Bruce B. Jarvis Bruce A. Marien 《Phosphorus, sulfur, and silicon and the related elements》2013,188(2-3):177-178
Abstract Reaction of a series of triarylphosphines with α-halo-m-cyanobenzyl phenyl sulfones gives the following Hammett ρ values: (CI) ρ = ?1.84; (Br) ρ = ?3.03; (I) ρ = ?3.36. 相似文献