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81.
Jul M. Weeren 《Fresenius' Journal of Analytical Chemistry》1895,34(1):133-134
Ohne Zusammenfassung 相似文献
82.
Černý Miroslav Šandera Pavel Pokluda Jaroslav 《Czechoslovak Journal of Physics》1999,49(10):1495-1501
Ab initio calculation of ideal strength of cubic crystals under three-axial tension was performed using the LMTO-ASA method. Computed values are in a good agreement with those obtained previously by means of semi-empirical polynomial approach. The values of equilibrium lattice parameter obtained in the framework of ab initio method are well comparable with the experimental data whereas a less satisfactory agreement was achieved in the case of bulk moduli. 相似文献
83.
Abstract The main results of this paper give two criteria for certain infinite series of rational numbers to be Liouville. Some examples
are also included.
Keywords: Liouville numbers, Infinite series
Mathematics Subject Classification (2000): 11J82 相似文献
84.
We give conditions sufficient for sequences consisting of real numbers to ensure that their expressible sets have Hausdorff
dimension zero. 相似文献
85.
Ale Ricka Libor Dostl Roman Jambor Vladimír Buchta Jirí Brus Ivana Císarov Michal Holcapek Jaroslav Holecek 《应用有机金属化学》2002,16(6):315-322
A set of seven [2,6‐bis(dimethylaminomethyl)phenyl]diphenyltin(IV) ({[(CH3)2NCH2]2(C6H3)}(C6H5)2Sn+X?) ionic organotin(IV) compounds (X = Br, NO3, CN, SCN, SeCN, BF4 and PF6) has been prepared and characterized by electrospray ionization mass spectrometry, 1H NMR spectroscopy in CDCl3,119Sn NMR in CDCl3 and DMSO‐d6 solution, as well as by 13C and 119Sn CP/MAS NMR spectroscopy and X‐ray diffraction techniques in the solid state. The in vitro antifungal activity of these water‐soluble ionic organotin(IV) compounds was compared with starting compounds and the antifungal drugs currently in clinical use. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
86.
Jul Meyer und J. Jannek 《Fresenius' Journal of Analytical Chemistry》1913,52(9):534-538
Ohne Zusammenfassung 相似文献
87.
88.
89.
Andrea Schenkmayerová Anikó Bertóková Jana Šefčovičová Vladimír Štefuca Marek Bučko Alica Vikartovská Peter Gemeiner Ján Tkáč Jaroslav Katrlík 《Analytica chimica acta》2015
A microbial biosensor for 2-phenylethanol (2-PE) based on the bacteria Gluconobacter oxydans was developed and applied in monitoring of a biotechnological process. The cells of G. oxydans were immobilized within a disposable polyelectrolyte complex gel membrane consisting of sodium alginate, cellulose sulphate and poly(methylene-co-guanidine) attached onto a miniaturized Clark oxygen electrode, forming whole cell amperometric biosensor. Measured changes in oxygen concentration were proportional to changes in 2-PE concentration. The biosensor sensitivity was 864 nA mM−1 (RSD = 6%), a detection limit of 1 μM, and the biosensor response towards 2-PE was linear in the range 0.02–0.70 mM. The biosensor preserved 93% of its initial sensitivity after 7 h of continuous operation and exhibited excellent storage stability with loss of only 6% of initial sensitivity within two months, when stored at 4 °C. The developed system was designed and successfully used for an off-line monitoring of whole course of 2-PE biooxidation process producing phenylacetic acid (PA) as industrially valuable aromatic compound. The biosensor measurement did not require the use of hazardous organic solvent. The biosensor response to 2-PE was not affected by interferences from PA and phenylacetaldehyde at concentrations present in real samples during the biotransformation and the results were in a very good agreement with those obtained via gas chromatography. 相似文献
90.
Various types of carbon nanoparticles were directly mixed with microbial cells of Gluconobacter oxydans within a 3-D bionanocomposite in order to prepare a highly sensitive ethanol biosensor with a short response time. From all carbonaceous nanomaterials tested, single- or multi-walled carbon nanotubes provided the highest sensitivity of detection (117–121 µA cm?2 mM?1), but from a practical point of view, Ketjen black 300 and 600 provide very low detection limit (2–6 µM) and high sensitivity for the ethanol analysis (84–88 µA cm?2 mM?1)with a shortresponse time (14–33 s). Moreover, the price of Ketjen black is a few orders of magnitude lower compared to that of carbon nanotubes. Finally, the study showed that the morphology of nanoparticles rather than their surface modification is the key element in achieving high sensitivity of ethanol detection. 相似文献