全文获取类型
收费全文 | 1032篇 |
免费 | 28篇 |
国内免费 | 3篇 |
专业分类
化学 | 702篇 |
晶体学 | 20篇 |
力学 | 5篇 |
数学 | 213篇 |
物理学 | 123篇 |
出版年
2022年 | 7篇 |
2021年 | 18篇 |
2020年 | 11篇 |
2019年 | 15篇 |
2018年 | 16篇 |
2017年 | 21篇 |
2016年 | 35篇 |
2015年 | 46篇 |
2014年 | 28篇 |
2013年 | 62篇 |
2012年 | 54篇 |
2011年 | 52篇 |
2010年 | 41篇 |
2009年 | 36篇 |
2008年 | 43篇 |
2007年 | 51篇 |
2006年 | 37篇 |
2005年 | 33篇 |
2004年 | 21篇 |
2003年 | 16篇 |
2002年 | 22篇 |
2001年 | 8篇 |
2000年 | 14篇 |
1999年 | 13篇 |
1997年 | 14篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 11篇 |
1992年 | 11篇 |
1991年 | 12篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1987年 | 11篇 |
1986年 | 8篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 12篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 10篇 |
1979年 | 9篇 |
1978年 | 9篇 |
1977年 | 13篇 |
1975年 | 16篇 |
1974年 | 11篇 |
1966年 | 9篇 |
1958年 | 23篇 |
1957年 | 10篇 |
1956年 | 6篇 |
排序方式: 共有1063条查询结果,搜索用时 0 毫秒
101.
The use of hydrophilic interaction liquid chromatography (HILIC) in food analysis in the last decade is reviewed. The HILIC mechanism is briefly discussed, but main emphasis is put on the use of HILIC for separation of different food matrices. The food matrices are divided into food of animal origin and related products, vegetables, fruits and related compounds, and other food-related matrices. A list on important applications is provided for each category including experimental conditions and a brief summary of the results. The 100 references included will provide the reader a comprehensive overview and insight into HILIC applications to food analysis. 相似文献
102.
A resin-bound nitroso compound sequestered a single unexpected component from crude plant seed extracts. Several plants, including Piper nigrum, Eugenia caryophyllata, and Pimenta dioica, were extracted with organic solvent in the presence of a nitroso-containing resin. The nitroso resin selectively sequestered a single compound, β-caryophyllene, via a chemo- and regioselective ene reaction. The ene product was released from the resin, and proper selection of the solid-phase linker and cleavage cocktail allowed concomitant further transformation of the primary ene product to a novel functionalized polycycle. Preliminary studies indicate that the new hydroxylamine-containing natural product derivatives have antibiotic activity. 相似文献
103.
Nonlinear Dynamics - In this work, the combination of the 0–1 test for chaos and approximate entropy is applied to a newly established mechanical model instead of the Lyapunov exponent... 相似文献
104.
105.
This work presents a systematic theoretical study on Cu(I) and Cu(II) cations in variable hydrogen sulfide-aqua-ammine ligand fields. These ligands model the biologically most common environment for Cu ions. Molecular structures of the complexes were optimized at the density functional theory (DFT) level. Subsequent thorough energy analyses revealed the following trends: (i) The ammine complexes are the most stable, followed by those containing the aqua and hydrogen sulfide ligands, which are characterized by similar stabilization energies. (ii) The most preferred Cu(I) coordination number is 2 in ammine or aqua ligand fields. A qualitatively different binding picture was obtained for complexes with H(2)S ligands where the 4-coordination is favored. (iii) The 4- and 5-coordinated structures belong to the most stable complexes for Cu(II), regardless of the ligand types. Vertical and adiabatic ionization potentials of Cu(I) complexes were calculated. Charge distribution (using the natural population analysis (NPA) method) and molecular orbital analyses were performed to elucidate the nature of bonding in the examined systems. The results provide in-depth insight into the Cu-binding properties and can be, among others, used for the calibration of bioinorganic force fields. 相似文献
106.
107.
Jaroslav Milbauer 《Fresenius' Journal of Analytical Chemistry》1918,57(4):161-162
Ohne Zusammenfassung 相似文献
108.
109.
The choice of lateral and terminal substitution can have a major influence on the structure of a liquid crystalline supermolecule, which in turn can induce radically different phase behaviour. In this study we use molecular dynamics simulations to investigate the shape of a liquid crystal dendrimer within a liquid crystalline solvent. A coarse-grained (CG) simulation model is employed to represent a third generation dendrimer in which 32 mesogenic groups are bonded to chains at the end of each branch of the dendrimer. In this CG-model the liquid crystal groups can be appended either terminally or laterally. This bonding option is used to generate the structure of four separate systems: (a) a dendrimer with 32 terminal mesogens, (b) a dendrimer with 32 laterally appended mesogens, (c) and (d) dendrimers with 16 lateral and 16 terminal groups represented with laterally bonded sites on one side of the molecule, model (c) or next to terminally bonded sites, model (d). The simulations show that the dendrimer is able to change shape in response to molecular environment and that the molecular shape adopted depends critically on the nature of the lateral/terminal susbstitution. 相似文献
110.