A note on the radical of a Banach algebra

Relying on the results of the paper [5], we show that the Jacobson radical of a Banach algebra can be characterized as the set of exactly those elements perturbations by which leave the spectrum invariant. A number of corollaries are listed.     

UV Light-induced Crosslinking of the Complementary Strands of Plasmid pUC19 DNA Restriction Fragments

Restriction fragments of pUC19 DNA were irradiated by various doses of UV light and analyzed by denaturing (alkaline) agarose gel electrophoresis. The irradiation generated retarded species whose mobility indicated two crosslinked DNA strands. Quantitative analysis of the experimental data provided an empirical equation relating the fraction of crosslinked DNA molecules to their length and to the dose of their irradiation by UV light. This equation can be used to predict the crosslinking behavior of pUC19-like DNA molecules whose primary structures do not much differ from a random nucleotide sequence. The amount of interstrand crosslinks increased with the (A+T) content of the pUC19 DNA fragments but the dependence was not clear-cut to indicate that oligonucleotide composition of DNA played a significant role as well.     

Influence of ion bombardment on growth and properties of PLD created DLC films

A hybrid PLD system with ion bombardment of films was developed. Growing DLC films were modified during the laser deposition (10 J?cm^?2) by argon ions with energy in the range from 40 eV to 210 eV and cathode current of 0.15 A and 0.5 A. The content of sp² “graphitic” and sp³ “diamond” bonds was measured using XPS. Sp³ bonds changed from 60 % to 81 %. We found the highest sp³ content for energy of 40 eV. Hardness (and reduced Young’s modulus) were determined by nanoindentation and reached 49 GPa (277 GPa). Film adhesion was studied using the scratch test and was up to 14 N for titanium substrates. Relations among deposition conditions and measured properties are presented.     

The Ramsey property for graphs with forbidden complete subgraphs

The following theorem is proved: Let G be a finite graph with cl(G) = m, where cl(G) is the maximum size of a clique in G. Then for any integer r ≥ 1, there is a finite graph H, also with cl(H) = m, such that if the edges of H are r-colored in any way, then H contains an induced subgraph G′ isomorphic to G with all its edges the same color.     

Surface and interface properties of thin pentacene and parylene layers

To improve Organic Thin Film Transistor (OTFT) properties we study OTFT semiconductor/dielectric interfacial properties via examination of the gate dielectric using thin Parylene C layer. Structural and morphology properties of pentacene layers deposited on parylene layer and SiO₂/Si substrate structure were compared. The surface morphology was investigated using atomic force microscopy (AFM) and scanning electron microscopy (SEM). AFM topography of pentacene layer in non-contact mode confirmed the preferable pentacene grain formation on parylene surface in dependence on layer thickness. The distribution of chemical species on the surfaces and composition depth profiles were measured by secondary ion mass spectroscopy (SIMS) and surface imaging. The depth profiles of the analyzed structures show a homogenous pentacene layer, characterized with C or C₂ ions. Relatively sharp interface between pentacene and parylene layers was estimated by characteristic increased intensity of CCl ions peak. For revealing the pentacene phases in the structures the Micro-Raman spectroscopy was utilized. Conformal coatings of parylene and pentacene layers without pinholes resulted from the deposition process as was confirmed by SIMS surface imaging. For the pentacene layers thicker than 20 nm, both thin and bulk pentacene phases were detected by Micro-Raman spectroscopy, while for the pentacene layer thickness of 5 and 10 nm the preferable thin phase was detected. The complete characterisation of pentacene layers deposited on SiO₂ and parylene surface revealed that the formation of large grains suggests 3D pentacene growth at parylene layer with small voids between grains and more than one monolayer step growth. The results will be utilized for optimization of the deposition process.      

Normisomorphismen und Normkurven endlichdimensionaler projektiver Desargues-Räume

In a finite dimensional desarguesian projective space the set of all points of intersection of homologous lines of two projective bundles of lines is called a non-degenerated (n. d.) normal curve, if the projective isomorphism is nondegenerated. Every frame determines a n. d. projective isomorphism of two bundles of lines called a normal isomorphism; every n. d. projective isomorphism of two bundles of lines is a normal isomorphism. A definition of osculating subspaces of a normal isomorphism is given and we show how the osculating subspaces can be constructed by using linear mappings. Simple examples show that there may be collineations fixing a n. d. normal curve but not fixing the osculating subspaces of the associated normal isomorphism. The set of osculating hyperplanes of a normal isomorphism is a n. d. normal curve in the dual space if and only if a certain number-theoretical condition holds.

---

---

Herrn emer.O. Univ.-Prof. Dr. J. Krames zum 85. Geburtstag gewidmet     

Impact of silica environment on hyperfine interactions in 𝜖-Fe2O3 nanoparticles

Magnetic nanoparticles have found broad applications in medicine, especially for cell targeting and transport, and as contrast agents in MRI. Our samples of ??-Fe₂O₃ nanoparticles were prepared by annealing in silica matrix, which was leached off and the bare particles were then coated with amorphous silica layers of various thicknesses. The distribution of particle sizes was determined from the TEM pictures giving the average size ～20 nm and the thickness of silica coating ～5; 8; 12; 19 nm. The particles were further characterized by the XRPD and DC magnetic measurements. The nanoparticles consisted mainly of ??-Fe₂O₃ with admixtures of ～1 % of the α phase and less than 1 % of the γ phase. The hysteresis loops displayed coercivities of ～2 T at room temperature. The parameters of hyperfine interactions were derived from transmission Mössbauer spectra. Observed differences of hyperfine fields for nanoparticles in the matrix and the bare ones are ascribed to strains produced during cooling of the composite. This interpretation is supported by slight changes of their lattice parameters and increase of the elementary cell volume deduced from XRD. The temperature dependence of the magnetization indicated a two-step magnetic transition of the ??-Fe₂O₃ nanoparticles spread between ～85 K and ～150 K, which is slightly modified by remanent tensile stresses in the case of nanoparticles in the matrix. The subsequent coating of the bare particles by silica produced no further change in hyperfine parameters, which indicates that this procedure does not modify magnetic properties of nanoparticles.     

Role of dispersed phase in the creep of ferritic steels

The effect of carbide particles of M4C₃ and M₂₃C₆ on the creep properties of low-alloy and modified chromium steels is investigated.Presented at the 4th International Symposium on Plasticity of Metals and Alloys, Srní, Czechoslovakia, September 7–11, 1987.